Reaction of amino acid esters with N-(2-iodophenyl)allenamides gives optically active products

Cascade Heck-Alkylation Reaction Gives α-Alkyl Tryptophans

Nonstabilized Carbenes Used for Asymmetric Cyclopropanations
Transition metal carbenoids generated from dihaloalkane precursors

Copper-Catalyzed Synthesis of Carbonic Acid Anhydrides
Blue-light-mediated synthesis starting from alkyl iodides and carbon monoxide

Total Syntheses of the Diterpenoids Scabrolide A and Yonarolide
The carbocyclic skeleton was efficiently constructed from two chiral-pool-derived fragments using a [5,5]-bicyclic lactone

Gold-Catalyzed Heck Reaction
Methodology overcomes limitations of previous transition metal-catalyzed Heck reactions

Beer in a Can or Bottle: Which is Better for Freshness and Stability?
There is no general best package for all beer styles but rather the effects of package type are dependent on beer style
![Regioselective Arylation of Pyrrolo[2,3-d]pyrimidines](https://www.chemistryviews.org/wp-content/uploads/2023/04/pyrrolopyrimidines-125x94.png)
Regioselective Arylation of Pyrrolo[2,3-d]pyrimidines
Palladium-catalyzed reaction with arylboronic acids

First Total Synthesis of (+)-Pedrolide
Diterpenoid with a 5–5–6–6–3-fused pentacyclic carbon skeleton

Convergent Total Synthesis of (+)-Ineleganolide
Natural product with a highly oxidized framework and a central seven-membered ring

Highly Strained Antiaromatic Metallacycle Isolated
Smallest angle of a metal vinylidene within a six-membered ring reported so far