Electrophilicity/nucleophilicity of common open-shell synthetic intermediates calculated and experimentally validated
Polarity of Over 550 Radicals Calculated
Frustrated Lewis Pair Anchored on Copper Nanoclusters for Catalysis
Immobilized catalysts for hydrogenation reactions provide high activity and regioselectivity
Enantioselective Alkylation of Primary Phosphines
Nickel-catalyzed asymmetric transformation using alkyl halides gives P-stereogenic secondary phosphine-boranes with high enantioselectivity
Twisting Planar Aromatic Compounds into a Figure Eight
Oxidative cleavage of an internal double bond of a polycyclic aromatic hydrocarbon (PAH) gives a figure-eight-shaped macrocycle
Gold(I) Catalysis Provides Access to Alkynyl C-Glycosides
Silyl-assisted, gold(I)-catalyzed transformation gives useful precursors for complex glycosides
New Strategy to Access Ketyl Radical Anions
Coupling of aldehydes and alkenes via α-hydroxy sulfinate and ketyl radical anion intermediates
2-Aminopyridines Made from Bench-Stable Reagents
2-Halopyridinium ketene hemiaminals allow for nucleophilic aromatic substitutions with amines
Organocatalyst for Electrochemical Hydrogen Evolution
Metal-free, N-heterocyclic phosphine (NHP)-type organocatalyst provides high activity
Metal-Free Synthesis of (Per)Fluoroalkyl-Functionalized Nitro-Indoles
Base-catalyzed intramolecular cyclization of N-acyl amides provides access to indole derivatives
Bismuth Catalyst Can Degrade the Stable SF6
Pincer bismuthinidene complexes allow reactions with inert greenhouse gas and the related PhSF5