Possible starting materials for subvalent gallium and indium chemistry with very weakly coordinating ligands

“Naked” Ga(I) and In(I) Salts

Don’t Forget Thermodynamics
Klaus Kümmerer on green and sustainable chemistry, the importance of kinetics, and why it is important to do something outside your area of interest once in a while

Cyclooctatetraene-Embedded Carbon Nanorings
Carbon nanorings prepared in a Yamamoto coupling can form host-guest complexes with fullerenes

Unusual Reaction Gives A Peroxynitrite
[ONOO]– obtained via a cascade reaction between KO3 and ammonia in the presence of a partially fluorinated aniline-based cation

Sparkler Burns in Raw Egg
A cool Easter experiment and a bit of chemistry to go with it

Bis(Aluminyl)Magnesium Compound with Dual Reactivity
Al–Mg–Al system shows both radical chemistry and nucleophilic behavior at aluminium

Uranyl Captured in a Heterobimetallic Crown Ether Complex
Tailored macrocyclic ligand forms an isolable complex with UO22+

Salts of Protonated Sulfur Dioxide Synthesized
Elusive hemi- and monoprotonated SO2 cations isolated as Sb2F11− salts

Does the Ligand Connectivity of MOFs Affect Their Mechanical Stability?
High-pressure behavior of metal–organic frameworks (MOFs) with different linkers compared

The First Crystalline Compound with a –C≡C–COO– Anion
Double deprotonation of propiolic acid gives elusive, Y-shaped anion