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Category: News

Hydroborations Using a Cyclic Carbodiphosphorane Catalyst
Catalysis|Organic

Hydroborations Using a Cyclic Carbodiphosphorane Catalyst

November 9, 2023

Transformations of carbodiimide and isocyanate substrates at room temperature

Dioxaphosphabicyclo[2.2.2]octanes as Cage-Like Phosphine Ligands
Inorganic|Organic

Dioxaphosphabicyclo[2.2.2]octanes as Cage-Like Phosphine Ligands

November 9, 2023

Relatively air-stable phosphines prepared in a one-pot reaction from tris(hydroxymethyl)phosphine

Bacterial Hemoglobin as a Biocatalyst for the Synthesis of Benzoxazoles
Bio|Catalysis

Bacterial Hemoglobin as a Biocatalyst for the Synthesis of Benzoxazoles

November 8, 2023

Efficient, green method uses Vitreoscilla hemoglobin in water at room temperature

Highly Oxidizing Iodine(III) Reagents
Inorganic|Organic

Highly Oxidizing Iodine(III) Reagents

November 8, 2023

Bistriflimide groups enhance the reactivity of hypervalent iodine compounds

Carbon–Heteroatom Cross-Coupling Catalyzed by Nickel Naphthyridine Complexes
Catalysis|Organic

Carbon–Heteroatom Cross-Coupling Catalyzed by Nickel Naphthyridine Complexes

November 6, 2023

Light-promoted formation of C‒N and C‒O bonds using Ni(II) complexes

Cobalt–SiH2 Derivative Provides Access to Silicide Complexes
Inorganic

Cobalt–SiH2 Derivative Provides Access to Silicide Complexes

November 6, 2023

Modular assembly of silicide structures using a synthon for the simplest terminal silylene complex

Switching the Selectivity of CO2 Reduction
Catalysis|Inorganic

Switching the Selectivity of CO2 Reduction

November 5, 2023

Replacing Co with Fe in a polypyridine complex changes the product from formate or  H2 to CO

Electrochemical Deoxygenative Homo-Coupling of Aromatic Aldehydes
Organic

Electrochemical Deoxygenative Homo-Coupling of Aromatic Aldehydes

November 5, 2023

Access to bibenzyl and stilbene derivatives

Electrophotochemical Trifluoromethylation of Arenes
Organic

Electrophotochemical Trifluoromethylation of Arenes

November 4, 2023

Inexpensive trifluoroacetic acid used as a source of CF3

Azo-Dipyrazolate MOF for Acetylene Purification
Inorganic

Azo-Dipyrazolate MOF for Acetylene Purification

November 3, 2023

Chain-type, zinc-based metal-organic frameworks (MOFs) act as promising adsorbents for challenging gas separation

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