Transformations of carbodiimide and isocyanate substrates at room temperature

Hydroborations Using a Cyclic Carbodiphosphorane Catalyst
![Dioxaphosphabicyclo[2.2.2]octanes as Cage-Like Phosphine Ligands](https://www.chemistryviews.org/wp-content/uploads/2023/11/dioxaphosphabicyclooctanes_2023-125x94.png)
Dioxaphosphabicyclo[2.2.2]octanes as Cage-Like Phosphine Ligands
Relatively air-stable phosphines prepared in a one-pot reaction from tris(hydroxymethyl)phosphine

Bacterial Hemoglobin as a Biocatalyst for the Synthesis of Benzoxazoles
Efficient, green method uses Vitreoscilla hemoglobin in water at room temperature

Highly Oxidizing Iodine(III) Reagents
Bistriflimide groups enhance the reactivity of hypervalent iodine compounds

Carbon–Heteroatom Cross-Coupling Catalyzed by Nickel Naphthyridine Complexes
Light-promoted formation of C‒N and C‒O bonds using Ni(II) complexes

Cobalt–SiH2 Derivative Provides Access to Silicide Complexes
Modular assembly of silicide structures using a synthon for the simplest terminal silylene complex

Switching the Selectivity of CO2 Reduction
Replacing Co with Fe in a polypyridine complex changes the product from formate or H2 to CO

Electrochemical Deoxygenative Homo-Coupling of Aromatic Aldehydes
Access to bibenzyl and stilbene derivatives

Electrophotochemical Trifluoromethylation of Arenes
Inexpensive trifluoroacetic acid used as a source of CF3

Azo-Dipyrazolate MOF for Acetylene Purification
Chain-type, zinc-based metal-organic frameworks (MOFs) act as promising adsorbents for challenging gas separation