Radical–Metal Complex with Record Fluorescence Quantum Yield

Radical–Metal Complex with Record Fluorescence Quantum Yield

Author: ChemistryViews

Radical fluorescence can be useful in the development of luminescent materials. Metal complexation can enhance the photoproperties of organic radicals. For example, the fluorescence quantum yield of the (3,5-dichloro-4-pyridyl)bis(2,4,6-trichlorophenyl)methyl radical (PyBTM) can be enhanced from 2 % to 8 % by coordination to a gold(I) phosphine complex [1].

Yohei Hattori, Ryukoku University, Otsu, Shiga, Japan, and colleagues have used a related, fluorine-functionalized radical ligand, the (3,5-difluoro-4-pyridyl)bis(2,4,6-trichlorophenyl)methyl radical (F2PyBTM), and enhanced its fluorescence quantum yield up to 36 % by coordination to Au(I) complexes with different N-heterocyclic carbene (NHC) ligands (general structure pictured). This is a new record fluorescence quantum yield among luminescent radical–metal complexes.

The team synthesized hexafluoroantimonate salts of the desired gold(I) complexes by reacting [Au(NHC)Cl]-type precursors with silver hexafluoroantimonate (AgSbF6) and F2PyBTM, giving the desired products and AgCl. The resulting radical complexes are stable under ambient conditions and have fluorescence quantum yields of 13–36 %. The highest fluorescence quantum yield was achieved using an 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) NHC ligand, which provides a nine-fold enhancement over the F2PyBTM radical alone.




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