Amine-free, directing-group-free transformation using quantum dots as a photocatalyst
α-Alkylation of Saturated Cyclic Ketones
Ruthenium-Catalyzed Path to Aryl and Alkenyl Halides from Fluorosulfonates
Transformation of readily available starting materials is compatible with chloride, bromide, and iodide
Machine-Learning Model Predicts Enzyme-Substrate Pairs
Method can be used across a broad range of different enzymes and metabolites
Photochemical Deracemization of 3-Substituted Oxindoles
Racemate successfully converted into enantiomerically pure or enriched material in the presence of a chiral benzophenone catalyst
Total Synthesis of Chaetoglobin A
Dimeric alkaloid from a fungus has a chiral axis connecting two azaphilone systems
Gold-Catalyzed Reaction Gives Antitumor-Active Spirocyclic Oxindoles
Formal cycloaddition reaction of terminal alkynes or ynamides with isatin-derived ketimines
Synthesis of Bis-Benzofulvenes
Route from gem-dibromoolefins via bromobenzofulvene intermediates
Phosphine Oxide-Substituted Cyclam Ligand Synthesized
Ligand with high selectivity for Cu(II) over competing divalent cations
Nickel-Catalyzed Coupling of Heteroarenes and Arenols
Pivalic anhydride used as an in-situ activating reagent in C−H/C−OH coupling
Alkene Insertion into Carbon–Halogen Bonds Enabled by Aggregation
Ionic insertion without additional catalysts or promoters