First Total Synthesis of Pepluacetal

First Total Synthesis of Pepluacetal

Route relying on a Wolff rearrangement/lactonization cascade, a ring-closing metathesis/cyclopropanation sequence, and a late-stage transannular carbenoid insertion

Exploring Superatomic-Based Chirality

Exploring Superatomic-Based Chirality

Using superatoms as centers and simulating inter-atomic bonding behavior through inter-superatomic bonding shows promise for constructing novel asymmetric chiral molecules