Coupling of tertiary alkyl halides with secondary alkyl zinc reagents gives products with high steric hindrance

Quaternary Carbon Centers Built Using an Iron-Catalyzed Coupling Reaction

Buckybowl Conformation Controlled by Crystallization Solvent
Monofluorosumanene forms crystals with entirely different dielectric responses depending on the crystallization conditions

Chiral Double π-Helical Nanoribbons
Creating a platform to understand how chirality spreads and dissymmetry amplifies

First Complex With a Plutonium Carbon Double Bond
Preparation of a diphosphoniomethanide-Pu complex along with two diphosphonioalkylidene-Pu complexes

Palladium-Catalyzed Aminoalkynylation Gives Chiral Isoindolinones
Efficient coupling of O-phenyl hydroxamic ethers with terminal alkynes

Efficient Radioiodination of Arenes
Clean radioiodination of aryl boronic acids at room temperature using low loadings of a copper precatalyst

First Chalcogen Bonds Centered at Water Oxygen Atoms
Highly polarized water molecules trapped between two lithium ions show unprecedented interaction

Cube-Shaped, Water-Stable Boronate Ester Cages
Steric shielding provides unprecedented stability

Carboiodanation of Arynes Using Organoiodine(III) Reagents
Unique nucleophilic reactivity allows for additions across the C−C triple bond of arynes

Mesoionic Janus-Type Dicarbenes Form Bimetallic Complexes
Two carbene centers on a single ring can bind two metals with short intermetallic distances