Unprecedented reaction gives distinct rearrangement products that cannot be explained by classical reactivity models

Conformers Undergo Different Reactions Controlled by Quantum Tunneling

Half-Sandwich Complexes of Magnesium as Catalysts
s-Block catalysts with applications in different dehydrocoupling and hydroelementation reactions
![Visible-Light-Driven Synthesis of Bicyclo[2.1.1]hexanes](https://www.chemistryviews.org/wp-content/uploads/2022/11/bicyclohexanes-125x94.jpg)
Visible-Light-Driven Synthesis of Bicyclo[2.1.1]hexanes
Intramolecular crossed [2 + 2] photocycloaddition leads to useful building blocks

Cycloparaphenylenes with a Twist
Alkene insertion into cycloparaphenylenes gives circular molecules with Möbius topology
![Quasi-[7]Circulenes Prepared from Aza[5]helicenes](https://www.chemistryviews.org/wp-content/uploads/2022/11/quasicirculene-125x94.jpg)
Quasi-[7]Circulenes Prepared from Aza[5]helicenes
Electrophilic borylation followed by formation of an N→B bond

Upcycling Plastics via Fungal Biosynthesis
Fungi metabolize diacids derived from polyethylene into pharmaceutically active compounds

In-situ Phosgene Synthesis from Chloroform
Photochemical oxidation of chloroform in a continuous flow reactor for on-demand phosgenation

Subvalent Ni(I) Complex for Small-Molecule Activation
Bis(diphenyl)-phosphine functionalized ß-diketimine ligand system

Dimethyl Ether Activates Metal–Organic Frameworks
Gentle method for MOF activation removes guest solvent molecules and prevents structural collapse

TiCl4-Catalyzed Reduction of Carboxylic Acids to Alcohols
Safe reduction protocol for a broad range of acids using NH3BH3