Unprecedented reaction of a bismuth hydride with phenylacetylene

The First Hydrobismuthation

Microporous Sodium Metal–Organic Framework
Octacarboxylate linker used to build an alkali metal-based framework

How Long Can Champagne Be Stored?
The size of the bottle is important for the gradual release of CO2 in champagne as it ages

General Path to N-Arylpiperidines
Ring-opening and ring-closing approach gives pyridinium salts that can be converted to N-(hetero)arylpiperidine derivatives

Cyclization of 5-Iodo-4-Pentenenitriles Gives Cyclopentenones
Ligand-free Pd(0)-catalyzed cyclization followed by imine hydrolysis

4-Iodine N-Methylpyridinium for Solid-Phase Peptide Synthesis
Bench-stable and cost-effective coupling reagent

Molecular Tweezers Made from Carbaporphyrin Linked to Nanographenes
Hybrid systems act as receptors for relatively large substrates

Triplet Vinylarsinidene Synthesized
Higher congener of vinylnitrene prepared by low-temperature photolysis or high-vacuum flash pyrolysis

General Path to 3-Methylindoles
Oxazoline palladacycle with NHC ligand catalyzes cyclization reaction of ortho-dihaloarenes and N-allylamines

Defluoroalkylation of gem-Difluoroalkenes
α-Fluoroalkenyl alcohols prepared via C–F/C–H coupling