Ligand-mediated control of closed- and open-shell electronic states

Bis(9-Boraphenanthrene) and Stable Biradical Form Isolated

Sulfurative 1,2-Diamination of Phenylacetylenes
DABCO-catalyzed path to quinoxaline-2-thiones

Protein Levels Involved in Cognitive Impairment Caused by Sleep Deprivation
Levels of pleiotrophin found to be associated with cognitive function

Enantioselective Synthesis of Difluoroalanine
Straightforward multigram synthesis, peptide incorporation, and hydrophobicity assessment

Catalyst-to-Zn Transmetalation Gives Useful Zinc Metallacycles
Asymmetric synthesis of zinc metallacycles from alkynes and imines

Dehydrogenative Coupling of N-Heterocycles with Aldehydes
Dehydrogenative coupling gives ketone derivatives

Trifluoromethylthiolation of Tryptophan and Tyrosine Derivatives
Functionalization enhances the local hydrophobicity of peptides

Asymmetric Synthesis of Bulky Amines Using Enzymes
Engineered imine reductases used for the conversion of diphenylmethanimines

Catalytic Asymmetric Carbene Insertion into P–H Bonds
Transition-metal catalysis combined with organocatalysis to allow new asymmetric reactions

Benzoselenophenes Synthesized from Enamides and Elemental Selenium
TMSCN-enabled, radical-mediated tandem reaction