Transition-metal catalysis combined with organocatalysis to allow new asymmetric reactions

Catalytic Asymmetric Carbene Insertion into P–H Bonds

Benzoselenophenes Synthesized from Enamides and Elemental Selenium
TMSCN-enabled, radical-mediated tandem reaction

Chemoenzymatic Synthesis of 13-Oxoverruculogen
Organic peroxide natural product with promising cytotoxicity

Oxidative Cross-Coupling of 3-Hydroxycarbazoles with Arenols
Bismuth(III)-catalyzed transformation gives hydroxybiaryls

First Total Syntheses of Hyperireflexolides A and B
Bioinspired pathway involves dearomatization and fragmentation of an acylphloroglucinol

Cross-Coupling Reactions of Aryl Iodides with Silver Carboxylates
Gold-catalyzed C–O cross-coupling

Microplastics Detected in Human Heart Tissue
Samples collected from cardiac surgery patients contain several types of microplastic particles

Concise Total Syntheses of Hamigeran Natural Products
Compounds with a 6–7–5 tricyclic carbon skeleton and interesting biological activities

Co(III)-Catalyzed Oxidative C–H Alkenylation of Acrylamides
Cross-coupling of α,β-unsaturated compounds with unactivated alkenes

An Isolable Diiminoborane
BN analogue of butadiyne can be used for the controlled release of dinitrigen