Reaction mediated by N,N,N',N'-tetramethylethylenediamine (TMEDA) via a hydride transfer

Reduction of Phosphine Oxides to Phosphines Mediated by an Amine

Hydride-Storing Ligand for Hydrogenation Catalysis
Iridium complex with a pyridinium-based ligand for NADH-like hydride storage and release

Practical Path to Substituted Terminal Monofluoroalkenes
Horner–Wadsworth–Emmons olefination/hydrolysis/decarboxylation sequence gives vinyl fluorides

C–H Bond Phosphorylation Using Iron Photocatalysis
Diverse tertiary phosphines prepared from industrial phosphine sources

Tetrasilane Used for Divergent Synthesis of Silacycles
Time-controlled palladium-catalyzed reaction using octamethyl-1,4-dioxacyclohexasilane

Gas-Phase Synthesis of Coronene
Polycyclic aromatic hydrocarbon (PAH) prepared via aryl-radical-mediated ring annulations

Stereoselective Total Synthesis of (+)-Preussin
Gold(I)-catalyzed intramolecular dehydrative amination used as a key step

Biocatalytic Synthesis of Metaxalone
Protein engineering of a halohydrin dehalogenase leads to useful oxazolidinone products

New Class of Negatively Curved Polycyclic Arenes
Tandem oxidative ring expansion gives products with oxepine or thiepine rings

Benzoxazinones Prepared from Aniline Derivatives and CO
Rh(III)-catalyzed ortho-C–H bond carbonylation gives useful heterocycles