Electrophilic borylation followed by formation of an N→B bond
![Quasi-[7]Circulenes Prepared from Aza[5]helicenes](https://www.chemistryviews.org/wp-content/uploads/2022/11/quasicirculene-125x94.jpg)
Quasi-[7]Circulenes Prepared from Aza[5]helicenes

In-situ Phosgene Synthesis from Chloroform
Photochemical oxidation of chloroform in a continuous flow reactor for on-demand phosgenation

TiCl4-Catalyzed Reduction of Carboxylic Acids to Alcohols
Safe reduction protocol for a broad range of acids using NH3BH3

Styrene Derivatives Synthesized from Allyl Silanes
Allyl silanes isomerized to alkenyl silanes, followed by a Hiyama coupling

Boron-Functionalized Heptaphosphide Zintl Cluster
Transition-metal-free catalyst for hydroborations

1,2-Diborete Biradicaloid Isolated
Four-membered C2B2 heterocycles stabilized by cyclic alkyl(amino)carbene (CAAC) units

TiO2/Au Nanocomposites for CO2 Reduction
Easy-to-synthesize catalysts with high activity and stability

Monometallic Endohedral Azafullerene
Substitution and encapsulation can be used to tailor the electronic states of fullerenes

Disilicon Dicarbonyl Complex
Reaction of disilyne with carbon monoxide gives unique complex

Electrochemical Synthesis of Dibenzothiophenes
Electro-oxidative C–S coupling using Bu4NBr as a halogen mediator