Unprecedented reaction gives distinct rearrangement products that cannot be explained by classical reactivity models

Intramolecular crossed [2 + 2] photocycloaddition leads to useful building blocks

Electrophilic borylation followed by formation of an N→B bond

Photochemical oxidation of chloroform in a continuous flow reactor for on-demand phosgenation

Safe reduction protocol for a broad range of acids using NH₃BH₃

Allyl silanes isomerized to alkenyl silanes, followed by a Hiyama coupling

Transition-metal-free catalyst for hydroborations

Four-membered C₂B₂ heterocycles stabilized by cyclic alkyl(amino)carbene (CAAC) units

Easy-to-synthesize catalysts with high activity and stability

Substitution and encapsulation can be used to tailor the electronic states of fullerenes