Iridium-catalyzed asymmetric allylic alkylation reaction

Asymmetric Substitution of Methyl Azaarenes

Pushing the Length Limit of Dihydrodiboraacenes
Boron‐embedded heptacene and nonacene synthesized

Carboxylic Acids Used Directly as Acyl Radical Precursors
Boronic-acid-mediated photocatalysis enables intramolecular hydroacylation of olefins

An Extremely Bulky Cyclopentadienyl Ligand
Complete series of alkali metal salts of a penta-terphenyl cyclopentadienyl ligand prepared

Cyanogramides B and C Synthesized
Biosynthetic precursors of a spiro indole alkaloid from marine-derived bacteria

Stable Aromatic Trications
Tricarboxybenzenes were (tri)protonated to give surprisingly stable species

Priestley Medal 2022 for Peter B. Dervan
Highest honor of the American Chemical Society (ACS) presented to researcher working at the interface of chemistry and biology

Engineered Enzymes Used to Synthesize Biaryls
Biocatalytic cross-couplings with cytochrome P450 enzymes

F/Cl Exchange Reactions of Fluoromethanes and Fluoroolefins
Reaction catalyzed by highly Lewis acidic nanoscopic aluminum chlorofluoride

First Total Synthesis of (−)-3-Oxoisotaxodione
Chiral bicyclic hydrazide used as an organocatalyst for key synthetic step