Cross-coupling of alkyl acids, alkynes, and [1.1.1]propellane
![Three-Component Reaction Gives Substituted Bicyclo[1.1.1]pentanes](https://www.chemistryviews.org/wp-content/uploads/2022/06/propellane-125x94.jpg)
Three-Component Reaction Gives Substituted Bicyclo[1.1.1]pentanes

Triflic Acid-Catalyzed Reaction Gives Diaryl Sulfones
Metal-free sulfonylation approach

Regioselective Carboboration of Terminal Alkynes
Cyclic(alkyl)(amino)carbene (CAAC) ligands favor α-selectivity in copper-catalyzed reaction

Enantioselective Hydrocarbamoylation of Alkenes
Metal-catalyzed route to chiral amides using a carbamoylating reagent

Nickel-Bromide-Catalyzed Suzuki Coupling Reactions
Ligand-free and activatorless C–C coupling reactions

Angewandte Chemie 26/2022: Enlightening Chemistry
Overview of the latest issue of Angewandte Chemie

Nonactivated Cyclopropanes Used to Prepare Lactams
Secondary amines and anilines as directing groups for carbonylative C–C bond insertions

Not All Organocatalysts Are Equally Ecofriendly
Aminocatalysts are more environmentally friendly than hydrogen‐bonding catalysts

Bioinspired Synthesis of Emeriones A–C
Asymmetric total syntheses of fungal metabolites enabled by 8π/6π electrocyclization cascade

A New Mechanism for AIE-TADF Behaviors
Conformational isomerization can play a role in thermally activated delayed fluorescence (TADF) with aggregation-induced emission (AIE)