Sequential borylation, 1,2-carbon migration, and oxidation with Oxone

1,1-Oxycarbonation of Terminal Alkynes

Carbene Insertion into the γ-C–H Bonds of Aliphatic Amines
Regioselective transformation uses a palladium catalyst and a picolinamide directing group

Alfred Hassner (1930 – 2024)
Internationally known organic chemist, known for small-ring heterocycles and organic synthesis methodology, passed away

Does the Ligand Connectivity of MOFs Affect Their Mechanical Stability?
High-pressure behavior of metal–organic frameworks (MOFs) with different linkers compared

Azoxy-Triazenes Used for the Aziridination of Alkenes
Readily available species serving as nitrogen atom sources in a photoinduced transformation

Decarboxylative Amination of Substituted Malonic Acid Half Oxyesters
Organocatalyzed reaction with dialkyl azodicarboxylates gives α-aminoester derivatives

New Method for Protein Desulfurization
Mild protocol using tris(2-carboxyethyl)phosphine hydrochloride (TCEP) as a reductant and tetrahydroxydiboron as a radical initiator

How Do Organic Radicals Aggregate in Polar Fluorocarbon Solvents?
Aggregates of radicals that form intermolecular hydrogen bonds can accelerate catalysis

First Total Synthesis of Pepluacetal
Route relying on a Wolff rearrangement/lactonization cascade, a ring-closing metathesis/cyclopropanation sequence, and a late-stage transannular carbenoid insertion

Behind the Science: Singlet Fission in a New Series of Tetracene Oligomers
Novel molecular system with a hexaphenylbenzene core and multiple tetracene chromophores arranged to dictate through-space coupling, addressing low singlet fission efficiencies in tetracene dimers