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Journal of Applied Polymer Science

A facile route to prepare homogeneous silicone resin doped with titanium

Published: 19 April 2019

Author(s): Jianjun Chen, Zien Fu, Hengchao Huang, Zhonghua Chen, Xingrong Zeng

ABSTRACT A facile route was introduced to prepare homogeneous silicone resin doped with titanium hybrid with high refractive index (RI). Specifically, the hybrids were obtained from the transesterification of hydroxyl‐phenyl‐vinyl silicone resin and titanium isopropoxide under anhydrous conditions. The structures of hybrid silicone and their corresponding intermediates (hydroxyl‐phenyl‐vinyl silicone) were characterized by nuclear magnetic resonance spectroscopy (1H NMR, 29Si NMR) as well as...

Journal of Applied Polymer Science

Fabrication and electrochemical characterization of polyimide‐derived carbon nanofibers for self‐standing supercapacitor electrode materials

Published: 18 April 2019

Author(s): Nam Koo Han, Ji Hyung Ryu, Do Un Park, Jae Hak Choi, Young Gyu Jeong

ABSTRACT We report the electrochemical performance of aromatic polyimide (PI)‐based carbon nanofibers (CNFs), which were fabricated by electrospinning, imidization, and carbonization process of poly(amic acid) (PAA) as an aromatic PI precursor. For the purpose, PAA solution was electrospun into nanofibers, which were then converted into CNFs via one‐step (PAA‐CNFs) or two‐step heat treatment (PI‐CNFs) of imidization and carbonization. The FTIR and Raman spectra demonstrated a successful...

Journal of Applied Polymer Science

Curing of a tetrafluoroethylene–propylene elastomer with high‐vinyl polybutadiene rubber and peroxide

Published: 18 April 2019

Author(s): Chuanbo Cong, Qingkun Liu, Peng Wei, Xiaoyu Meng, Qiong Zhou

ABSTRACT A cocuring agent is necessary for tetrafluoroethylene–propylene elastomer (FEPM), which cannot be cured by peroxide alone. We observed that high‐vinyl polybutadiene rubber (HVBR) could be used as a cocuring agent for FEPM. The structure and properties of FEPM–HVBR blend vulcanizates were investigated by 13C‐NMR, differential scanning calorimetry, swelling tests, tensile tests, dynamic mechanical analysis, and thermogravimetric analysis. This research showed that HVBR significantly...

Journal of Applied Polymer Science

Polyacrylonitrile–poly(1‐vinyl pyrrolidone‐co‐vinyl acetate) blend based gel polymer electrolytes incorporated with sodium iodide salt for dye‐sensitized solar cell applications

Published: 18 April 2019

Author(s): Norshahirah Mohamad Saidi, Hong Ming Ng, Fatin Saiha Omar, Shahid Bashir, K. Ramesh, S. Ramesh

ABSTRACT New gel polymer electrolytes (GPEs) were prepared via the blending of a polyacrylonitrile polymer and a poly(1‐vinyl pyrrolidone‐co‐vinyl acetate) copolymer. The sodium iodide (NaI) salt concentration was varied for each GPE sample. From ionic conductivity (σ) studies, we observed that the sample with a 40 wt % NaI salt content (N40) showed the highest σ of 3.54 × 10−3 ± 0.05 S/cm at room temperature, and all of the GPE samples obeyed Arrhenius behavior. The dielectric properties of...

International Journal of Quantum Chemistry

Comment on “Approximate Analytical Versus Numerical Solutions of Schrödinger Equation Under Molecular Hua Potential”

Published: 18 April 2019

Author(s): M. Ferdjaoui, A. Khodja, F. Benamira, L. Guechi

International Journal of Quantum Chemistry

Reply to comment on “Approximate analytical versus numerical solutions of Schrödinger equation under molecular Hua potential”

Published: 18 April 2019

Author(s): Hassan Hassanabadi, Bentol Hoda Yazarloo, Saber Zarrinkamar, Mehdi Solaimani

ChemBioChem

Organic Semiconductors for Photothermal Therapy and Photoacoustic Imaging

Published: 18 April 2019

Author(s): Xuemei Wang, Zhongmin Geng, Hailin Cong, Youqing Shen, Bing Yu

Abstract In recent years, semiconducting polymer nanoparticles (SPNs) have been attracting considerable attention because of their outstanding characteristics such as higher light and thermal stability. They are widely used in fields of biomedicine such as photoacoustic (PA) imaging (PAI), photodynamic therapy (PDT), and photothermal therapy (PTT). PAI, a new imaging modality based on PA effects, shows great promise in biomedical applications. SPNs that display strong optical absorbance in the...

ChemBioChem

Genome‐Scale CRISPR/Cas9 Screening Reveals Squalene Epoxidase as a Susceptibility Factor for Cytotoxicity of Malformin A1

Published: 18 April 2019

Author(s): Yukio Koizumi, Jun Fukushima, Yayoi Kobayashi, Ayumi Kadowaki, Miyuki Natsui, Tomokazu Yamaguchi, Yumiko Imai, Toshihiro Sugiyama, Keiji Kuba

Abstract Malformin A1 (MA1) is a fungus‐produced cyclic pentapeptide. MA1 exhibits teratogenicity to plants, fibrinolysis‐enhancing activity, and cytotoxicity to mammalian cells. To clarify the cytotoxic mechanism of MA1, we screened for the genes involved in the cytotoxicity of MA1 in monocytoid U937 cells by using a CRISPR/Cas9‐based genome‐wide knockout library. Screening was performed by positive selection for cells that were resistant to MA1 treatment, and single guide RNAs (sgRNAs)...

ChemBioChem

Photoactivable Elimination of Tumorigenic Human Induced Pluripotent Stem Cells by Using a Lectin–Doxorubicin Prodrug Conjugate

Published: 18 April 2019

Author(s): Johann Dion, Fumi Minoshima, Sayoko Saito, Kayo Kiyoi, Kayo Hasehira, Hiroaki Tateno

Abstract Human pluripotent stem cells (hPSCs) are attractive resources for regenerative medicine, but medical applications are hindered by their tumorigenic potential. Previously, a hPSC‐specific lectin probe, rBC2LCN, was identified through comprehensive glycome analysis by using high‐density lectin microarrays. Herein, a lectin–doxorubicin (DOX) prodrug conjugate, with controllable photolysis activation for the elimination of tumorigenic human induced pluripotent stem cells, has been...

ChemBioChem

Ordered and Isomerically Stable Bicyclic Peptide Scaffolds Constrained through Cystine Bridges and Proline Turns

Published: 18 April 2019

Author(s): Ping Lin, Hongwei Yao, Jun Zha, Yibing Zhao, Chuanliu Wu

Abstract Bicyclic peptides are attractive scaffolds for the design of potent protein binders and new therapeutics. However, peptide bicycles constrained through disulfide bonds are rarely stable or tolerant to sequence manipulation owing to disulfide isomerization, especially for peptides lacking a regular secondary structure. Herein, we report the discovery and identification of a class of bicyclic peptide scaffolds with ordered but irregular secondary structures. These peptides have a...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

February 2019


	Pingyu Zhang, Huaiyi Huang, Samya Banerjee, Guy J. Clarkson, Chen Ge, Cinzia Imberti, Peter J. Sadler Nucleus-Targeted Organoiridium-Albumin Conjugate for Photodynamic Cancer Therapy [Communication] Angew. Chem. Int. Ed. 2019, vol. 58, p. 2350

	Marion Rusch, Arnaud Thevenon, Dominic Hoepfner, Thomas Aust, Christian Studer, Maude Patoor, Patrick Rollin, Madeleine Livendahl, Beatrice Ranieri, Esther Schmitt, Carsten Spanka, Karl Gademann, Laure C. Bouchez Design and Synthesis of Metabolically Stable tRNA Synthetase Inhibitors Derived from Cladosporin [Communication] ChemBioChem 2019, vol. 20, p. 644

	Wei Jin, Laura Pastor-Pérez, DeKui Shen, Antonio Sepúlveda-Escribano, Sai Gu, Tomas Ramirez Reina Catalytic Upgrading of Biomass Model Compounds: Novel Approaches and Lessons Learnt from Traditional Hydrodeoxygenation - a Review [Review] ChemCatChem 2019, vol. 11, p. 924

	Dieter Wöhrle Kunststoffe [Artikel] Chem. Unserer Zeit 2019, vol. 53, p. 50

	Thomas Wirth Meet the Board of ChemistryOpen: Thomas Wirth [Meet the Board] ChemistryOpen 2019, vol. 8, p. 251

	Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang Chemical Sensors Based on Metal-Organic Frameworks [Review] ChemPlusChem 2016, vol. 81, p. 675

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, p. 6055

	Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen Regulatory Aspects of Nanomaterials in the EU [Research Article] Chem. Ing. Tech. 2017, vol. 89, p. 224

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, p. 75

	Mao Jiang, Kangli Wang, Shu Gao, Ruxing Wang, Jing Han, Jie Yan, Shijie Cheng, Kai Jiang Selenium as Extra Binding Site for Sulfur Species in Sulfurized Polyacrylonitrile Cathodes for High Capacity Lithium-Sulfur Batteries [Article] CHEMELECTROCHEM 2019, vol. 6, p. 1365

	Tianchao Niu, Jialin Zhang, Wei Chen Surface Engineering of Two-Dimensional Materials [Focus Review] ChemNanoMat 2019, vol. 5, p. 6

	Dennis Rottschäfer, Beate Neumann, Hans-Georg Stammler, Ryohei Kishi, Masayoshi Nakano, Rajendra S. Ghadwal A Phosphorus Analogue of p-Quinodimethane with a Planar P₄ Ring: A Metal-Free Diphosphorus Source [Communication] Chem. Eur. J. 2019, vol. 25, p. 3244

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, p. 2696

	Arun K. Sinha, Danish Equbal Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review] Asian J. Org. Chem. 2019, vol. 8, p. 32

	Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper] ChemMedChem 2018, vol. 13, p. 988

	Gloria Tabacchi Supramolecular Organization in Confined Nanospaces [Review] ChemPhysChem 2018, vol. 19, p. 1249

	Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review] ChemPhotoChem 2018, vol. 2, p. 386

	An-Na Cho, Nam-Gyu Park Impact of Interfacial Layers in Perovskite Solar Cells [Review] ChemSusChem 2017, vol. 10, p. 3687

	Didier Astruc Why is Ferrocene so Exceptional? [Microreview] Eur. J. Inorg. Chem. 2017, p. 6

	Mabuatsela V. Maphoru, Josef Heveling, Sreejarani Kesavan Pillai Solvent and Temperature Effects on the Platinum‐Catalyzed Oxidative Coupling of 1‐Naphthols [Full Paper] Eur. J. Org. Chem. 2016, p. 331

	Cover Picture Lebensmittelchemie 1/2019 [Cover Picture] Lebensmittelchemie 2019, vol. 73

	Elementerätsel 1 [Wissenschaft + Forschung] Nachr. Chem. 2019, vol. 67, p. 37

	Schüleraufgabe: CHEMKON 2/2017 [Schüleraufgabe] CHEMKON 2017, vol. 24, p. 91

	Zheng Ma, Douglas R. MacFarlane, Mega Kar Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview] Batteries & Supercaps 2019, vol. 2, p. 115

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal

2017


	Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

	Philippe Compain, Anne Bodlenner The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview] ChemBioChem 2014, vol. 15, pp. 1239–1251

	Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75

	Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

	Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez Gated Silica Mesoporous Materials in Sensing Applications [Review] ChemistryOpen 2015, vol. 4, pp. 418–437

	Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang Direct Growth of NiCo₂S₄ Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper] ChemPlusChem 2014, vol. 79, pp. 577–583

	Francisco Trespalacios, Ignacio E. Grossmann Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review] Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

	Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86

	Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127

	Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview] Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

	Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp²)–H Bonds [Focus Review] Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

	Derong Cao, Herbert Meier Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review] Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

	Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann Bromodomains and Their Pharmacological Inhibitors [Review] ChemMedChem 2014, vol. 9, pp. 438–464

	Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera The Bright Future of Unconventional σ/π-Hole Interactions [Review] ChemPhysChem 2015, vol. 16, pp. 2496–2517

	Ksenia S. Egorova, Valentine P. Ananikov Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review] ChemSusChem 2014, vol. 7, pp. 336–360

	Shunichi Fukuzumi, Dachao Hong Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview] Eur. J. Inorg. Chem. 2014, pp. 645–659

	Fabien Toulgoat, Sébastien Alazet, Thierry Billard Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview] Eur. J. Org. Chem. 2014, pp. 2415–2428

	David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar Mit Klick zu neuen Liganden [Magazin] Nachr. Chem. 2011, vol. 59, pp. 937–941