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Advanced Synthesis & Catalysis

Enantiopure Chiral Phosphines Bearing a Sulfinyl Group and their Application in Catalytic Enantiodivergent Synthesis of Polysubstituted Pyrrolines

Published: 26 May 2020

Author(s): Hanyuan Li, Bojuan Li, Jianwei Zeng, Changzun Jiang, Zhengjie He

Abstract In this work, a type of enantiopure chiral phosphines bearing a polar S=O sulfinyl group as the chiral unit in the molecule has been developed, which can be prepared in either enantiomeric form from commercially available materials by a three‐step route. The enantiopure chiral phosphines can catalyse enantiodivergent asymmetric [4+1] annulation reactions of α,β‐unsaturated imines and allylic carbonates, delivering polysubstituted pyrrolines in either enantiomeric form in up to 99%...

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ChemBioChem

Monitoring Dicer‐Mediated miRNA‐21 Maturation and Ago2 Loading by a Dual‐Colour FIT PNA Probe Set

Published: 26 May 2020

Author(s): Natalia Loibl, Christoph Arenz, Oliver Seitz

Abstract The inhibition of micro RNA (miRNA) maturation by Dicer and loading matured miRNAs into the RNA‐induced silencing complex (RISC) is envisioned as a modality for treatment of cancer. Existing methods for evaluating maturation either focus on the conversion of modified precursors or detect mature miRNA. Whereas the former is not applicable to native pre‐miRNA, the latter approach underestimates maturation when both nonmatured and matured miRNA molecules are subject to cleavage. We...

Advanced Synthesis & Catalysis

Photocatalyzed Amidoarylation of 1,3‐Butadiene

Published: 26 May 2020

Author(s): Cyrille Gosset, Aurélien Moncomble, Clément Dumont, Sylvain Pellegrini, Till Bousquet, Mathieu Sauthier, Lydie Pélinski

Abstract 1,3‐Butadiene is involved in a photocatalyzed amidoarylation reaction that allows the synthesis of N‐allyl amides. The reaction was evaluated on a wide range of aryl diazonium salts and nitriles as co‐reactants. Selectivity issues were studied from the help of a computational approach.

Chemie Ingenieur Technik - CIT

Hybrid Semi‐parametric Modeling in Separation Processes: A Review

Published: 26 May 2020

Author(s): Kevin McBride, Edgar Ivan Sanchez Medina, Kai Sundmacher

Abstract Separations of mixtures play a critical role in chemical industries. Over the last century, the knowledge in the area of chemical thermodynamics and modeling of separation processes has been substantially expanded. Since the models are still not completely accurate, hybrid models can be used as an alternative that allows to retain existing knowledge and augment it using data. This paper explores some of the weaknesses in the current knowledge in separations design, simulation,...

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Journal of Forensic Sciences

Women and Men who Committed Murder: Male/Female Psychopathic Homicides

Published: 26 May 2020

Author(s): Felice Carabellese, Alan R. Felthous, Gabriele Mandarelli, Domenico Montalbò, Donatella La Tegola, Giovanna Parmigiani, Ilaria Rossetto, Filippo Franconi, Fabio Ferretti, Fulvio Carabellese, Roberto Catanesi

Abstract The present study was designed to compare gender differences in psychiatric diagnosis with the dimension of psychopathy in women and men who had attempted or committed homicide. The study samples consisted of 39 homicidal females and 48 homicidal males who were confined in one of Italy’s REMS or prison facilities in two southern provinces of Italy (Puglia and Basilicata). Assessment instruments included the SCID‐5, the PID‐5 IRF, and the PCL‐R. Each gender group was stratified...

Journal of Forensic Sciences

Detection of Mitragynine in Mitragyna Speciosa (Kratom) Using Surface‐Enhanced Raman Spectroscopy with Handheld Devices

Published: 26 May 2020

Author(s): Adam Lanzarotta, Michael D. Thatcher, Lisa M. Lorenz, JaCinta S. Batson

Abstract A simple, quick, selective, sensitive, and effective field‐friendly method capable of being used by nonexperts has been developed for detecting mitragynine in Mitragyna speciosa (kratom) using surface‐enhanced Raman spectroscopy (SERS). Over 100 samples and blanks (known to be either positive or negative for the presence of mitragynine) were examined in duplicate using five identical handheld Raman spectrometers, which provided a data set of over 1,000 examinations. Based on the...

Journal of Food Processing and Preservation

Production and characterization of edible film based on gelatin–chitosan containing Ferulago angulate essential oil and its application in the prolongation of the shelf life of turkey meat

Published: 26 May 2020

Author(s): Hamid Reza Naseri, Faranak Beigmohammadi, Reza Mohammadi, Ehsan Sadeghi

Abstract Plant essential oils have been recognized as valid alternatives to synthetic food additives due to their proved antimicrobial functions. The film in this study was prepared by the casting technique using a gelatin–chitosan blend containing different concentrations of Ferulago Angulate Essential Oil (FAEO) to examine its antibacterial, physical, and mechanical properties. Scanning Electron Microscopy (SEM) was carried out to explain the structure–property relationships. Incorporating...

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Advanced Functional Materials

Cation Exchange Protocols to Radiolabel Aqueous Stabilized ZnS, ZnSe, and CuFeS2 Nanocrystals with 64Cu for Dual Radio‐ and Photo‐Thermal Therapy

Published: 26 May 2020

Author(s): Tommaso Avellini, Nisarg Soni, Niccolò Silvestri, Sergio Fiorito, Francesco De Donato, Claudia De Mei, Martin Walther, Marco Cassani, Sandeep Ghosh, Liberato Manna, Holger Stephan, Teresa Pellegrino

Abstract Here, cation exchange (CE) reactions are exploited to radiolabel ZnSe, ZnS, and CuFeS2 metal chalcogenide nanocrystals (NCs) with 64Cu. The CE protocol requires one simple step, to mix the water‐soluble NCs with a 64Cu solution, in the presence of vitamin C used to reduce Cu(II) to Cu(I). Given the quantitative cation replacement on the NCs, a high radiochemical yield, up to 99%, is reached. Also, provided that there is no free 64Cu, no purification step is needed, making the protocol...

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Advanced Materials

Engineering Co2MnAlxSi1−x Heusler Compounds as a Model System to Correlate Spin Polarization, Intrinsic Gilbert Damping, and Ultrafast Demagnetization

Published: 26 May 2020

Author(s): Charles Guillemard, Wei Zhang, Gregory Malinowski, Claudia de Melo, Jon Gorchon, Sebastien Petit‐Watelot, Jaafar Ghanbaja, Stéphane Mangin, Patrick Le Fèvre, Francois Bertran, Stéphane Andrieu

Abstract Engineering of magnetic materials for developing better spintronic applications relies on the control of two key parameters: the spin polarization and the Gilbert damping, responsible for the spin angular momentum dissipation. Both of them are expected to affect the ultrafast magnetization dynamics occurring on the femtosecond timescale. Here, engineered Co2MnAlxSi1‐x Heusler compounds are used to adjust the degree of spin polarization at the Fermi energy, P, from 60% to 100% and to...

Advanced Functional Materials

Ionically Generated Built‐In Equilibrium Space Charge Zones—a Paradigm Change for Lead Halide Perovskite Interfaces

Published: 26 May 2020

Author(s): Gee Yeong Kim, Alessandro Senocrate, Davide Moia, Joachim Maier

Abstract Methylammonium lead iodide (MAPI) is the archetype of the intensively researched class of perovskites for photovoltaics. Nonetheless, even equilibrium aspects are far from being fully understood. Equilibrium space charge effects at the MAPI/TiO2 and MAPI/Al2O3 interfaces are discussed, which are of paramount significance for solar cells. Different from the photovoltaic literature in which such built‐in potentials are considered as being generated solely by electronic charge carriers,...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

January 2020


	Hendrik Naatz, Bella B. Manshian, Carla Rios Luci, Vasiliki Tsikourkitoudi, Yiannis Deligiannakis, Johannes Birkenstock, Suman Pokhrel, Lutz Mädler, Stefaan J. Soenen Model-Based Nanoengineered Pharmacokinetics of Iron-Doped Copper Oxide for Nanomedical Applications [Research Article] Angew. Chem. Int. Ed. 2020, vol. 59, no. 5, p. 1828

	Marc-André Kasper, Marcus Gerlach, Anselm F. L. Schneider, Christiane Groneberg, Philipp Ochtrop, Stefanie Boldt, Dominik Schumacher, Jonas Helma, Heinrich Leonhardt, Mathias Christmann, Christian P. R. Hackenberger N-Hydroxysuccinimide-Modified Ethynylphosphonamidates Enable the Synthesis of Configurationally Defined Protein Conjugates [Full Paper] ChemBioChem 2020, vol. 21, no. 1-2, p. 113

	Michael Bowker Methanol Synthesis from CO₂ Hydrogenation [Minireview] ChemCatChem 2019, vol. 11, no. 17, p. 4238

	V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article] Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

	Dieter Wöhrle Kunststoffe [Artikel] Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 50

	Balaram Mukhopadhyay, Rituparna Das Chemical O-Glycosylations: An Overview [Review] ChemistryOpen 2016, vol. 5, no. 5, p. 401

	Daewoo Han, Andrew J. Steckl Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review] ChemPlusChem 2019, vol. 84, no. 10, p. 1453

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055

	Rüdiger-A. Eichel, Walter Leitner, Kurt Wagemann Warum wir uns mit Power-to-X beschäftigen [Editorial] Chem. Ing. Tech. 2020, vol. 92, no. 1-2, p. 3

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

	Gerhard Hilt Basic Strategies and Types of Applications in Organic Electrochemistry [Concept] ChemElectroChem 2020, vol. 7, no. 2, p. 395

	Claire M. Cobley Introducing our Inaugural Early Career Advisory Board [Editorial] ChemNanoMat 2020, vol. 6, no. 1, p. 4

	Felix Blei, Sebastian Dörner, Janis Fricke, Florian Baldeweg, Felix Trottmann, Anna Komor, Florian Meyer, Christian Hertweck, Dirk Hoffmeister Simultaneous Production of Psilocybin and a Cocktail of β-Carboline Monoamine Oxidase Inhibitors in “Magic” Mushrooms [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 3, p. 729

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

	Arun K. Sinha, Danish Equbal Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review] Asian J. Org. Chem. 2019, vol. 8, no. 1, p. 32

	Thomas H. Pillow, Pragya Adhikari, Robert A. Blake, Jinhua Chen, Geoffrey Del Rosario, Gauri Deshmukh, Isabel Figueroa, Karen E. Gascoigne, Amrita V. Kamath, Susan Kaufman, Tracy Kleinheinz, Katherine R. Kozak, Brandon Latifi, Douglas D. Leipold, Chun Sing Li, Ruina Li, Melinda M. Mulvihill, Aimee O'Donohue, Rebecca K. Rowntree, Jack D. Sadowsky, John Wai, Xinxin Wang, Cong Wu, Zijin Xu, Hui Yao, Shang-Fan Yu, Donglu Zhang, Richard Zang, Hongyan Zhang, Hao Zhou, Xiaoyu Zhu, Peter S. Dragovich Antibody Conjugation of a Chimeric BET Degrader Enables in vivo Activity [Full Paper] ChemMedChem 2020, vol. 15, no. 1, p. 17

	Vitali Tugarinov, Theodoros K. Karamanos, Alberto Ceccon, G. Marius Clore Optimized NMR Experiments for the Isolation of I=1/2 Manifold Transitions in Methyl Groups of Proteins [Communication] ChemPhysChem 2020, vol. 21, no. 1, p. 13

	Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review] ChemPhotoChem 2018, vol. 2, no. 5, p. 386

	Kassem Beydoun, Jürgen Klankermayer Efficient Plastic Waste Recycling to Value-Added Products by Integrated Biomass Processing [Communication] ChemSusChem 2020, vol. 13, no. 3, p. 488

	Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief The Periodic Table of the Chemical Elements and Sustainable Development [Essay] Eur. J. Inorg. Chem. 2019, p. 4170

	Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056

	Cover Picture Lebensmittelchemie 6/2019 [Cover Picture] Lebensmittelchemie 2019, vol. 73, no. 6

	Christian Hering-Junghans, Christian Sindlinger Trendbericht Anorganische Chemie: Hauptgruppen [Wissenschaft + Forschung] Nachr. Chem. 2020, vol. 68, no. 1, p. 50

	Jana Novotny, Corina Wagner, Marco Oetken Titelbild: Elektrochemisch aktive Polymere am Beispiel Polypyrrol: Modellsystem einer künstlichen Synapse Ein elektrochemischer Alleskönner - Teil 2 (CHEMKON 8/2019) [Titelbild] CHEMKON 2019, vol. 26, no. 8, p. 331

	Meng Cheng, Ramasubramonian Deivanayagam, Reza Shahbazian-Yassar 3D Printing of Electrochemical Energy Storage Devices: A Review of Printing Techniques and Electrode/Electrolyte Architectures [Review] Batteries & Supercaps 2020, vol. 3, no. 2, p. 130

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from Chemistry Europe, ACES, and GDCh journals

Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.


	Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication] Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

	Lik Hang Yuen, Raphael M. Franzini Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview] ChemBioChem 2017, vol. 18, pp. 829–836

	Konstantinos C. Christoforidis, Paolo Fornasiero Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review] ChemCatChem 2017, vol. 9, pp. 1523–1544

	Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview] ChemistryOpen 2018, vol. 7, pp. 169–179

	Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, pp. 945–956

	Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe₃O₄@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826

	Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication] ChemElectroChem 2017, vol. 4, pp. 1840–1845

	Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper] ChemNanoMat 2017, vol. 3, pp. 328–335

	Chengwei Liu, Michal Szostak Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview] Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

	Jian Shu, Dianping Tang Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review] Chem. Asian J. 2017, vol. 12, pp. 2780–2789

	Jian Rong, Chuanfa Ni, Jinbo Hu Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review] Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

	Juan Alberto Sirvent, Ulrich Lücking Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper] ChemMedChem 2017, vol. 12, pp. 487–501

	Grzegorz Greczynski, Lars Hultman C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication] ChemPhysChem 2017, vol. 18, pp. 1507–1512

	Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept] ChemPhotoChem 2017, vol. 1, pp. 148–158

	Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication] ChemSusChem 2017, vol. 10, pp. 87–90

	Enzo Alessio Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview] Eur. J. Inorg. Chem. 2017, pp. 1549–1560

	Marcel Garbe, Kathrin Junge, Matthias Beller Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview] Eur. J. Org. Chem. 2017, pp. 4344–4362

	Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review] Batteries Supercaps 2018, vol. 1, pp. 41–68

	Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe₃O₄@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826