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Chemistry - A European Journal
Enantioselective Acyl Migration Reactions of Furanyl Carbonates with Chiral DMAP Derivatives
Published: 16 January 2019
Author(s): Kazuki Fujii, Koichi Mitsudo, Hiroki Mandai, Toshinobu Korenaga, Seiji Suga
Abstract An efficient enantioselective acyl migration reaction of furanyl carbonates was developed to construct all‐carbon quaternary stereogenic centers. In some cases, the reactions required only 0.05 mol % (minimum 500 ppm) of catalyst and showed a high turnover frequency value (TOF; 3640 h−1). Multigram‐scale reactions (10 grams) also proceeded with high enantioselectivity ( 99:1 e.r.) in quantitative yield. The catalyst was robust and easily recovered in 98 % yield. A wide range of...
Chemistry - A European Journal
Published: 16 January 2019
Author(s): Matthias Lischka, Renhao Dong, Mingchao Wang, Natalia Martsinovich, Massimo Fritton, Lukas Grossmann, Wolfgang M. Heckl, Xinliang Feng, Markus Lackinger
Abstract The interplay between the self‐assembly and surface chemistry of 2,3,6,7,10,11‐hexaaminotriphenylene (HATP) on Cu(111) was complementarily studied by high‐resolution scanning tunneling microscopy (STM) and X‐ray photoelectron spectroscopy (XPS) under ultra‐high vacuum conditions. To shed light on the competitive metal coordination, comparative experiments were carried out on pristine and nickel‐covered Cu(111). Directly after room‐temperature deposition of HATP onto pristine Cu(111),...
Chemistry - A European Journal
A Practical General Method for the Preparation of Long Acenes
Published: 16 January 2019
Author(s): Andrej Jancarik, Gaspard Levet, André Gourdon
Abstract The field of long acenes, the narrowest of the zig‐zag graphene nanoribbons, has been an area of significant interest in the past decade because of its potential applications in organic electronics, spintronics and plasmonics. However the low solubility and high reactivity of these compounds has so far hindered their preparation on large scales. We report here a concise strategy for the synthesis of higher acenes through Diels–Alder condensation of arynes with a protected tetraene...
Journal of the American Ceramic Society
Large strain under low driving field in lead‐free relaxor/ferroelectric composite ceramics
Published: 16 January 2019
Author(s): Pengyuan Fan, Yangyang Zhang, Yiwei Zhu, Weigang Ma, Kai Liu, Xueting He, Mohsin Ali Marwat, Bing Xie, Ming Li, Haibo Zhang
Abstract 0.75(Na0.5Bi0.5)TiO3–0.25SrTiO3 lead‐free incipient piezoceramic is a promising candidate for actuator applications due to their large reversible electromechanical strains at the relatively low driving field of 40 kV/cm. In order to further reduce the driving field of 0.75(Na0.5Bi0.5)TiO–0.25SrTiO3 relaxor ceramic to meet the requirements for real actuators application, the relaxor/ferroelectric (RE/FE) 0‐3 composite ceramics method was employed. The polarization and strain behaviors...
Journal of the American Ceramic Society
Published: 16 January 2019
Author(s): Ronaldo C. Gennari, Rossano Lang, José A. Eiras, Manuel H. Lente
Abstract The influence of the sintering temperature and the dwell time on the structural, optical, and dielectric properties of [KNbO3]0.8[Ba(Ni0.5Nb0.5)O3−δ]0.2 ceramics (KBNNO) was systematically investigated. X‐ray diffraction measurements of the ceramic bodies sintered at different temperatures indicated that all samples presented a cubic‐like structure. However, the results remarkably revealed that both the sintering temperature and the dwell time are crucial factors that must be taken...
Chemistry - An Asian Journal
Published: 16 January 2019
Author(s): Jian Bao, Wenjun Liu, Junfeng Xie, Li Xu, Meili Guan, Fengcai Lei, Yan Zhao, Yunpeng Huang, Jiexiang Xia, Huaming Li
Abstract Developing highly active, stable and robust electrocatalysts based on earth‐abundant elements for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is important for many renewable energy conversion processes. Herein, NixCo3‐xO4 nanoneedle arrays grown on 3D porous nickel foam (NF) was synthesized as a bifunctional electrocatalyst with OER and HER activity for full water splitting. Benefiting from the advantageous structure, the composite exhibits superior OER...
Chemistry - An Asian Journal
Published: 16 January 2019
Author(s): Mizuho Kondo, Taku Yamoto, Seiya Miura, Mayuko Hashimoto, Chitoshi Kitamura, Nobuhiro Kawatsuki
Pest Management Science
Mixed effects of landscape complexity and insecticide use on ladybeetle abundance in wheat fields
Published: 16 January 2019
Author(s): Long Yang, Qian Zhang, Bing Liu, Yingda Zeng, Yunfei Pan, Minlong Li, Yanhui Lu
Abstract BACKGROUND Although the abundance of insect natural enemies in crop fields may be influenced by the surrounding landscape and local field management, particularly insecticide use at the local scale, few studies have examined these factors simultaneously. In this study, we investigated the effects of landscape context and insecticide use in local fields on ladybeetle abundance in wheat fields in northern China. RESULTS Woodlots and fallow land were the most important landscape...
Journal of the American Ceramic Society
Published: 16 January 2019
Author(s): Ping Zhang, Kexin Sun, Mi Xiao, Zhentai Zheng
Abstract A novel system Li3Mg2(Nb(1−x)Mox)O6+x/2 (0 ≤ x ≤ 0.08) microwave dielectric ceramics were fabricated by the solid‐state method. The charge compensation of Mo6+ ions substitution for Nb5+ ions was performed by introducing oxygen ions. The X‐ray diffraction patterns and Rietveld refinements indicated Li3Mg2(Nb(1−x)Mox)O6+x/2 ceramics with single phase and orthorhombic structure. Micro‐structure and density confirmed that the grain of Li3Mg2(Nb(1‐x)Mox)O6+x/2 ceramics grew well. In...
Journal of the American Ceramic Society
Chemical equilibrium analysis of silicon carbide oxidation in oxygen and air
Published: 16 January 2019
Author(s): Samuel Y. Chen, Iain D. Boyd
Abstract Due to their refractory nature and oxidation resistance, Ultra‐High Temperature Ceramic materials, including silicon carbide, are of interest in hypersonic aerospace applications. To analyze the thermodynamic behavior of silicon carbide during transition between passive and active oxidation states, chemical equilibrium calculations are performed. The predicted oxygen pressures for passive‐to‐active transition show improved agreement up to an order of magnitude with experimental...
Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal
September 2018
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Runze Mao, Jonathan Balon, Xile Hu Decarboxylative C(sp3)−O Cross-Coupling [Communication] Angew. Chem. Int. Ed. 2018, vol. 57, p. 13624 |
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Klaus F. Wagenbauer, Floris A. S. Engelhardt, Evi Stahl, Vera K. Hechtl, Pierre Stömmer, Fabian Seebacher, Letizia Meregalli, Philip Ketterer, Thomas Gerling, Hendrik Dietz How We Make DNA Origami [Concept] ChemBioChem 2017, vol. 18, p. 1873 |
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Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper] ChemCatChem 2011, vol. 3, p. 1159 |
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Matthias Epple, Joachim Enax Moderne Zahnpflege aus chemischer Sicht [Artikel] Chem. Unserer Zeit 2018, vol. 52, p. 218 |
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Balaram Mukhopadhyay, Rituparna Das Chemical O-Glycosylations: An Overview [Review] ChemistryOpen 2016, vol. 5, p. 401 |
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Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang Chemical Sensors Based on Metal-Organic Frameworks [Review] ChemPlusChem 2016, vol. 81, p. 675 |
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Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, p. 6055 |
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Peter Buchholz, Torsten Brandenburg Demand, Supply, and Price Trends for Mineral Raw Materials Relevant to the Renewable Energy Transition Wind Energy, Solar Photovoltaic Energy, and Energy Storage [Review] Chem. Ing. Tech. 2018, vol. 90, p. 141 |
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Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, p. 75 |
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Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review] ChemElectroChem 2018, vol. 5, p. 6 |
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Hejin Jiang, Li Zhang, Minghua Liu Self-Assembly of 1D Helical Nanostructures into Higher Order Chiral Nanostructures in Supramolecular Systems [Focus Review] ChemNanoMat 2018, vol. 4, p. 720 |
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Sa Xiao, Yi Lu, Xin Li, Bing-Yu Xiao, Liang Wu, Jian-Ping Song, Yu-Xuan Xiao, Si-Ming Wu, Jie Hu, Yong Wang, Gang-Gang Chang, Ge Tian, Silvia Lenaerts, Christoph Janiak, Xiao-Yu Yang, Bao-Lian Su Hierarchically Dual-Mesoporous TiO2 Microspheres for Enhanced Photocatalytic Properties and Lithium Storage [Full Paper] Chem. Eur. J. 2018, vol. 24, p. 13246 |
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Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, p. 2696 |
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Michael C. Willis, Edward J. Emmett The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry [Focus Review] Asian J. Org. Chem. 2015, vol. 4, p. 602 |
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Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper] ChemMedChem 2018, vol. 13, p. 988 |
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Gloria Tabacchi Supramolecular Organization in Confined Nanospaces [Review] ChemPhysChem 2018, vol. 19, p. 1249 |
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Baokun Qiao, Zhiyong Jiang Catalytic Photoreduction Induced by Visible Light [Minireview] ChemPhotoChem 2018, vol. 2, p. 703 |
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Xinyue Zhang, Mingyue Jiang, Na Niu, Zhijun Chen, Shujun Li, Shouxin Liu, Jian Li Natural-Product-Derived Carbon Dots: From Natural Products to Functional Materials [Review] ChemSusChem 2018, vol. 11, p. 11 |
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Ross J. Marshall, Ross S. Forgan Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview] Eur. J. Inorg. Chem. 2016, p. 4310 |
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Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056 |
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Cover Picture Lebensmittelchemie 4/2018 [Cover Picture] Lebensmittelchemie 2018, vol. 72 |
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Thomas U. Probst Umbrüche beim Kunststoffrecycling [Industrie & Technik] Nachr. Chem. 2018, vol. 66, p. 868 |
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Alexander Engl, Alexandra Schmelzer, Björn Risch Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel] CHEMKON 2018, vol. 25, p. 7 |
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Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016 |
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Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal
2017
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Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430 |
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Philippe Compain, Anne Bodlenner The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview] ChemBioChem 2014, vol. 15, pp. 1239–1251 |
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Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75 |
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Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14 |
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Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez Gated Silica Mesoporous Materials in Sensing Applications [Review] ChemistryOpen 2015, vol. 4, pp. 418–437 |
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Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper] ChemPlusChem 2014, vol. 79, pp. 577–583 |
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Francisco Trespalacios, Ignacio E. Grossmann Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review] Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012 |
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Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86 |
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Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127 |
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Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview] Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886 |
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Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review] Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47 |
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Derong Cao, Herbert Meier Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review] Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262 |
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Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann Bromodomains and Their Pharmacological Inhibitors [Review] ChemMedChem 2014, vol. 9, pp. 438–464 |
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Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera The Bright Future of Unconventional σ/π-Hole Interactions [Review] ChemPhysChem 2015, vol. 16, pp. 2496–2517 |
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Ksenia S. Egorova, Valentine P. Ananikov Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review] ChemSusChem 2014, vol. 7, pp. 336–360 |
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Shunichi Fukuzumi, Dachao Hong Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview] Eur. J. Inorg. Chem. 2014, pp. 645–659 |
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Fabien Toulgoat, Sébastien Alazet, Thierry Billard Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview] Eur. J. Org. Chem. 2014, pp. 2415–2428 |
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David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar Mit Klick zu neuen Liganden [Magazin] Nachr. Chem. 2011, vol. 59, pp. 937–941 |
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