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Chemistry - A European Journal
NMR Crystallography Reveals Carbonate Induced Al‐Ordering in ZnAl Layered Double Hydroxide
Published: 25 October 2021
Author(s): Sambhu Radhakrishnan, Karl Lauwers, C. Vinod Chandran, Julien Trébosc, Sreeprasanth Pulinthanathu Sree, Johan A. Martens, Francis Taulelle, Christine E. A. Kirschhock, Eric Breynaert
Abstract Layered double hydroxides (LDHs) serve a score of applications in catalysis, drug delivery, and environmental remediation. Smarter crystallography, combining X‐ray diffraction and NMR spectroscopy revealed how interplay between carbonate and pH determines the LDH structure and Al ordering in ZnAl LDH. Carbonate intercalated ZnAl LDHs were synthesized at different pH (pH 8.5, pH 10.0, pH 12.5) with a Zn/Al ratio of 2, without subsequent hydrothermal treatment to avoid extensive...
Advanced Synthesis & Catalysis
Published: 25 October 2021
Author(s): Chen Chen, Jie Ding, Liying Liu, Yujie Huang, Bolin Zhu
Abstract We presented a palladium‐catalyzed domino cyclization/phosphorylation of gem‐dibromoolefins, which utilize H‐phosphinates and secondary phosphine oxides as the phosphine sources, respectively. A variety of phosphorylated heteroaromatics were obtained in moderate to good yields with wide functional group compatibility. This one‐pot reaction enables multiple bond‐forming events including C−X (X=O, N, S) and C−P bonds using easily available starting materials. Moreover, this protocol can...
Angewandte Chemie
Published: 25 October 2021
Author(s): Lei Huang, Ya‐Qiong Su, Shibo Xi, Shahid Zaman, Bo You, Shujiang Ding, Bao Yu Xia, Yanyang Qin, Dai Dang, Ruijuan Qi
Abstract Integrated fabrication through the strong interaction between catalyst and carrier is crucial to realize efficient oxygen electrocatalysis for fuel cells. We report herein a porous Pt‐rich alloy encapsulated by graphitic carbon via integration engineering, where a synergistic catalysis between ternary PtCuCo alloy and graphitic Co‐N‐C results in the optimized reaction pathway and improved oxygen reduction reaction (ORR) performance. The hybrid catalyst [email protected]‐N‐C delivers a mass...
PROTEOMICS
Insights from tissue “omics” analysis on intestinal remodeling in celiac disease
Published: 25 October 2021
Author(s): Jorunn Stamnaes
Abstract Celiac disease (CeD) is a prevalent intestinal disorder that only develops in genetically susceptible individuals when they mount a harmful CD4+ T‐cell response towards gluten peptides. Intake of gluten leads to inflammation and remodeling of the small intestine with symptoms such as nausea and diarrhea. The only current treatment is a lifelong gluten free diet. The immunological basis for CeD is well characterized but the mechanisms that drive intestinal remodeling are still poorly...
Angewandte Chemie International Edition
Published: 25 October 2021
Author(s): Yongfang Sun, Yunlei Chen, Xiangyu Zhang, Yurong He, Zhongxian Qiu, Wentao Zheng, Fei Wang, Haijun Jiao, Yong Yang, Yongwang Li, Xiaodong Wen
Abstract In catalysis science, the electronic structure of the active site determines the structure–activity relationship of the catalyst to a large extent. Therefore, modulating the electronic structure has become a main route for the rational design of metal‐based catalyst materials. In this work, we prepared a LaCoSiHx material that has more electronegativity and a lower workfunction than traditional supported Co‐based catalysts. Using CO2 methanation as a model catalytic reaction, the...
Advanced Synthesis & Catalysis
Published: 25 October 2021
Author(s): Deepa Rawat, Subbarayappa Adimurthy
Abstract Ruthenium catalysed denitrogenative transannulation of pyridotriazoles with naphthoquinones provided the transannulated benzo[f]pyrido[1,2‐a]indoles derivatives in good to excellent yields. While pyridotriazoles with indoles in presence of PivOH and oxone yield indolizino[3,2‐b]indoles under metal‐free conditions. Quinone annulation proceeds through ruthenium‐carbenoid intermediate while indole annulation may proceed via a diazo‐pyridinium intermediate. Control experiments suggest...
Angewandte Chemie
Published: 25 October 2021
Author(s): Yongfang Sun, Yunlei Chen, Xiangyu Zhang, Yurong He, Zhongxian Qiu, Wentao Zheng, Fei Wang, Haijun Jiao, Yong Yang, Yongwang Li, Xiaodong Wen
Abstract In catalysis science, the electronic structure of the active site determines the structure–activity relationship of the catalyst to a large extent. Therefore, modulating the electronic structure has become a main route for the rational design of metal‐based catalyst materials. In this work, we prepared a LaCoSiHx material that has more electronegativity and a lower workfunction than traditional supported Co‐based catalysts. Using CO2 methanation as a model catalytic reaction, the...
Angewandte Chemie International Edition
Fatigue‐Resistant Interfacial Layer for Safe Lithium Metal Batteries
Published: 25 October 2021
Author(s): Rui‐Min Gao, Hua Yang, Cao‐Yu Wang, Huan Ye, Fei‐Fei Cao, Zai‐Ping Guo
Abstract The plating/stripping of Li dendrites can fracture the static solid electrolyte interphase (SEI) and cause significant dynamic volume variations in the Li anode, which give rise to poor cyclability and severe safety hazards. Herein, a tough polymer with a slide‐ring structure was designed as a self‐adaptive interfacial layer for Li anodes. The slide‐ring polymer with a dynamically crosslinked network moves freely while maintaining its toughness and fracture resistance, which allows it...
Chemie Ingenieur Technik - CIT
Evaluation von Sicherheitslebenszyklusmodellen in der modularen Automation
Published: 25 October 2021
Author(s): Florian Pelzer, Sebastian Pannasch, Leon Urbas
Abstract The dynamic interconnection of modular plants contradicts static paradigms of functional safety originating from conventional plant engineering. An adaptation of the safety lifecycle models developed for conventional plant engineering is therefore necessary in order to be able to represent the aspects of flexible interconnection of plants. This paper describes the development and evaluation of safety lifecycles in the context of focus group workshops for Process Equipment Assemblies...
Angewandte Chemie International Edition
Published: 25 October 2021
Author(s): Lei Huang, Ya‐Qiong Su, Ruijuan Qi, Dai Dang, Yanyang Qin, Shibo Xi, Shahid Zaman, Bo You, Shujiang Ding, Bao Yu Xia
Abstract Integrated fabrication through the strong interaction between catalyst and carrier is crucial to realize efficient oxygen electrocatalysis for fuel cells. We report herein a porous Pt‐rich alloy encapsulated by graphitic carbon via integration engineering, where a synergistic catalysis between ternary PtCuCo alloy and graphitic Co‐N‐C results in the optimized reaction pathway and improved oxygen reduction reaction (ORR) performance. The hybrid catalyst [email protected]‐N‐C delivers a mass...
Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal
September 2021
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Fang Zhang, Juewen Liu Label-Free Colorimetric Biosensors Based on Aptamers and Gold Nanoparticles: A Critical Review [Review] Anal. Sens. 2021, vol. 1, no. 1, p. 30 |
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Rola Houhou, Thomas Bocklitz Trends in artificial intelligence, machine learning, and chemometrics applied to chemical data [Review] Anal. Sci. Adv. 2021, vol. 2, no. 3-4, p. 128 |
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Alana Zülke, Yi Li, Peter Keil, Robert Burrell, Sacha Belaisch, Mangayarkarasi Nagarathinam, Michael P. Mercer, Harry E. Hoster High-Energy Nickel-Cobalt-Aluminium Oxide (NCA) Cells on Idle: Anode- versus Cathode-Driven Side Reactions [Article] Batteries Supercaps 2021, vol. 4, no. 6, p. 934 |
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Kim Bartels, Tanya Lasitza-Male, Hagen Hofmann, Christian Löw Single-Molecule FRET of Membrane Transport Proteins [Minireview] ChemBioChem 2021, vol. 22, no. 17, p. 2657 |
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Christian M. Heckmann, Francesca Paradisi Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review] ChemCatChem 2020, vol. 12, no. 24, p. 6082 |
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Pooja Vadhva, Ji Hu, Michael J. Johnson, Richard Stocker, Michele Braglia, Dan J. L. Brett, Alexander J. E. Rettie Electrochemical Impedance Spectroscopy for All-Solid-State Batteries: Theory, Methods and Future Outlook [Review] ChemElectroChem 2021, vol. 8, no. 11, p. 1930 |
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Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837 |
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Trishna Rajbongshi, Kashyap Kumar Sarmah, Ramesh Ganduri, Suryanarayan Cherukuvada, Mihails Arhangelskis, Ranjit Thakuria Cover Feature: Mechanosynthesis of Eutectics of Anti-Inflammatory Drug Ethenzamide - A Comparison with Analogous Cocrystals (Chemistry - Methods 9/2021) [Cover Picture] Chem. Methods 2021, vol. 1, no. 9, p. 398 |
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Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication] ChemistryOpen 2020, vol. 9, no. 7, p. 743 |
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Jelena Đorović Jovanović, Marko Antonijević, Ali A. El-Emam, Zoran Marković Comparative MD Study of Inhibitory Activity of Opaganib and Adamantane-Isothiourea Derivatives toward COVID-19 Main Protease Mpro [Full Paper] ChemistrySelect 2021, vol. 6, no. 33, p. 8603 |
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Antoine Daina, Vincent Zoete A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication] ChemMedChem 2016, vol. 11, no. 11, p. 1117 |
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Thomas D. Svejstrup, Anamitra Chatterjee, Denis Schekin, Thomas Wagner, Julia Zach, Magnus J. Johansson, Giulia Bergonzini, Burkhard König Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors [Communication] ChemPhotoChem 2021, vol. 5, no. 9, p. 808 |
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Thomas G. Mayerhöfer, Susanne Pahlow, Jürgen Popp The Bouguer-Beer-Lambert Law: Shining Light on the Obscure [Review] ChemPhysChem 2020, vol. 21, no. 18, p. 2029 |
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Giuseppe Zuccarello, Imma Escofet, Ulysse Caniparoli, Antonio M. Echavarren New-Generation Ligand Design for the Gold-Catalyzed Asymmetric Activation of Alkynes [Minireview] ChemPlusChem 2021, vol. 86, no. 9, p. 1283 |
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Layla Filiciotto, Gadi Rothenberg Biodegradable Plastics: Standards, Policies, and Impacts [Review] ChemSusChem 2021, vol. 14, no. 1, p. 56 |
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Marleen H. M. E. Stevendaal, Jan C. M. Hest, Alexander F. Mason Functional Interactions Between Bottom-Up Synthetic Cells and Living Matter for Biomedical Applications [Review] ChemSystemsChem 2021, vol. 3, eLoc. e2100009 |
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Wolfgang Jud, C. Oliver Kappe, David Cantillo One-pot multistep electrochemical strategy for the modular synthesis of epoxides, glycols, and aldehydes from alkenes [Full article] Electrochem. Sci. Adv. 2021, vol. 1, eLoc. e2100002 |
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Silène Engbers, Evgeniya A. Trifonova, Kristopher M. Hess, Folkert Vries, Johannes E. M. N. Klein Synthesis of a Sterically Encumbered Pincer Au(III)−OH Complex [Communication] Eur. J. Inorg. Chem. 2021, p. 3561 |
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Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056 |
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Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemistryViews 2016 |
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Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper] Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636 |
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Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696 |
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B. Lilli Neumeier, Mikhail Khorenko, Frauke Alves, Oliver Goldmann, Joanna Napp, Ute Schepers, Holger M. Reichardt, Claus Feldmann Fluorescent Inorganic-Organic Hybrid Nanoparticles [Focus Review] ChemNanoMat 2019, vol. 5, no. 1, p. 24 |
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Xinlan A. F. Cook, Loïc R. E. Pantaine, David C. Blakemore, Ian B. Moses, Neal W. Sach, Andre Shavnya, Michael C. Willis Base-Activated Latent Heteroaromatic Sulfinates as Nucleophilic Coupling Partners in Palladium-Catalyzed Cross-Coupling Reactions [Research Article] Angew. Chem. Int. Ed. 2021, vol. 60, no. 41, p. 22461 |
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Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75 |
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Özge Çepelioğullar Mutlu, Thomas Zeng Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A Review [Review] Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674 |
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Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review] Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596 |
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Martin Witt, Christopher Heuer, Lina Miethke, John-Alexander Preuß, Johanna Sophie Rehfeld, Torsten Schüling, Cornelia Blume, Stefanie Thoms, Frank Stahl Nachweismethoden von SARS-CoV-2 [Artikel] Chem. Unserer Zeit 2020, vol. 54, no. 6, p. 368 |
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Digitalisierung nach der Pandemie [Editorial] CHEMKON 2021, vol. 28, no. 6, p. 234 |
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Jörg Häseler Liebe Mitglieder der Lebensmittelchemischen Gesellschaft [Article] Lebensmittelchemie 2021, vol. 75, no. S2 |
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Denis Priester, Ingo Krossing Elektromobilität und synthetische Kraftstoffe [Industrie + Technik] Nachr. Chem. 2021, vol. 69, no. 9, p. 36 |
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Most cited articles from Chemistry Europe, ACES, and GDCh journals
Articles on this list are the most frequently cited ones among those published in 2018 or 2019 according to Web of Science. They have contributed the most to the journal's impact factor in 2020.
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Jing Pan, Xin Long Tian, Shahid Zaman, Zehua Dong, Hongfang Liu, Ho Seok Park, Bao Yu Xia Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium-Air and Zinc-Air Batteries [Minireview] Batteries Supercaps 2019, vol. 2, pp. 336–347 |
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Veeresh Juturu, Jin Chuan Wu Heterologous Protein Expression in Pichia pastoris: Latest Research Progress and Applications [Review] ChemBioChem 2018, vol. 19, pp. 7–21 |
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Tingmin Di, Quanlong Xu, WingKei Ho, Hua Tang, Quanjun Xiang, Jiaguo Yu Review on Metal Sulphide-based Z-scheme Photocatalysts [Review] ChemCatChem 2019, vol. 11, pp. 1394–1411 |
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Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review] ChemElectroChem 2018, vol. 5, pp. 6–19 |
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Min Feng, Ming-Liang Tong Single Ion Magnets from 3d to 5f: Developments and Strategies [Minireview] Chem. Eur. J. 2018, vol. 24, pp. 7574–7594 |
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Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview] ChemistryOpen 2018, vol. 7, pp. 169–179 |
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Patil S. Basavarajappa, Bhojya Naik H. Seethya, Nagaraju Ganganagappa, Kumaraswamy B. Eshwaraswamy, Raghava Reddy Kakarla Enhanced Photocatalytic Activity and Biosensing of Gadolinium Substituted BiFeO3 Nanoparticles [Full Paper] ChemistrySelect 2018, vol. 3, pp. 9025–9033 |
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Deepti Goyal, Amandeep Kaur, Bhupesh Goyal Benzofuran and Indole: Promising Scaffolds for Drug Development in Alzheimer's Disease [Review] ChemMedChem 2018, vol. 13, pp. 1275–1299 |
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Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review] ChemPhotoChem 2018, vol. 2, pp. 386–402 |
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Weiyin Gao, Chenxin Ran, Jun Xi, Bo Jiao, Wenwen Zhang, Mincai Wu, Xun Hou, Zhaoxin Wu High-Quality Cs2AgBiBr6 Double Perovskite Film for Lead-Free Inverted Planar Heterojunction Solar Cells with 2.2 % Efficiency [Communication] ChemPhysChem 2018, vol. 19, pp. 1696–1700 |
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Achini Japahuge, Tao Zeng Theoretical Studies of Singlet Fission: Searching for Materials and Exploring Mechanisms [Review] ChemPlusChem 2018, vol. 83, pp. 146–182 |
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Peixun Xiong, Xinxin Zhao, Yunhua Xu Nitrogen-Doped Carbon Nanotubes Derived from Metal-Organic Frameworks for Potassium-Ion Battery Anodes [Full Paper] ChemSusChem 2018, vol. 11, pp. 202–208 |
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Nadja Stucke, Benedikt M. Flöser, Thomas Weyrich, Felix Tuczek Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments [Microreview] Eur. J. Inorg. Chem. 2018, pp. 1337–1355 |
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Davin Tan, Tomislav Friščić Mechanochemistry for Organic Chemists: An Update [Microreview] Eur. J. Org. Chem. 2018, pp. 18–33 |
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Esther von Grotthuss, Alexandra John, Thomas Kaese, Matthias Wagner Doping Polycyclic Aromatics with Boron for Superior Performance in Materials Science and Catalysis [Focus Review] Asian J. Org. Chem. 2018, vol. 7, pp. 37–53 |
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Min-Hua Huang, Wen-Juan Hao, Bo Jiang Recent Advances in Radical-Enabled Bicyclization and Annulation/1,n-Bifunctionalization Reactions [Focus Review] Chem. Asian J. 2018, vol. 13, pp. 2958–2977 |
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Amit Kumar, Qiang Xu Two-Dimensional Layered Materials as Catalyst Supports [Focus Review] ChemNanoMat 2018, vol. 4, pp. 28–40 |
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Leyre Marzo, Santosh K. Pagire, Oliver Reiser, Burkhard König Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? [Review] Angew. Chem. Int. Ed. 2018, vol. 57, pp. 10034–10072 |
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Sayantani Sikdar, Madhusree Kundu A Review on Detection and Abatement of Heavy Metals [Review] ChemBioEng Rev. 2018, vol. 5, pp. 18–29 |
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Marwa Elkady, Hassan Shokry, Hesham Hamad Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article] Chem. Eng. Technol. 2018, vol. 41, pp. 553–562 |
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Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review] Chem. Ing. Tech. 2018, vol. 90, pp. 17–35 |
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