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Chemistry - A European Journal

Cooperative Ligands in Dissolution of Gold

Published: 17 May 2021

Author(s): Eeva Heliövaara, Henri Liljeqvist, Mikko Muuronen, Aleksi Eronen, Karina Moslova, Timo Repo

Abstract Development of new, environmentally benign dissolution methods for metallic gold is driven by needs in the circular economy. Gold is widely used in consumer electronics, but sustainable and selective dissolution methods for Au are scarce. Herein, we describe a quantitative dissolution of gold in organic solution under mild conditions by using hydrogen peroxide as an oxidant. In the dissolution reaction, two thiol ligands, pyridine‐4‐thiol and 2‐mercaptobenzimidazole, work in a...

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Advanced Synthesis & Catalysis

Iron‐Catalyzed Three‐Component Cyanoalkylsulfonylation of 2,3‐Allenoic Acids, Sulfur Dioxide, and Cycloketone Oxime Esters: Access to Cyanoalkylsulfonylated Butenolides

Published: 17 May 2021

Author(s): Xiangyun Zheng, Tianshuo Zhong, Xiao Yi, Qitao Shen, Chuanliu Yin, Lei Zhang, Jian Zhou, Junyu Chen, Chuanming Yu

Abstract An iron‐catalyzed three‐component cyanoalkylsulfonylation of 2,3‐allenoic acids, K2S2O5, and the ring‐opening of cyclobutanone oxime esters is described. The radical tandem cyclization route allows access to diverse cyanoalkylsulfonylated butenolides in moderate to good yields under mild conditions. Moreover, the products are further converted, offering the corresponding derivatives.

Advanced Synthesis & Catalysis

Enantioselective Catalyzed Synthesis of Amino Derivatives Using Electrophilic Open‐Chain N‐Activated Ketimines

Published: 17 May 2021

Author(s): Marino Petrini, Alessandro Palmieri, Gabriele Lupidi

Abstract N‐Activated ketimines are characterized by the presence of acyl, sulfonyl, and phosphinoyl groups linked to the nitrogen atom of the azomethine system. These electron‐withdrawing groups enhance the electrophilic character of the imino moiety allowing the addition of even weak nucleophilic reagents. The presence of the oxygen atoms in these activating groups with its coordinating and Lewis or Brønsted properties is of paramount importance in asymmetric catalyzed reactions. This review...

Chemistry - A European Journal

Coordination‐Driven Selective Formation of D2 Symmetric Octanuclear Organometallic Cages

Published: 17 May 2021

Author(s): Long Zhang, Yue‐Jian Lin, Zhen‐Hua Li, J. Fraser Stoddart, Guo‐Xin Jin

Chemistry - An Asian Journal

Zinc Oxide‐Based Acetone Gas Sensors for Breath Analysis: A Review

Published: 17 May 2021

Author(s): Qasem A. Drmosh, Ibrahim Olanrewaju Alade, Mohammad Qamar, Sheikh Akbar

Abstract Acetone is one of the toxic, explosive, and harmful gases. It may cause several health hazard issues such as narcosis and headache. Acetone is also regarded as a key biomarker to diagnose several diseases as well as monitor the disorders in human health. Based on clinical findings, acetone concentration in human breath is correlated with many diseases such as asthma, halitosis, lung cancer, and diabetes. Thus, its investigation can become a new approach for health monitoring. Better...

Chemistry - An Asian Journal

The Role of Sulphonamides and N‐Sulphonyl Ketimines/Aldimines as Directing Groups in the Field of C−H Activation

Published: 17 May 2021

Author(s): Mary Sravani Galla, Darshana Bora, Nagula Shankaraiah

Abstract Sulphonamides and N‐sulphonyl ketimines/aldimines have turned out to be versatile motifs in the field of synthetic and medicinal chemistry. The field of C−H activation/functionalization flourished remarkably due to their synthetic applicability and directing group plays a remarkable role to achieve regioselectivity in these reactions. The current review summarizes recent tactics by utilizing sulphonamides and N‐sulphonyl ketimines/aldimines as directing groups for C−H activation or...

Zeitschrift für anorganische und allgemeine Chemie

Chemoselective Hydrogenation of Olefins Using a Nanostructured Nickel Catalyst

Published: 17 May 2021

Author(s): Mara Klarner, Sandra Bieger, Markus Drechsler, Rhett Kempe

Abstract The selective hydrogenation of functionalized olefins is of great importance in the chemical and pharmaceutical industry. Here, we report on a nanostructured nickel catalyst that enables the selective hydrogenation of purely aliphatic and functionalized olefins under mild conditions. The earth‐abundant metal catalyst allows the selective hydrogenation of sterically protected olefins and further tolerates functional groups such as carbonyls, esters, ethers and nitriles. The...

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Chemistry - An Asian Journal

Highly Emissive Metal‐Organic Frameworks for Sensitive and Selective Detection of Nitrofuran and Quinolone Antibiotics

Published: 17 May 2021

Author(s): Zhenzhong Cong, Zhenfeng Song, Yunxiao Ma, Mingchang Zhu, Ying Zhang, Shuangyan Wu, Enjun Gao

Abstract The overuse of antibiotics makes its detection very significant for human health. New facile methods and high‐performance sensory materials will be urgently needed for detection of antibiotics. Unfortunately, there are few reports on fluorescence enhancement of antibiotics detection. Herein, based on the modulability of the coordination mode, we proposed two MOFs with different coordination modes based on different metal ions: Zn‐MOF (1) and Cd‐MOF (2). The fluorescence of 1 and 2 can...

Zeitschrift für anorganische und allgemeine Chemie

Selective separation of uranium using modified Dowex 1X8 /TOA from carbonate leaching of Dolostone ore, Allouga area, Sinai

Published: 17 May 2021

Author(s): Ahmed R. Bakry, Doaa I. Zaki, Elham A. Gamil, Saleh M. El Hady, Nasr A. Abdel Fattah

Abstract Leaching of uranium from a technological sample (680 mg/Kg U) in SW Sinai of Um Bogma Formation is carried out using a mix of sodium carbonte/sodium bicarbonate in presence of an oxidant (MnO2 or H2O2). The relevant factors e.g. (grain size=−200 mesh, alkali concentration= 100 g/l (3 : 1) mixed Na2CO3/NaHCO3, time=2 h, solid/liquid ratio=1/3, T=50 °C and H2O2=60 ml) of alkaline leaching of uranium have been optimized. This is followed by uranium recovery using an anion exchange resin,...

European Journal of Inorganic Chemistry

Location of Cu Atom in Au‐Based Nanocluster and Its Optical Properties

Published: 17 May 2021

Author(s): Xiuqing Ren, Xuemei Fu, Xinzhang Lin, Jie Tang, He Wang, Chao Liu, Jiahui Huang

Abstract Atomically precise alloy nanoclusters are one of the important nanomaterials, benefiting to investigate the structure‐property correlations at atomic level. Herein, we reported Au19Cu2(SR)15 (SR: adamantanethiol) alloy nanocluster. The crystal structure of Cu−Au nanoclusters was determined by X‐ray crystallography and the molecular mass was further characterized via Fourier transform ion cyclotron resonance mass spectrometer (FT‐ICR‐MS). The crystal structure shows the kernel of...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

March 2021


	Yunqi Shao, Lisanne Knijff, Florian M. Dietrich, Kersti Hermansson, Chao Zhang Modelling Bulk Electrolytes and Electrolyte Interfaces with Atomistic Machine Learning [Minireview] Batteries & Supercaps 2021, vol. 4, no. 4, p. 585

	Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview] ChemBioChem 2021, vol. 22, no. 7, p. 1176

	Christian M. Heckmann, Francesca Paradisi Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review] ChemCatChem 2020, vol. 12, no. 24, p. 6082

	Gerhard Hilt Basic Strategies and Types of Applications in Organic Electrochemistry [Concept] ChemElectroChem 2020, vol. 7, no. 2, p. 395

	Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

	Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication] ChemistryOpen 2020, vol. 9, no. 7, p. 743

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055

	Antoine Daina, Vincent Zoete A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication] ChemMedChem 2016, vol. 11, no. 11, p. 1117

	Sebastian Gisbertz, Bartholomäus Pieber Heterogeneous Photocatalysis in Organic Synthesis [Review] ChemPhotoChem 2020, vol. 4, no. 7, p. 456

	Trevor A. Hamlin, Marcel Swart, F. Matthias Bickelhaupt Nucleophilic Substitution (S_N2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent [Minireview] ChemPhysChem 2018, vol. 19, no. 11, p. 1315

	Daewoo Han, Andrew J. Steckl Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review] ChemPlusChem 2019, vol. 84, no. 10, p. 1453

	Thomas Aro, Pedram Fatehi Production and Application of Lignosulfonates and Sulfonated Lignin [Review] ChemSusChem 2017, vol. 10, no. 9, p. 1861

	Carolin Hoyer, Peter Schwerk, Lisa Suntrup, Julia Beerhues, Maite Nössler, Uta Albold, Jens Dernedde, Karsten Tedin, Biprajit Sarkar Synthesis, Characterization, and Evaluation of Antibacterial Activity of Ferrocenyl-1,2,3-Triazoles, Triazolium Salts, and Triazolylidene Complexes of Gold(i) and Silver(i) [Full Paper] Eur. J. Inorg. Chem. 2021, p. 1373

	Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

	Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper] Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

	Daojin Zhou, Pengsong Li, Wenwen Xu, Sana Jawaid, Jamesh Mohammed-Ibrahim, Wen Liu, Yun Kuang, Xiaoming Sun Recent Advances in Non-Precious Metal-Based Electrodes for Alkaline Water Electrolysis [Minireview] ChemNanoMat 2020, vol. 6, no. 3, p. 336

	Huaibo Zhao, Daniele Leonori Minimization of Back-Electron Transfer Enables the Elusive sp³ C−H Functionalization of Secondary Anilines [Communication] Angew. Chem. Int. Ed. 2021, vol. 60, no. 14, p. 7669

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

	Özge Çepelioğullar Mutlu, Thomas Zeng Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A Review [Review] Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

	Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland Methane Pyrolysis for CO₂-Free H₂ Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review] Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

	Emiliano Feresin^, Mykhailo Kondratiuk, Julia Nowack, Lukas Gooßen^ Handreinigung auf molekularer Ebene - Die Rolle der Solvatation [Artikel] Chem. Unserer Zeit 2021, vol. 55, no. 1, p. 28

	Hilbert Meyer Guter Unterricht an guten Schulen? [Aufsatz] CHEMKON 2006, vol. 13, no. 2, p. 77

	Bambus in Coffee-to-go-Bechern [Analytik] Lebensmittelchemie 2021, vol. 75, no. 1, p. 2

	Jan Paradies, Jennifer Andexer, Uwe Beifuss, Florian Beuerle, Malte Brasholz, Rolf Breinbauer, Martin Ernst, Ruth Ganardi, Tobias A. M. Gulder, Wolfgang Hüttel, Stephanie Kath-Schorr, Karsten Körber, Markus Kordes, Matthias Lehmann, Thomas Lindel, Burkhard Luy, Christian Mück-Lichtenfeld, Claudia Muhle-Goll, Jochen Niemeyer, Roland Pfau, Jörg Pietruszka, Johannes L. Röckl, Norbert Schaschke, Mathias O. Senge, Bernd F. Straub, Siegfried R. Waldvogel, Thomas Werner, Daniel B. Werz, Christian Winter Organische Chemie [Wissenschaft + Forschung] Nachr. Chem. 2021, vol. 69, no. 3, p. 38

Most cited articles from Chemistry Europe, ACES, and GDCh journals

Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.


	Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication] Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

	Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review] Batteries Supercaps 2018, vol. 1, pp. 41–68

	Lik Hang Yuen, Raphael M. Franzini Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview] ChemBioChem 2017, vol. 18, pp. 829–836

	Konstantinos C. Christoforidis, Paolo Fornasiero Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review] ChemCatChem 2017, vol. 9, pp. 1523–1544

	Marwa Elkady, Hassan Shokry, Hesham Hamad Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article] Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

	Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview] ChemistryOpen 2018, vol. 7, pp. 169–179

	Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, pp. 945–956

	Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe₃O₄@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826

	Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review] Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

	Sayantani Sikdar, Madhusree Kundu A Review on Detection and Abatement of Heavy Metals [Review] ChemBioEng Rev. 2018, vol. 5, pp. 18–29

	Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication] ChemElectroChem 2017, vol. 4, pp. 1840–1845

	Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper] ChemNanoMat 2017, vol. 3, pp. 328–335

	Chengwei Liu, Michal Szostak Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview] Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

	Jian Shu, Dianping Tang Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review] Chem. Asian J. 2017, vol. 12, pp. 2780–2789

	Jian Rong, Chuanfa Ni, Jinbo Hu Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review] Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

	Juan Alberto Sirvent, Ulrich Lücking Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper] ChemMedChem 2017, vol. 12, pp. 487–501

	Grzegorz Greczynski, Lars Hultman C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication] ChemPhysChem 2017, vol. 18, pp. 1507–1512

	Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept] ChemPhotoChem 2017, vol. 1, pp. 148–158

	Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication] ChemSusChem 2017, vol. 10, pp. 87–90

	Enzo Alessio Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview] Eur. J. Inorg. Chem. 2017, pp. 1549–1560

	Marcel Garbe, Kathrin Junge, Matthias Beller Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview] Eur. J. Org. Chem. 2017, pp. 4344–4362