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Chemistry - A European Journal

Enantioselective Acyl Migration Reactions of Furanyl Carbonates with Chiral DMAP Derivatives

Published: 16 January 2019

Author(s): Kazuki Fujii, Koichi Mitsudo, Hiroki Mandai, Toshinobu Korenaga, Seiji Suga

Abstract An efficient enantioselective acyl migration reaction of furanyl carbonates was developed to construct all‐carbon quaternary stereogenic centers. In some cases, the reactions required only 0.05 mol % (minimum 500 ppm) of catalyst and showed a high turnover frequency value (TOF; 3640 h−1). Multigram‐scale reactions (10 grams) also proceeded with high enantioselectivity ( 99:1 e.r.) in quantitative yield. The catalyst was robust and easily recovered in 98 % yield. A wide range of...

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Chemistry - A European Journal

Competitive Metal Coordination of Hexaaminotriphenylene on Cu(111) by Intrinsic Copper Versus Extrinsic Nickel Adatoms

Published: 16 January 2019

Author(s): Matthias Lischka, Renhao Dong, Mingchao Wang, Natalia Martsinovich, Massimo Fritton, Lukas Grossmann, Wolfgang M. Heckl, Xinliang Feng, Markus Lackinger

Abstract The interplay between the self‐assembly and surface chemistry of 2,3,6,7,10,11‐hexaaminotriphenylene (HATP) on Cu(111) was complementarily studied by high‐resolution scanning tunneling microscopy (STM) and X‐ray photoelectron spectroscopy (XPS) under ultra‐high vacuum conditions. To shed light on the competitive metal coordination, comparative experiments were carried out on pristine and nickel‐covered Cu(111). Directly after room‐temperature deposition of HATP onto pristine Cu(111),...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

A Practical General Method for the Preparation of Long Acenes

Published: 16 January 2019

Author(s): Andrej Jancarik, Gaspard Levet, André Gourdon

Abstract The field of long acenes, the narrowest of the zig‐zag graphene nanoribbons, has been an area of significant interest in the past decade because of its potential applications in organic electronics, spintronics and plasmonics. However the low solubility and high reactivity of these compounds has so far hindered their preparation on large scales. We report here a concise strategy for the synthesis of higher acenes through Diels–Alder condensation of arynes with a protected tetraene...

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Journal of the American Ceramic Society

Large strain under low driving field in lead‐free relaxor/ferroelectric composite ceramics

Published: 16 January 2019

Author(s): Pengyuan Fan, Yangyang Zhang, Yiwei Zhu, Weigang Ma, Kai Liu, Xueting He, Mohsin Ali Marwat, Bing Xie, Ming Li, Haibo Zhang

Abstract 0.75(Na0.5Bi0.5)TiO3–0.25SrTiO3 lead‐free incipient piezoceramic is a promising candidate for actuator applications due to their large reversible electromechanical strains at the relatively low driving field of 40 kV/cm. In order to further reduce the driving field of 0.75(Na0.5Bi0.5)TiO–0.25SrTiO3 relaxor ceramic to meet the requirements for real actuators application, the relaxor/ferroelectric (RE/FE) 0‐3 composite ceramics method was employed. The polarization and strain behaviors...

thumbnail image: Journal of the American Ceramic Society

Journal of the American Ceramic Society

Effects of sintering process on the structural, dielectric, and optical absorption properties of KNbO3‐based ceramics

Published: 16 January 2019

Author(s): Ronaldo C. Gennari, Rossano Lang, José A. Eiras, Manuel H. Lente

Abstract The influence of the sintering temperature and the dwell time on the structural, optical, and dielectric properties of [KNbO3]0.8[Ba(Ni0.5Nb0.5)O3−δ]0.2 ceramics (KBNNO) was systematically investigated. X‐ray diffraction measurements of the ceramic bodies sintered at different temperatures indicated that all samples presented a cubic‐like structure. However, the results remarkably revealed that both the sintering temperature and the dwell time are crucial factors that must be taken...

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Chemistry - An Asian Journal

NixCo3‐xO4 Nanoneedle Arrays Grown on Ni Foam as an Efficient Bifunctional Electrocatalyst for Full Water Splitting

Published: 16 January 2019

Author(s): Jian Bao, Wenjun Liu, Junfeng Xie, Li Xu, Meili Guan, Fengcai Lei, Yan Zhao, Yunpeng Huang, Jiexiang Xia, Huaming Li

Abstract Developing highly active, stable and robust electrocatalysts based on earth‐abundant elements for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is important for many renewable energy conversion processes. Herein, NixCo3‐xO4 nanoneedle arrays grown on 3D porous nickel foam (NF) was synthesized as a bifunctional electrocatalyst with OER and HER activity for full water splitting. Benefiting from the advantageous structure, the composite exhibits superior OER...

thumbnail image: Chemistry - An Asian Journal

Chemistry - An Asian Journal

Controlling the Emergence and Shift Direction of Mechanochromic Luminescence Color of a Pyridine‐Terminated Compound

Published: 16 January 2019

Author(s): Mizuho Kondo, Taku Yamoto, Seiya Miura, Mayuko Hashimoto, Chitoshi Kitamura, Nobuhiro Kawatsuki

thumbnail image: Chemistry - An Asian Journal

Pest Management Science

Mixed effects of landscape complexity and insecticide use on ladybeetle abundance in wheat fields

Published: 16 January 2019

Author(s): Long Yang, Qian Zhang, Bing Liu, Yingda Zeng, Yunfei Pan, Minlong Li, Yanhui Lu

Abstract BACKGROUND Although the abundance of insect natural enemies in crop fields may be influenced by the surrounding landscape and local field management, particularly insecticide use at the local scale, few studies have examined these factors simultaneously. In this study, we investigated the effects of landscape context and insecticide use in local fields on ladybeetle abundance in wheat fields in northern China. RESULTS Woodlots and fallow land were the most important landscape...

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Journal of the American Ceramic Society

Crystal structure, densification, and microwave dielectric properties of Li3Mg2(Nb(1−x)Mox)O6+x/2 (0 ≤ x ≤ 0.08) ceramics

Published: 16 January 2019

Author(s): Ping Zhang, Kexin Sun, Mi Xiao, Zhentai Zheng

Abstract A novel system Li3Mg2(Nb(1−x)Mox)O6+x/2 (0 ≤ x ≤ 0.08) microwave dielectric ceramics were fabricated by the solid‐state method. The charge compensation of Mo6+ ions substitution for Nb5+ ions was performed by introducing oxygen ions. The X‐ray diffraction patterns and Rietveld refinements indicated Li3Mg2(Nb(1−x)Mox)O6+x/2 ceramics with single phase and orthorhombic structure. Micro‐structure and density confirmed that the grain of Li3Mg2(Nb(1‐x)Mox)O6+x/2 ceramics grew well. In...

thumbnail image: Journal of the American Ceramic Society

Journal of the American Ceramic Society

Chemical equilibrium analysis of silicon carbide oxidation in oxygen and air

Published: 16 January 2019

Author(s): Samuel Y. Chen, Iain D. Boyd

Abstract Due to their refractory nature and oxidation resistance, Ultra‐High Temperature Ceramic materials, including silicon carbide, are of interest in hypersonic aerospace applications. To analyze the thermodynamic behavior of silicon carbide during transition between passive and active oxidation states, chemical equilibrium calculations are performed. The predicted oxygen pressures for passive‐to‐active transition show improved agreement up to an order of magnitude with experimental...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

September 2018


Runze Mao, Jonathan Balon, Xile Hu
Decarboxylative C(sp3)−O Cross-Coupling [Communication]
Angew. Chem. Int. Ed. 2018, vol. 57, p. 13624

Klaus F. Wagenbauer, Floris A. S. Engelhardt, Evi Stahl, Vera K. Hechtl, Pierre Stömmer, Fabian Seebacher, Letizia Meregalli, Philip Ketterer, Thomas Gerling, Hendrik Dietz
How We Make DNA Origami [Concept]
ChemBioChem 2017, vol. 18, p. 1873

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Epple, Joachim Enax
Moderne Zahnpflege aus chemischer Sicht [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 218

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Peter Buchholz, Torsten Brandenburg
Demand, Supply, and Price Trends for Mineral Raw Materials Relevant to the Renewable Energy Transition Wind Energy, Solar Photovoltaic Energy, and Energy Storage [Review]
Chem. Ing. Tech. 2018, vol. 90, p. 141

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, p. 6

Hejin Jiang, Li Zhang, Minghua Liu
Self-Assembly of 1D Helical Nanostructures into Higher Order Chiral Nanostructures in Supramolecular Systems [Focus Review]
ChemNanoMat 2018, vol. 4, p. 720

Sa Xiao, Yi Lu, Xin Li, Bing-Yu Xiao, Liang Wu, Jian-Ping Song, Yu-Xuan Xiao, Si-Ming Wu, Jie Hu, Yong Wang, Gang-Gang Chang, Ge Tian, Silvia Lenaerts, Christoph Janiak, Xiao-Yu Yang, Bao-Lian Su
Hierarchically Dual-Mesoporous TiO2 Microspheres for Enhanced Photocatalytic Properties and Lithium Storage [Full Paper]
Chem. Eur. J. 2018, vol. 24, p. 13246

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Michael C. Willis, Edward J. Emmett
The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry [Focus Review]
Asian J. Org. Chem. 2015, vol. 4, p. 602

Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss
Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper]
ChemMedChem 2018, vol. 13, p. 988

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Baokun Qiao, Zhiyong Jiang
Catalytic Photoreduction Induced by Visible Light [Minireview]
ChemPhotoChem 2018, vol. 2, p. 703

Xinyue Zhang, Mingyue Jiang, Na Niu, Zhijun Chen, Shujun Li, Shouxin Liu, Jian Li
Natural-Product-Derived Carbon Dots: From Natural Products to Functional Materials [Review]
ChemSusChem 2018, vol. 11, p. 11

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Cover Picture Lebensmittelchemie 4/2018 [Cover Picture]
Lebensmittelchemie 2018, vol. 72

Thomas U. Probst
Umbrüche beim Kunststoffrecycling [Industrie & Technik]
Nachr. Chem. 2018, vol. 66, p. 868

Alexander Engl, Alexandra Schmelzer, Björn Risch
Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel]
CHEMKON 2018, vol. 25, p. 7

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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