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European Journal of Organic Chemistry

An Efficient Chan–Lam S ‐Arylation of Arylthioureas with Arylboronic Acids

Published: 17 August 2018

Author(s): Xing Liu, Shi‐Bo Zhang, Hui Zhu, Yu Cheng, Han‐Ying Peng, Zhi‐Bing Dong

A convenient and efficient protocol has been developed for the preparation of aryl‐isothioureas based on the Chan–Lam C–S coupling reaction. The desired aryl‐isothioureas were synthesized in good yields (up to 95 %) in the presence of Cu(OAc)2·H2O as catalyst and bipyridine as ligand. A variety of functional groups on the aryl‐thiourea and arylboronic acid reagents are tolerated. The method features mild reaction conditions and good yields, thereby...

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Advanced Functional Materials

A Review of Precious‐Metal‐Free Bifunctional Oxygen Electrocatalysts: Rational Design and Applications in Zn−Air Batteries

Published: 17 August 2018

Author(s): Hao‐Fan Wang, Cheng Tang, Qiang Zhang

Abstract The bifunctional electrocatalysis of oxygen reduction reactions (ORRs) and oxygen evolution reactions (OERs) is critical for the development of rechargeable Zn–air batteries. Both ORRs and OERs suffer from sluggish kinetics and high overpotentials, and the bifunctional reactivity is limited by the scaling relationship. Therefore, smart designs on electrocatalysts are requested to achieve high bifunctional ORR/OER activity...

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Advanced Materials

Manganese‐Oxide‐Based Electrode Materials for Energy Storage Applications: How Close Are We to the Theoretical Capacitance?

Published: 17 August 2018

Author(s): Yating Hu, Yue Wu, John Wang

Abstract Of the transition metals, Mn has the greatest number of different oxides, most of which have a special tunnel structure that enables bulk redox reactions. The high theoretical capacitance and capacity results from a greater number of accessible oxidation states than other transition metals, wide potential window, and the high natural abundance make MnOx species promising electrode materials for energy storage applications. Although...

Comprehensive Reviews in Food Science and Food Safety

Modeling Starch Digestograms: Computational Characteristics of Kinetic Models for in vitro Starch Digestion in Food Research

Published: 17 August 2018

Author(s): Giang T. Nguyen, Peter A. Sopade

Abstract Starch digestion is mostly investigated with in vitro techniques, and time‐course measurements are common. These yield digestograms that are modeled by theoretical, semitheoretical, and empirical kinetic equations, many of which are reviewed here. The Duggleby model has Michaelis–Menten functions, and its dependent variable is on both sides of the equation with no apparent parameter for maximum digestible starch (D∞). The Gaouar and...

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European Journal of Organic Chemistry

C–H Bond Activation by a Ruthenium(II) β ‐Diketonate Complex: A Mechanistic Study

Published: 17 August 2018

Author(s): Anamarija Briš, Iztok Turel, Jana Roithová

Ruthenium(II)‐catalysed C–H bond activation of arenes containing a functional directing group depends on the ligand coordinated to ruthenium(II). In this study, 2‐phenylpyridine C–H activation catalysed by a “piano‐stool“ ruthenium(II) complex containing a fluorinated β‐diketonate ligand was examined by ESI‐MS in combination with CID experiments. [Ru(β‐diketonate)(CTPhPy)Cl]+ was identified as an active intermediate, and its collisional activation...

Comprehensive Reviews in Food Science and Food Safety

A Review on the Dietary Flavonoid Tiliroside

Published: 17 August 2018

Author(s): Daniel M. Grochowski, Marcello Locatelli, Sebastian Granica, Francesco Cacciagrano, Michał Tomczyk

Abstract Among flavonoid derivatives, tiliroside is a flavonoid contained in several edible plants or specific plant parts (fruits, leaves, or roots). These parts are often widely used as both food and medicines, in the treatment of various ailments and, in some cases, as food supplements. Considering the easy access to many publications concerning tiliroside and the lack of a review that summarizes the current progress in studies...

Chemistry - A European Journal

Bifunctional Separator Coated with Hexachlorocyclotriphosphazene/Reduced Graphene Oxide for Enhanced Performance of Lithium–Sulfur Batteries

Published: 17 August 2018

Author(s): Yanping Zheng, Honghong Fan, Huanhuan Li, Chaoying Fan, Haiyan Yuan, Zhifang Yang, Kecheng Huang, Wenliang Li, Jingping Zhang

Abstract Although extensive research has been performed in the field of Li−S rechargeable batteries, commercial applications are still hindered by the dissolution of the reaction intermediates of lithium polysulfides (LiPSs). Through the combination of experimental and theoretical results, a bifunctional separator has been designed by coating hexachlorocyclotriphosphazene (HCCP)‐decorated reduced graphene oxide (rGO), which provides...

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Angewandte Chemie International Edition

Multidirectional Activity Control of Cellular Processes by a Versatile Chemo‐optogenetic Approach

Published: 17 August 2018

Author(s): Xi Chen, Muthukumaran Venkatachalapathy, Leif Dehmelt, Yao‐Wen Wu

Abstract The spatiotemporal dynamics of proteins or organelles plays a vital role in controlling diverse cellular processes. However, acute control of activity at distinct locations within a cell is challenging. A versatile multidirectional activity control (MAC) approach is presented, which employs a photoactivatable system that may be dimerized upon chemical inducement. The system comprises second‐generation SLF*‐TMP (S*T) and...

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Chemistry - A European Journal

Catalytic Asymmetric [8+3] Annulation Reactions of Tropones or Azaheptafulvenes with meso ‐Aziridines

Published: 17 August 2018

Author(s): Jianlin Zhang, Wanlong Xiao, Haipeng Hu, Lili Lin, Xiaohua Liu, Xiaoming Feng

Abstract Highly enantioselective [8+3] high‐order cycloaddition reactions of tropones or azaheptafulvenes with meso‐aziridines were achieved by a desymmetrization/annulation process in the presence of chiral N,N′‐dioxide/Mg(OTf)2 complex. The corresponding tetrahydrocyclohepta[b][1,4]oxazines and tetrahydro‐1H‐cyclohepta‐ [b]‐pyrazines were obtained in good yields (66–98 %) with excellent diastereo‐ and enantioselectivities (>19:1 d.r., 90–96 % ee). A...

Angewandte Chemie International Edition

Yujie Xiong

Published: 17 August 2018

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

June 2018


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	Parker Nichols, Alexandra Born, Morkos Henen, Dean Strotz, Celestine N Chi, Peter Güntert, Beat Rolf Vögeli Extending the Applicability of Exact Nuclear Overhauser Enhancements to Large Proteins and RNA [Minireview] ChemBioChem 2018

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	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, p. 6055

	Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen Regulatory Aspects of Nanomaterials in the EU [Research Article] Chem. Ing. Tech. 2017, vol. 89, p. 224

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	Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review] ChemElectroChem 2018, vol. 5, p. 6

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	Christopher J Matheson, Kimberly A Casalvieri, Donald S Backos, Philip Reigan Development of potent pyrazolopyrimidinone-based WEE1 inhibitors with limited single-agent cytotoxicity for cancer therapy [Full Paper] ChemMedChem 2018

	Gloria Tabacchi Supramolecular Organization in Confined Nanospaces [Review] ChemPhysChem 2018, vol. 19, p. 1249

	Emily B. Corcoran, François Lévesque, Jonathan P. McMullen, John R. Naber Studies Toward the Scaling of Gas-Liquid Photocycloadditions [Article] ChemPhotoChem 2018

	An-Na Cho, Nam-Gyu Park Impact of Interfacial Layers in Perovskite Solar Cells [Review] ChemSusChem 2017, vol. 10, p. 3687

	Ross J. Marshall, Ross S. Forgan Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview] Eur. J. Inorg. Chem. 2016, p. 4310

	Romaric Gérardy, Noémie Emmanuel, Thomas Toupy, Victor-Emmanuel Kassin, Nelly Ntumba Tshibalonza, Michaël Schmitz, Jean-Christophe M. Monbaliu Continuous Flow Organic Chemistry: Successes and Pitfalls at the Interface with Current Societal Challenges [Microreview] Eur. J. Org. Chem. 2018, p. 2301

	46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung] Lebensmittelchemie 2018, vol. 72, p. 1

	Markus Hiebel, Katharina Reh Kreislaufwirtschaft: Von Anfang an ans Ende denken [Industrie & Technik] Nachr. Chem. 2018, vol. 66, p. 606

	Alexander Engl, Alexandra Schmelzer, Björn Risch Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel] CHEMKON 2018, vol. 25, p. 7

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal

2016


	Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

	Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke Fluorescent Probes for G-Quadruplex Structures [Review] ChemBioChem 2013, vol. 14, pp. 540–558

	Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75

	Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

	Marc Steinmetz, Stefan Grimme Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper] ChemistryOpen 2013, vol. 2, pp. 115–124

	Philipp Scharf, Jens Müller Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review] ChemPlusChem 2013, vol. 78, pp. 20–34

	Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess Production of Liquid Hydrocarbons with CO₂ as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article] Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

	Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86

	Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127

	Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper] Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

	Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp²)–H Bonds [Focus Review] Chem. Asian J. 2014, vol. 9, pp. 26–47

	Naohiko Yoshikai, Ye Wei Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review] Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

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