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Comprehensive Reviews in Food Science and Food Safety

A Review on the Dietary Flavonoid Tiliroside

Published: 17 August 2018

Author(s): Daniel M. Grochowski, Marcello Locatelli, Sebastian Granica, Francesco Cacciagrano, Michał Tomczyk

Abstract Among flavonoid derivatives, tiliroside is a flavonoid contained in several edible plants or specific plant parts (fruits, leaves, or roots). These parts are often widely used as both food and medicines, in the treatment of various ailments and, in some cases, as food supplements. Considering the easy access to many publications concerning tiliroside and the lack of a review that summarizes the current progress in studies...

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Chemistry - A European Journal

Bifunctional Separator Coated with Hexachlorocyclotriphosphazene/Reduced Graphene Oxide for Enhanced Performance of Lithium–Sulfur Batteries

Published: 17 August 2018

Author(s): Yanping Zheng, Honghong Fan, Huanhuan Li, Chaoying Fan, Haiyan Yuan, Zhifang Yang, Kecheng Huang, Wenliang Li, Jingping Zhang

Abstract Although extensive research has been performed in the field of Li−S rechargeable batteries, commercial applications are still hindered by the dissolution of the reaction intermediates of lithium polysulfides (LiPSs). Through the combination of experimental and theoretical results, a bifunctional separator has been designed by coating hexachlorocyclotriphosphazene (HCCP)‐decorated reduced graphene oxide (rGO), which provides...

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Angewandte Chemie International Edition

Multidirectional Activity Control of Cellular Processes by a Versatile Chemo‐optogenetic Approach

Published: 17 August 2018

Author(s): Xi Chen, Muthukumaran Venkatachalapathy, Leif Dehmelt, Yao‐Wen Wu

Abstract The spatiotemporal dynamics of proteins or organelles plays a vital role in controlling diverse cellular processes. However, acute control of activity at distinct locations within a cell is challenging. A versatile multidirectional activity control (MAC) approach is presented, which employs a photoactivatable system that may be dimerized upon chemical inducement. The system comprises second‐generation SLF*‐TMP (S*T) and...

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Chemistry - A European Journal

Catalytic Asymmetric [8+3] Annulation Reactions of Tropones or Azaheptafulvenes with meso ‐Aziridines

Published: 17 August 2018

Author(s): Jianlin Zhang, Wanlong Xiao, Haipeng Hu, Lili Lin, Xiaohua Liu, Xiaoming Feng

Abstract Highly enantioselective [8+3] high‐order cycloaddition reactions of tropones or azaheptafulvenes with meso‐aziridines were achieved by a desymmetrization/annulation process in the presence of chiral N,N′‐dioxide/Mg(OTf)2 complex. The corresponding tetrahydrocyclohepta[b][1,4]oxazines and tetrahydro‐1H‐cyclohepta‐ [b]‐pyrazines were obtained in good yields (66–98 %) with excellent diastereo‐ and enantioselectivities (>19:1 d.r., 90–96 % ee). A...

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Angewandte Chemie International Edition

Yujie Xiong

Published: 17 August 2018

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Zeitschrift für anorganische und allgemeine Chemie

New Aspects with Regard to Silanide Chemistry in Particular Formation and Structure of the First Disilyl Sodate KMe 2 SiO 7 t Bu 3 Si 2 MeSiNaSiMeSi t Bu 3 2

Published: 17 August 2018

Author(s): Inge Sänger, Michael Gärtner, Michael Bolte, Matthias Wagner, Hans‐Wolfram Lerner

:The silanide Na[SiMe(SitBu3)2] was prepared by three step synthesis: In a first step, two equivalents of Na[SitBu3] were reacted with Cl2MeSi‐H to give (tBu3Si)2MeSi–H. In a second step the silane (tBu3Si)2MeSi–H was brominated. Thereby we could isolate single crystals of (tBu3Si)2MeSi–Br (monoclinic, space group C2/c), which were suitable for X‐ray diffraction. Subsequent reaction of (tBu3Si)2MeSi–Br with sodium yielded the silanide Na[SiMe(SitBu3)2] in heptane at room...

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Comprehensive Reviews in Food Science and Food Safety

Peanut ( Arachis hypogaea L.): A Prospective Legume Crop to Offer Multiple Health Benefits Under Changing Climate

Published: 17 August 2018

Author(s): Nudrat Aisha Akram, Fahad Shafiq, Muhammad Ashraf

Abstract Peanut is a multipurpose oil‐seed legume, which offer benefits in many ways. Apart from the peanut plant's beneficial effects on soil quality, peanut seeds are nutritious and medicinally and economically important. In this review, insights into peanut origin and its domestication are provided. Peanut is rich in bioactive components, including phenolics, flavonoids, polyphenols, and resveratrol. In addition, the involvement...

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Particle & Particle Systems Characterization

2D Dendritic Gold Nanostructures Formed on Silica Nanosheets: Transferability, Clean Surface, and Their Biomedical Application

Published: 17 August 2018

Author(s): Xiaoxiao Wang, Dandan Yang, Lizhu Chen, Bin Liu, Zhaogang Teng, Nongyue He, Zhifei Wang

Abstract The fabrication of 2D dendritic gold nanostructures (2D Au DNSs) has aroused extensive research interest because of their complicated structural characteristic and the unique optical and catalytic properties. However, to obtain transferable 2D Au DNS with clean surface is still extremely difficult, which severely limits their applications. In this work, transferable 2D Au DNSs are designed and constructed by the combination...

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ChemCatChem

Surprising Differences of Alkane C‐H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface‐Substrate Recognition?

Published: 17 August 2018

Author(s): Niels Rothermel, Donia Bouzouita, Tobias Röther, Iker de Rosal, Simon Tricard, Romuald Poteau, Torsten Gutmann, Bruno Chaudret, Hans‐Heinrich Limbach, Gerd Buntkowsky

Abstract The activation of C−H bonds of alkanes remains a major challenge for chemistry. In a series of deuteration experiments with D2 in contact with bis‐(diphenylphosphino) butane (dppb) stabilized ruthenium nanoparticles (liquid substrates, 60 °C, 6 bar D2) we have observed a surprisingly large reactivity of cyclopentane as compared to cyclohexane and other alkanes. DFT calculations using a ligand‐free Ru13H17 model cluster as...

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Zeitschrift für anorganische und allgemeine Chemie

Coordination‐directed and Hydrogen‐bonded Assembly of Supramolecular Architectures Constructed from Diverse Coordination of Linear, Triangular, Tetragonal Pyramid, Trigonal Bipyramid, and Octahedral Mononuclear Units

Published: 17 August 2018

Author(s): Lingling Zheng, Aiju Zhou, Chunxia Liao, X.‐D. Huang, Peiling Chen, Sheng Hu

Reaction of a imidazole phenol ligand 4‐(imidazlo‐1‐yl)phenol (L) with 3d metal salts afforded four complexes, namely, [Ni(L)6]·(NO3)2 (1), [Cu(L)4(H2O)]·(NO3)2·(H2O)5 (2), [Zn(L)4(H2O)]·(NO3)2·(H2O) (3), and [Ag2(L)4]·SO4 (4). All complexes are composed of monomeric units with diverse coordination arrangements and corresponding anions. All the hydroxyl groups of monomeric cations are used as hydrogen‐bond donors to form O–H···O hydrogen bonds. However, the...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

June 2018

 


Saki Ichikawa, Shaolin Zhu, Stephen L. Buchwald
A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination [Communication]
Angew. Chem. Int. Ed. 2018, vol. 57, p. 8714

Parker Nichols, Alexandra Born, Morkos Henen, Dean Strotz, Celestine N Chi, Peter Güntert, Beat Rolf Vögeli
Extending the Applicability of Exact Nuclear Overhauser Enhancements to Large Proteins and RNA [Minireview]
ChemBioChem 2018

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Klaus Roth
Die Suche nach dem Blau der „Blauen Blume“ [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 192

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Philip C. Andrews, Lisandra L. Martin, Alexandr N. Simonov
Leone Spiccia Memorial Issue [Editorial]
ChemPlusChem 2018, vol. 83, p. 548

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, p. 6

Santosh K. Tiwari, Raghvendra Kumar Mishra, Sung Kyu Ha, Andrzej Huczko
Evolution of Graphene Oxide and Graphene: From Imagination to Industrialization [Focus Review]
ChemNanoMat 2018, vol. 4, p. 598

R. Aleyda Garza-Sanchez, Tuhin Patra, Adrian Tlahuext-Aca, Felix Strieth-Kalthoff, Frank Glorius
DMSO as a Switchable Alkylating Agent in Heteroarene C−H Functionalization [Communication]
Chem. Eur. J. 2018

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Christopher J Matheson, Kimberly A Casalvieri, Donald S Backos, Philip Reigan
Development of potent pyrazolopyrimidinone-based WEE1 inhibitors with limited single-agent cytotoxicity for cancer therapy [Full Paper]
ChemMedChem 2018

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Emily B. Corcoran, François Lévesque, Jonathan P. McMullen, John R. Naber
Studies Toward the Scaling of Gas-Liquid Photocycloadditions [Article]
ChemPhotoChem 2018

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Romaric Gérardy, Noémie Emmanuel, Thomas Toupy, Victor-Emmanuel Kassin, Nelly Ntumba Tshibalonza, Michaël Schmitz, Jean-Christophe M. Monbaliu
Continuous Flow Organic Chemistry: Successes and Pitfalls at the Interface with Current Societal Challenges [Microreview]
Eur. J. Org. Chem. 2018, p. 2301

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Markus Hiebel, Katharina Reh
Kreislaufwirtschaft: Von Anfang an ans Ende denken [Industrie & Technik]
Nachr. Chem. 2018, vol. 66, p. 606

Alexander Engl, Alexandra Schmelzer, Björn Risch
Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel]
CHEMKON 2018, vol. 25, p. 7

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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