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Chemistry - A European Journal

Coordination‐Driven Selective Formation of D2 Symmetric Octanuclear Organometallic Cages

Published: 17 May 2021

Author(s): Long Zhang, Yue‐Jian Lin, Zhen‐Hua Li, J. Fraser Stoddart, Guo‐Xin Jin

thumbnail image: Chemistry - A European Journal

European Journal of Inorganic Chemistry

Location of Cu Atom in Au‐Based Nanocluster and Its Optical Properties

Published: 17 May 2021

Author(s): Xiuqing Ren, Xuemei Fu, Xinzhang Lin, Jie Tang, He Wang, Chao Liu, Jiahui Huang

Abstract Atomically precise alloy nanoclusters are one of the important nanomaterials, benefiting to investigate the structure‐property correlations at atomic level. Herein, we reported Au19Cu2(SR)15 (SR: adamantanethiol) alloy nanocluster. The crystal structure of Cu−Au nanoclusters was determined by X‐ray crystallography and the molecular mass was further characterized via Fourier transform ion cyclotron resonance mass spectrometer (FT‐ICR‐MS). The crystal structure shows the kernel of...

European Journal of Inorganic Chemistry

Synthesis and Characterisation of Transition Metal Complexes of a Novel 1,5‐benzodiazepine‐Functionalised Tertiary Phosphine

Published: 17 May 2021

Author(s): Sean E. Durran, Mark R. J. Elsegood, Thomas A. Noble, Martin B. Smith, Thomas Gelbrich, Michael B. Hursthouse, Mark E. Light

Abstract The one‐step synthesis (44 % isolated yield) of the 1,5‐benzodiazapine functionalised phosphine 1, C31H31N2OP, is reported. Bridge cleavage of {MCl(μ‐Cl)(η5‐Cp*)}2 (M=Ir, Rh) with 2 equiv. of 1 in CH2Cl2 gave the mononuclear compounds [MCl2(η5‐Cp*)(P‐1)] (M=Ir, 2 a; M=Rh, 2 b) in which 1 functions as a P‐monodentate ligand. Rapid C(sp3)−H bond activation, at room temperature, is observed for 2 a leading to the unusual cyclometallated complex [Ir(η5‐Cp*)(P,N,C‐1)]Cl2 3 (or 3‘) bearing...

European Journal of Inorganic Chemistry

Far‐Red and Near‐Infrared Boron Schiff Bases (BOSCHIBAs) Dyes Bearing Anionic Boron Clusters

Published: 17 May 2021

Author(s): María M. Corona‐López, Blanca M. Muñoz‐Flores, Mahdi Chaari, Rosario Nuñez, Víctor M. Jiménez‐Pérez

Abstract Here, we report a short series of six new boron Schiff bases (BOSCHIBAs), four of them bearing anionic boron clusters. The boron complexes (1–2) were synthesized by the multicomponent reaction. The Boron Schiff bases were appropriately functionalized with boron cluster anions [B12H12]2− (3–4) and [3,3’‐Co(C2B9H11)2]− (5–6). Remarkably, BOSCHIBAs bearing [B12H12]2− showed fluorescence emission to the NIR and far‐red regions (3: 747 nm, 4: 690 nm), while 5 and 6 exhibited emission in...

European Journal of Inorganic Chemistry

Reactivity of Copper(I) Complexes Containing Ligands Derived from (1S,3R)‐Camphoric Acid with Dioxygen

Published: 17 May 2021

Author(s): Fabian Stöhr, Niclas Kulhanek, Jonathan Becker, Richard Göttlich, Siegfried Schindler

ChemPhysChem

Cooperativity and Anticooperativity in Ion‐Water Interactions: Implications for the Aqueous Solvation of Ions

Published: 17 May 2021

Author(s): José Manuel Guevara‐Vela, Tomás Rocha‐Rinza, Arturo Sauza‐de la Vega

Abstract Non‐additive effects in hydrogen bonds (HB) take place as a consequence of electronic charge transfers. Therefore, it is natural to expect cooperativity and anticooperativity in ion‐water interactions. Nevertheless, investigations on this matter are scarce. This paper addresses the interactions of (i) the cations Li+, Na+, K+, Be2+, Mg2+, and Ca2+ together with (ii) the anions F−, Cl−, Br−, NO3− and SO42− with water clusters (H2O)n, n=1–8, and the effects of these ions on the HBs...

ChemPlusChem

Cooperative Self‐Assembly in Linear Chains Based on Halogen Bonds

Published: 17 May 2021

Author(s): Pascal Vermeeren, Lando P. Wolters, Gábor Paragi, Célia Fonseca Guerra

European Journal of Inorganic Chemistry

An Isomeric Copper‐Diisophthalate Framework Platform for Storage and Purification of C2H2 and Exploration of the Positional Effect of the Methyl Group

Published: 17 May 2021

Author(s): Yabing He, Jingxian Chen, Simin Hu, Zhenzhen Jiang, Tingting Xu, Ping Zhou, Lihui Fan, Shengjie Lin

Abstract Three isostructural metal‐organic frameworks (MOFs) based on dicopper paddlewheels and dimethyl‐functionalized linear diisophthalate ligands were solvothermally constructed, with the aim to investigate their performance regarding acetylene (C2H2) storage as well as separation and purification and to further understand the positional effect of the weakly polarized methyl functionality. Isotherm measurements and IAST selectivity analyses revealed that the three compounds exhibited the...

Chemistry - A European Journal

Tuning the Size and Geometry of Heteroleptic Coordination Cages by Varying the Ligand Bent Angle

Published: 17 May 2021

Author(s): Ru‐Jin Li, Farzaneh Fadaei‐Tirani, Rosario Scopelliti, Kay Severin

Abstract Spherical assemblies of the type [PdnL2n]2n+ can be obtained from PdII salts and curved N‐donor ligands, L. It is well established that the bent angle, α, of the ligand is a decisive factor in the self‐assembly process, with larger angles leading to complexes with a higher nuclearity, n. Herein, we report heteroleptic coordination cages of the type [PdnLnL′n]2n+, for which a similar correlation between the ligand bent angle and the nuclearity is observed. Tetranuclear cages were...

ChemSusChem

18.4 % Organic Solar Cells Using a High Ionization Energy Self‐Assembled Monolayer as Hole‐Extraction Interlayer

Published: 17 May 2021

Author(s): Yuanbao Lin, Artiom Magomedov, Yuliar Firdaus, Dimitris Kaltsas, Abdulrahman El‐Labban, Hendrik Faber, Dipti R. Naphade, Emre Yengel, Xiaopeng Zheng, Emre Yarali, Neha Chaturvedi, Kalaivanan Loganathan, Despoina Gkeka, Sanaa H. AlShammari, Osman M. Bakr, Frédéric Laquai, Leonidas Tsetseris, Vytautas Getautis, Thomas D. Anthopoulos

Abstract Self‐assembled monolayers (SAMs) based on Br‐2PACz ([2‐(3,6‐dibromo‐9H‐carbazol‐9‐yl)ethyl]phosphonic acid) 2PACz ([2‐(9H‐Carbazol‐9‐yl)ethyl]phosphonic acid) and MeO‐2PACz ([2‐(3,6‐dimethoxy‐9H‐carbazol‐9‐yl)ethyl]phosphonic acid) molecules were investigated as hole‐extracting interlayers in organic photovoltaics (OPVs). The highest occupied molecular orbital (HOMO) energies of these SAMs were measured at −6.01 and −5.30 eV for Br‐2PACz and MeO‐2PACz, respectively, and found to...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

March 2021


	Yunqi Shao, Lisanne Knijff, Florian M. Dietrich, Kersti Hermansson, Chao Zhang Modelling Bulk Electrolytes and Electrolyte Interfaces with Atomistic Machine Learning [Minireview] Batteries & Supercaps 2021, vol. 4, no. 4, p. 585

	Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview] ChemBioChem 2021, vol. 22, no. 7, p. 1176

	Christian M. Heckmann, Francesca Paradisi Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review] ChemCatChem 2020, vol. 12, no. 24, p. 6082

	Gerhard Hilt Basic Strategies and Types of Applications in Organic Electrochemistry [Concept] ChemElectroChem 2020, vol. 7, no. 2, p. 395

	Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

	Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication] ChemistryOpen 2020, vol. 9, no. 7, p. 743

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055

	Antoine Daina, Vincent Zoete A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication] ChemMedChem 2016, vol. 11, no. 11, p. 1117

	Sebastian Gisbertz, Bartholomäus Pieber Heterogeneous Photocatalysis in Organic Synthesis [Review] ChemPhotoChem 2020, vol. 4, no. 7, p. 456

	Trevor A. Hamlin, Marcel Swart, F. Matthias Bickelhaupt Nucleophilic Substitution (S_N2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent [Minireview] ChemPhysChem 2018, vol. 19, no. 11, p. 1315

	Daewoo Han, Andrew J. Steckl Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review] ChemPlusChem 2019, vol. 84, no. 10, p. 1453

	Thomas Aro, Pedram Fatehi Production and Application of Lignosulfonates and Sulfonated Lignin [Review] ChemSusChem 2017, vol. 10, no. 9, p. 1861

	Carolin Hoyer, Peter Schwerk, Lisa Suntrup, Julia Beerhues, Maite Nössler, Uta Albold, Jens Dernedde, Karsten Tedin, Biprajit Sarkar Synthesis, Characterization, and Evaluation of Antibacterial Activity of Ferrocenyl-1,2,3-Triazoles, Triazolium Salts, and Triazolylidene Complexes of Gold(i) and Silver(i) [Full Paper] Eur. J. Inorg. Chem. 2021, p. 1373

	Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

	Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper] Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

	Daojin Zhou, Pengsong Li, Wenwen Xu, Sana Jawaid, Jamesh Mohammed-Ibrahim, Wen Liu, Yun Kuang, Xiaoming Sun Recent Advances in Non-Precious Metal-Based Electrodes for Alkaline Water Electrolysis [Minireview] ChemNanoMat 2020, vol. 6, no. 3, p. 336

	Huaibo Zhao, Daniele Leonori Minimization of Back-Electron Transfer Enables the Elusive sp³ C−H Functionalization of Secondary Anilines [Communication] Angew. Chem. Int. Ed. 2021, vol. 60, no. 14, p. 7669

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

	Özge Çepelioğullar Mutlu, Thomas Zeng Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A Review [Review] Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

	Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland Methane Pyrolysis for CO₂-Free H₂ Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review] Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

	Emiliano Feresin^, Mykhailo Kondratiuk, Julia Nowack, Lukas Gooßen^ Handreinigung auf molekularer Ebene - Die Rolle der Solvatation [Artikel] Chem. Unserer Zeit 2021, vol. 55, no. 1, p. 28

	Hilbert Meyer Guter Unterricht an guten Schulen? [Aufsatz] CHEMKON 2006, vol. 13, no. 2, p. 77

	Bambus in Coffee-to-go-Bechern [Analytik] Lebensmittelchemie 2021, vol. 75, no. 1, p. 2

	Jan Paradies, Jennifer Andexer, Uwe Beifuss, Florian Beuerle, Malte Brasholz, Rolf Breinbauer, Martin Ernst, Ruth Ganardi, Tobias A. M. Gulder, Wolfgang Hüttel, Stephanie Kath-Schorr, Karsten Körber, Markus Kordes, Matthias Lehmann, Thomas Lindel, Burkhard Luy, Christian Mück-Lichtenfeld, Claudia Muhle-Goll, Jochen Niemeyer, Roland Pfau, Jörg Pietruszka, Johannes L. Röckl, Norbert Schaschke, Mathias O. Senge, Bernd F. Straub, Siegfried R. Waldvogel, Thomas Werner, Daniel B. Werz, Christian Winter Organische Chemie [Wissenschaft + Forschung] Nachr. Chem. 2021, vol. 69, no. 3, p. 38

Most cited articles from Chemistry Europe, ACES, and GDCh journals

Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.


	Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication] Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

	Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review] Batteries Supercaps 2018, vol. 1, pp. 41–68

	Lik Hang Yuen, Raphael M. Franzini Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview] ChemBioChem 2017, vol. 18, pp. 829–836

	Konstantinos C. Christoforidis, Paolo Fornasiero Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review] ChemCatChem 2017, vol. 9, pp. 1523–1544

	Marwa Elkady, Hassan Shokry, Hesham Hamad Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article] Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

	Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview] ChemistryOpen 2018, vol. 7, pp. 169–179

	Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, pp. 945–956

	Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe₃O₄@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826

	Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review] Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

	Sayantani Sikdar, Madhusree Kundu A Review on Detection and Abatement of Heavy Metals [Review] ChemBioEng Rev. 2018, vol. 5, pp. 18–29

	Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication] ChemElectroChem 2017, vol. 4, pp. 1840–1845

	Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper] ChemNanoMat 2017, vol. 3, pp. 328–335

	Chengwei Liu, Michal Szostak Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview] Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

	Jian Shu, Dianping Tang Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review] Chem. Asian J. 2017, vol. 12, pp. 2780–2789

	Jian Rong, Chuanfa Ni, Jinbo Hu Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review] Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

	Juan Alberto Sirvent, Ulrich Lücking Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper] ChemMedChem 2017, vol. 12, pp. 487–501

	Grzegorz Greczynski, Lars Hultman C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication] ChemPhysChem 2017, vol. 18, pp. 1507–1512

	Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept] ChemPhotoChem 2017, vol. 1, pp. 148–158

	Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication] ChemSusChem 2017, vol. 10, pp. 87–90

	Enzo Alessio Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview] Eur. J. Inorg. Chem. 2017, pp. 1549–1560

	Marcel Garbe, Kathrin Junge, Matthias Beller Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview] Eur. J. Org. Chem. 2017, pp. 4344–4362