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Chemistry - A European Journal

Coordination‐Driven Selective Formation of D2 Symmetric Octanuclear Organometallic Cages

Published: 17 May 2021

Author(s): Long Zhang, Yue‐Jian Lin, Zhen‐Hua Li, J. Fraser Stoddart, Guo‐Xin Jin

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European Journal of Inorganic Chemistry

Location of Cu Atom in Au‐Based Nanocluster and Its Optical Properties

Published: 17 May 2021

Author(s): Xiuqing Ren, Xuemei Fu, Xinzhang Lin, Jie Tang, He Wang, Chao Liu, Jiahui Huang

Abstract Atomically precise alloy nanoclusters are one of the important nanomaterials, benefiting to investigate the structure‐property correlations at atomic level. Herein, we reported Au19Cu2(SR)15 (SR: adamantanethiol) alloy nanocluster. The crystal structure of Cu−Au nanoclusters was determined by X‐ray crystallography and the molecular mass was further characterized via Fourier transform ion cyclotron resonance mass spectrometer (FT‐ICR‐MS). The crystal structure shows the kernel of...

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Synthesis and Characterisation of Transition Metal Complexes of a Novel 1,5‐benzodiazepine‐Functionalised Tertiary Phosphine

Published: 17 May 2021

Author(s): Sean E. Durran, Mark R. J. Elsegood, Thomas A. Noble, Martin B. Smith, Thomas Gelbrich, Michael B. Hursthouse, Mark E. Light

Abstract The one‐step synthesis (44 % isolated yield) of the 1,5‐benzodiazapine functionalised phosphine 1, C31H31N2OP, is reported. Bridge cleavage of {MCl(μ‐Cl)(η5‐Cp*)}2 (M=Ir, Rh) with 2 equiv. of 1 in CH2Cl2 gave the mononuclear compounds [MCl2(η5‐Cp*)(P‐1)] (M=Ir, 2 a; M=Rh, 2 b) in which 1 functions as a P‐monodentate ligand. Rapid C(sp3)−H bond activation, at room temperature, is observed for 2 a leading to the unusual cyclometallated complex [Ir(η5‐Cp*)(P,N,C‐1)]Cl2 3 (or 3‘) bearing...

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Far‐Red and Near‐Infrared Boron Schiff Bases (BOSCHIBAs) Dyes Bearing Anionic Boron Clusters

Published: 17 May 2021

Author(s): María M. Corona‐López, Blanca M. Muñoz‐Flores, Mahdi Chaari, Rosario Nuñez, Víctor M. Jiménez‐Pérez

Abstract Here, we report a short series of six new boron Schiff bases (BOSCHIBAs), four of them bearing anionic boron clusters. The boron complexes (1–2) were synthesized by the multicomponent reaction. The Boron Schiff bases were appropriately functionalized with boron cluster anions [B12H12]2− (3–4) and [3,3’‐Co(C2B9H11)2]− (5–6). Remarkably, BOSCHIBAs bearing [B12H12]2− showed fluorescence emission to the NIR and far‐red regions (3: 747 nm, 4: 690 nm), while 5 and 6 exhibited emission in...

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Reactivity of Copper(I) Complexes Containing Ligands Derived from (1S,3R)‐Camphoric Acid with Dioxygen

Published: 17 May 2021

Author(s): Fabian Stöhr, Niclas Kulhanek, Jonathan Becker, Richard Göttlich, Siegfried Schindler

thumbnail image: European Journal of Inorganic Chemistry

ChemPhysChem

Cooperativity and Anticooperativity in Ion‐Water Interactions: Implications for the Aqueous Solvation of Ions

Published: 17 May 2021

Author(s): José Manuel Guevara‐Vela, Tomás Rocha‐Rinza, Arturo Sauza‐de la Vega

Abstract Non‐additive effects in hydrogen bonds (HB) take place as a consequence of electronic charge transfers. Therefore, it is natural to expect cooperativity and anticooperativity in ion‐water interactions. Nevertheless, investigations on this matter are scarce. This paper addresses the interactions of (i) the cations Li+, Na+, K+, Be2+, Mg2+, and Ca2+ together with (ii) the anions F−, Cl−, Br−, NO3− and SO42− with water clusters (H2O)n, n=1–8, and the effects of these ions on the HBs...

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ChemPlusChem

Cooperative Self‐Assembly in Linear Chains Based on Halogen Bonds

Published: 17 May 2021

Author(s): Pascal Vermeeren, Lando P. Wolters, Gábor Paragi, Célia Fonseca Guerra

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European Journal of Inorganic Chemistry

An Isomeric Copper‐Diisophthalate Framework Platform for Storage and Purification of C2H2 and Exploration of the Positional Effect of the Methyl Group

Published: 17 May 2021

Author(s): Yabing He, Jingxian Chen, Simin Hu, Zhenzhen Jiang, Tingting Xu, Ping Zhou, Lihui Fan, Shengjie Lin

Abstract Three isostructural metal‐organic frameworks (MOFs) based on dicopper paddlewheels and dimethyl‐functionalized linear diisophthalate ligands were solvothermally constructed, with the aim to investigate their performance regarding acetylene (C2H2) storage as well as separation and purification and to further understand the positional effect of the weakly polarized methyl functionality. Isotherm measurements and IAST selectivity analyses revealed that the three compounds exhibited the...

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Chemistry - A European Journal

Tuning the Size and Geometry of Heteroleptic Coordination Cages by Varying the Ligand Bent Angle

Published: 17 May 2021

Author(s): Ru‐Jin Li, Farzaneh Fadaei‐Tirani, Rosario Scopelliti, Kay Severin

Abstract Spherical assemblies of the type [PdnL2n]2n+ can be obtained from PdII salts and curved N‐donor ligands, L. It is well established that the bent angle, α, of the ligand is a decisive factor in the self‐assembly process, with larger angles leading to complexes with a higher nuclearity, n. Herein, we report heteroleptic coordination cages of the type [PdnLnL′n]2n+, for which a similar correlation between the ligand bent angle and the nuclearity is observed. Tetranuclear cages were...

thumbnail image: Chemistry - A European Journal

ChemSusChem

18.4 % Organic Solar Cells Using a High Ionization Energy Self‐Assembled Monolayer as Hole‐Extraction Interlayer

Published: 17 May 2021

Author(s): Yuanbao Lin, Artiom Magomedov, Yuliar Firdaus, Dimitris Kaltsas, Abdulrahman El‐Labban, Hendrik Faber, Dipti R. Naphade, Emre Yengel, Xiaopeng Zheng, Emre Yarali, Neha Chaturvedi, Kalaivanan Loganathan, Despoina Gkeka, Sanaa H. AlShammari, Osman M. Bakr, Frédéric Laquai, Leonidas Tsetseris, Vytautas Getautis, Thomas D. Anthopoulos

Abstract Self‐assembled monolayers (SAMs) based on Br‐2PACz ([2‐(3,6‐dibromo‐9H‐carbazol‐9‐yl)ethyl]phosphonic acid) 2PACz ([2‐(9H‐Carbazol‐9‐yl)ethyl]phosphonic acid) and MeO‐2PACz ([2‐(3,6‐dimethoxy‐9H‐carbazol‐9‐yl)ethyl]phosphonic acid) molecules were investigated as hole‐extracting interlayers in organic photovoltaics (OPVs). The highest occupied molecular orbital (HOMO) energies of these SAMs were measured at −6.01 and −5.30 eV for Br‐2PACz and MeO‐2PACz, respectively, and found to...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

March 2021

 


Yunqi Shao, Lisanne Knijff, Florian M. Dietrich, Kersti Hermansson, Chao Zhang
Modelling Bulk Electrolytes and Electrolyte Interfaces with Atomistic Machine Learning [Minireview]
Batteries & Supercaps 2021, vol. 4, no. 4, p. 585

Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll
Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview]
ChemBioChem 2021, vol. 22, no. 7, p. 1176

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Gerhard Hilt
Basic Strategies and Types of Applications in Organic Electrochemistry [Concept]
ChemElectroChem 2020, vol. 7, no. 2, p. 395

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Sebastian Gisbertz, Bartholomäus Pieber
Heterogeneous Photocatalysis in Organic Synthesis [Review]
ChemPhotoChem 2020, vol. 4, no. 7, p. 456

Trevor A. Hamlin, Marcel Swart, F. Matthias Bickelhaupt
Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent [Minireview]
ChemPhysChem 2018, vol. 19, no. 11, p. 1315

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Thomas Aro, Pedram Fatehi
Production and Application of Lignosulfonates and Sulfonated Lignin [Review]
ChemSusChem 2017, vol. 10, no. 9, p. 1861

Carolin Hoyer, Peter Schwerk, Lisa Suntrup, Julia Beerhues, Maite Nössler, Uta Albold, Jens Dernedde, Karsten Tedin, Biprajit Sarkar
Synthesis, Characterization, and Evaluation of Antibacterial Activity of Ferrocenyl-1,2,3-Triazoles, Triazolium Salts, and Triazolylidene Complexes of Gold(i) and Silver(i) [Full Paper]
Eur. J. Inorg. Chem. 2021, p. 1373

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama
Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper]
Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

Daojin Zhou, Pengsong Li, Wenwen Xu, Sana Jawaid, Jamesh Mohammed-Ibrahim, Wen Liu, Yun Kuang, Xiaoming Sun
Recent Advances in Non-Precious Metal-Based Electrodes for Alkaline Water Electrolysis [Minireview]
ChemNanoMat 2020, vol. 6, no. 3, p. 336

Huaibo Zhao, Daniele Leonori
Minimization of Back-Electron Transfer Enables the Elusive sp3 C−H Functionalization of Secondary Anilines [Communication]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 14, p. 7669

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Emiliano Feresin*, Mykhailo Kondratiuk, Julia Nowack, Lukas Gooßen*
Handreinigung auf molekularer Ebene - Die Rolle der Solvatation [Artikel]
Chem. Unserer Zeit 2021, vol. 55, no. 1, p. 28

Hilbert Meyer
Guter Unterricht an guten Schulen? [Aufsatz]
CHEMKON 2006, vol. 13, no. 2, p. 77

Bambus in Coffee-to-go-Bechern [Analytik]
Lebensmittelchemie 2021, vol. 75, no. 1, p. 2

Jan Paradies, Jennifer Andexer, Uwe Beifuss, Florian Beuerle, Malte Brasholz, Rolf Breinbauer, Martin Ernst, Ruth Ganardi, Tobias A. M. Gulder, Wolfgang Hüttel, Stephanie Kath-Schorr, Karsten Körber, Markus Kordes, Matthias Lehmann, Thomas Lindel, Burkhard Luy, Christian Mück-Lichtenfeld, Claudia Muhle-Goll, Jochen Niemeyer, Roland Pfau, Jörg Pietruszka, Johannes L. Röckl, Norbert Schaschke, Mathias O. Senge, Bernd F. Straub, Siegfried R. Waldvogel, Thomas Werner, Daniel B. Werz, Christian Winter
Organische Chemie [Wissenschaft + Forschung]
Nachr. Chem. 2021, vol. 69, no. 3, p. 38

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.

 


Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review]
Batteries Supercaps 2018, vol. 1, pp. 41–68

Lik Hang Yuen, Raphael M. Franzini
Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview]
ChemBioChem 2017, vol. 18, pp. 829–836

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, pp. 1523–1544

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, pp. 945–956

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen
Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication]
ChemElectroChem 2017, vol. 4, pp. 1840–1845

Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang
Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper]
ChemNanoMat 2017, vol. 3, pp. 328–335

Chengwei Liu, Michal Szostak
Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview]
Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

Jian Shu, Dianping Tang
Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review]
Chem. Asian J. 2017, vol. 12, pp. 2780–2789

Jian Rong, Chuanfa Ni, Jinbo Hu
Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

Juan Alberto Sirvent, Ulrich Lücking
Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper]
ChemMedChem 2017, vol. 12, pp. 487–501

Grzegorz Greczynski, Lars Hultman
C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication]
ChemPhysChem 2017, vol. 18, pp. 1507–1512

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, pp. 148–158

Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang
Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication]
ChemSusChem 2017, vol. 10, pp. 87–90

Enzo Alessio
Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview]
Eur. J. Inorg. Chem. 2017, pp. 1549–1560

Marcel Garbe, Kathrin Junge, Matthias Beller
Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview]
Eur. J. Org. Chem. 2017, pp. 4344–4362

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH