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ChemCatChem

Stereo‐ and Regioselective Cu‐Catalyzed Hydroboration of Alkynyl Chalcogenoethers

Published: 25 May 2020

Author(s): Isadora M. Oliveira, Henrique A. Esteves, Mariana P. Darbem, Arthur Sartorelli, Thiago C. Correra, André F. Rodrigues‐Oliveira, Daniel C. Pimenta, Julio Zukerman‐Schpector, Flávia Manarin, Hélio A. Stefani

Abstract A mild stereo‐ and regioselective Cu‐catalyzed hydroboration method for the synthesis of (Z)‐seleno‐alkenyl boronates and (Z)‐thio‐alkenylboronates from internal alkynes in the presence of commercially available B2pin2 is presented. This highly selective transformation relies on the use of N‐heterocyclic carbene (NHC) complex IPrCuCl as the active catalytic species. We also explore the functionalization of the alkenylboronates obtained via oxidation to give α‐chalcogeno ketones,...

ChemPhysChem

Preparation of Long‐Lived States in a Multi‐Spin System by Using an Optimal Control Method

Published: 25 May 2020

Author(s): Daxiu Wei, Jiaxiang Xin, Kairui Hu, Yefeng Yao

Abstract The lifetime Ts of a long‐lived nuclear spin state (LLS) could be much longer than the longitudinal order T1. Many spin systems were used to produce long‐lived states, including two or more homonuclear spins that couple to each other. For multiple homonuclear spins with rather small chemical shift difference, normally it is difficult to selectively control the spins and then to prepare a LLS. Herein, we present a scheme that prepares different spin orders in a multi‐spin system by...

ChemCatChem

Selective Oxyfunctionalisation Reactions Driven by Sulfite Oxidase‐Catalysed In Situ Generation of H2O2

Published: 25 May 2020

Author(s): Morten M. C. H. Schie, Alexander T. Kaczmarek, Florian Tieves, Patricia Gomez de Santos, Caroline E. Paul, Isabel W. C. E. Arends, Miguel Alcalde, Günter Schwarz, Frank Hollmann

ChemCatChem

Titania Morphology‐Dependent Catalysis of CuOx/TiO2 Catalysts in CO Oxidation and Water Gas Shift Reactions

Published: 25 May 2020

Author(s): Zongyou Yu, Zhenhua Zhang, Yunshang Zhang, Weixin Huang

Abstract CuOx/TiO2 nanocatalysts (x=0 or 1) with ∼11 % wt. Cu loading employing TiO2 nanocrystals with various morphologies predominantly exposing {001}, {100}, and {101} facets as supports have been synthesized as catalysts for CO oxidation with excess of O2 (oxidative atmosphere) and water gas shift (WGS) reaction (reductive atmosphere). Strong TiO2 morphology effects were observed. The strongest Cu2O−TiO2 interaction was observed in CuO−TiO2{001} nanocatalyst, while the strongest Cu‐TiO2...

European Journal of Organic Chemistry

Transition‐Metal Catalyzed Stereoselective γ‐Arylation and Friedel‐Crafts Alkylation: A Concise Synthesis of Indenes

Published: 25 May 2020

Author(s): Karu Ramesh, Gedu Satyanarayana

A highly stereoselective [Pd]‐catalyzed arylation of tert‐alkenols, is presented and applied to the synthesis of indenes using intramolecular Friedel–Crafts alkylation sequence. The initial Heck reaction is performed by using water as the green solvent. A simple acid triggers intramolecular alkylation in short reaction times at room temperature. Notably, indenes have been accomplished using a single column chromatography technique.

thumbnail image: European Journal of Organic Chemistry

Chemistry - A European Journal

Rhodium Nanoparticles as a Novel Photosensitizing Agent in Photodynamic Therapy against Cancer

Published: 25 May 2020

Author(s): Andres Machuca, Estefania Garcia‐Calvo, Daniela S. Anunciação, Jose L. Luque‐Garcia

Abstract Photodynamic therapy (PDT) is a promising alternative treatment for different types of cancer due to its high selectivity, which prevents healthy tissues from being damaged. The use of nanomaterials in PDT has several advantages over classical photosensitizing agents, due to their unique properties and their capacity for functionalization. Especially interesting is the use of metallic nanoparticles, which are capable of absorbing electromagnetic radiation and either transferring this...

Chemistry - A European Journal

Cationic Carbosilane Dendritic Systems as Promising Anti‐Amyloid Agents in Type 2 Diabetes

Published: 25 May 2020

Author(s): Tania Lozano‐Cruz, Gema Alcarraz‐Vizán, F. Javier Mata, Sara Pablo, Paula Ortega, Yorley Duarte, Felipe Bravo‐Moraga, Fernando D. González‐Nilo, Anna Novials, Rafael Gómez

Abstract The most common denominator of many of the neurodegenerative diseases is badly folded protein accumulation, which results in the formation of insoluble protein deposits located in different parts of the organism, causing cell death and tissue degeneration. Dendritic systems have turned out to be a promising new therapeutic approach for the treatment of these diseases due to their ability to modulate the folding of these proteins. With this perspective, and focused on type 2 diabetes...

ChemSusChem

Valorization of Plastic Wastes for the Synthesis of Imidazolium‐Based Self‐Supported Elastomeric Ionenes

Published: 25 May 2020

Author(s): Jeremy Demarteau, Kathryn E. O'Harra, Jason E. Bara, Haritz Sardon

Abstract Imidazolium‐based ionenes are known to be high‐performance materials for a great variety of applications. The preparation of these polymers requires the use of bis‐imidazole starting monomers, which are commonly prepared by using toxic chloride reagents. In this study, bis‐imidazole monomers are synthesized by organocatalytic chemical recycling of discarded plastics through chemical depolymerization. By using poly(ethylene terephthalate) and bisphenol A polycarbonate as starting...

ChemSusChem

Research Progress in Lignin‐Based Slow/Controlled Release Fertilizer

Published: 25 May 2020

Author(s): Jing Chen, Xiaolin Fan, Lidan Zhang, Xiaojuan Chen, Shaolong Sun, Run‐Cang Sun

Abstract As a skeleton component of plants, lignin is an organic macromolecule polymer that can be regenerated and naturally degraded. Annually, plant growth produces about 150 billion tons of lignin. In industrial processes such as paper and biomass‐refining industry, large amounts of lignin are formed as by‐products. Most of technical lignins are directly combusted to obtain heat, which not only is a waste of organic matter but also leads to environmental pollution and other issues....

ChemSusChem

Transition Metal Phosphide‐Based Materials for Efficient Electrochemical Hydrogen Evolution: A Critical Review

Published: 25 May 2020

Author(s): Chen‐Chen Weng, Jin‐Tao Ren, Zhong‐Yong Yuan

Abstract As hydrogen has been increasingly considered as promising sustainable energy supply, electrochemical overall water splitting driven by highly efficient non‐noble metal electrocatalysts has aroused extensive attention. Transition metal phosphides (TMPs) have demonstrated remarkable electrocatalytic performance, including high activity and robust durability towards hydrogen evolution reaction (HER) in acidic and alkaline as well as neutral electrolytes. In this Review, up‐to‐date...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

January 2020


	Hendrik Naatz, Bella B. Manshian, Carla Rios Luci, Vasiliki Tsikourkitoudi, Yiannis Deligiannakis, Johannes Birkenstock, Suman Pokhrel, Lutz Mädler, Stefaan J. Soenen Model-Based Nanoengineered Pharmacokinetics of Iron-Doped Copper Oxide for Nanomedical Applications [Research Article] Angew. Chem. Int. Ed. 2020, vol. 59, no. 5, p. 1828

	Marc-André Kasper, Marcus Gerlach, Anselm F. L. Schneider, Christiane Groneberg, Philipp Ochtrop, Stefanie Boldt, Dominik Schumacher, Jonas Helma, Heinrich Leonhardt, Mathias Christmann, Christian P. R. Hackenberger N-Hydroxysuccinimide-Modified Ethynylphosphonamidates Enable the Synthesis of Configurationally Defined Protein Conjugates [Full Paper] ChemBioChem 2020, vol. 21, no. 1-2, p. 113

	Michael Bowker Methanol Synthesis from CO₂ Hydrogenation [Minireview] ChemCatChem 2019, vol. 11, no. 17, p. 4238

	V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article] Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

	Dieter Wöhrle Kunststoffe [Artikel] Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 50

	Balaram Mukhopadhyay, Rituparna Das Chemical O-Glycosylations: An Overview [Review] ChemistryOpen 2016, vol. 5, no. 5, p. 401

	Daewoo Han, Andrew J. Steckl Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review] ChemPlusChem 2019, vol. 84, no. 10, p. 1453

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055

	Rüdiger-A. Eichel, Walter Leitner, Kurt Wagemann Warum wir uns mit Power-to-X beschäftigen [Editorial] Chem. Ing. Tech. 2020, vol. 92, no. 1-2, p. 3

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

	Gerhard Hilt Basic Strategies and Types of Applications in Organic Electrochemistry [Concept] ChemElectroChem 2020, vol. 7, no. 2, p. 395

	Claire M. Cobley Introducing our Inaugural Early Career Advisory Board [Editorial] ChemNanoMat 2020, vol. 6, no. 1, p. 4

	Felix Blei, Sebastian Dörner, Janis Fricke, Florian Baldeweg, Felix Trottmann, Anna Komor, Florian Meyer, Christian Hertweck, Dirk Hoffmeister Simultaneous Production of Psilocybin and a Cocktail of β-Carboline Monoamine Oxidase Inhibitors in “Magic” Mushrooms [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 3, p. 729

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

	Arun K. Sinha, Danish Equbal Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review] Asian J. Org. Chem. 2019, vol. 8, no. 1, p. 32

	Thomas H. Pillow, Pragya Adhikari, Robert A. Blake, Jinhua Chen, Geoffrey Del Rosario, Gauri Deshmukh, Isabel Figueroa, Karen E. Gascoigne, Amrita V. Kamath, Susan Kaufman, Tracy Kleinheinz, Katherine R. Kozak, Brandon Latifi, Douglas D. Leipold, Chun Sing Li, Ruina Li, Melinda M. Mulvihill, Aimee O'Donohue, Rebecca K. Rowntree, Jack D. Sadowsky, John Wai, Xinxin Wang, Cong Wu, Zijin Xu, Hui Yao, Shang-Fan Yu, Donglu Zhang, Richard Zang, Hongyan Zhang, Hao Zhou, Xiaoyu Zhu, Peter S. Dragovich Antibody Conjugation of a Chimeric BET Degrader Enables in vivo Activity [Full Paper] ChemMedChem 2020, vol. 15, no. 1, p. 17

	Vitali Tugarinov, Theodoros K. Karamanos, Alberto Ceccon, G. Marius Clore Optimized NMR Experiments for the Isolation of I=1/2 Manifold Transitions in Methyl Groups of Proteins [Communication] ChemPhysChem 2020, vol. 21, no. 1, p. 13

	Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review] ChemPhotoChem 2018, vol. 2, no. 5, p. 386

	Kassem Beydoun, Jürgen Klankermayer Efficient Plastic Waste Recycling to Value-Added Products by Integrated Biomass Processing [Communication] ChemSusChem 2020, vol. 13, no. 3, p. 488

	Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief The Periodic Table of the Chemical Elements and Sustainable Development [Essay] Eur. J. Inorg. Chem. 2019, p. 4170

	Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056

	Cover Picture Lebensmittelchemie 6/2019 [Cover Picture] Lebensmittelchemie 2019, vol. 73, no. 6

	Christian Hering-Junghans, Christian Sindlinger Trendbericht Anorganische Chemie: Hauptgruppen [Wissenschaft + Forschung] Nachr. Chem. 2020, vol. 68, no. 1, p. 50

	Jana Novotny, Corina Wagner, Marco Oetken Titelbild: Elektrochemisch aktive Polymere am Beispiel Polypyrrol: Modellsystem einer künstlichen Synapse Ein elektrochemischer Alleskönner - Teil 2 (CHEMKON 8/2019) [Titelbild] CHEMKON 2019, vol. 26, no. 8, p. 331

	Meng Cheng, Ramasubramonian Deivanayagam, Reza Shahbazian-Yassar 3D Printing of Electrochemical Energy Storage Devices: A Review of Printing Techniques and Electrode/Electrolyte Architectures [Review] Batteries & Supercaps 2020, vol. 3, no. 2, p. 130

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from Chemistry Europe, ACES, and GDCh journals

Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.


	Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication] Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

	Lik Hang Yuen, Raphael M. Franzini Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview] ChemBioChem 2017, vol. 18, pp. 829–836

	Konstantinos C. Christoforidis, Paolo Fornasiero Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review] ChemCatChem 2017, vol. 9, pp. 1523–1544

	Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview] ChemistryOpen 2018, vol. 7, pp. 169–179

	Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, pp. 945–956

	Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe₃O₄@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826

	Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication] ChemElectroChem 2017, vol. 4, pp. 1840–1845

	Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper] ChemNanoMat 2017, vol. 3, pp. 328–335

	Chengwei Liu, Michal Szostak Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview] Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

	Jian Shu, Dianping Tang Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review] Chem. Asian J. 2017, vol. 12, pp. 2780–2789

	Jian Rong, Chuanfa Ni, Jinbo Hu Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review] Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

	Juan Alberto Sirvent, Ulrich Lücking Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper] ChemMedChem 2017, vol. 12, pp. 487–501

	Grzegorz Greczynski, Lars Hultman C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication] ChemPhysChem 2017, vol. 18, pp. 1507–1512

	Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept] ChemPhotoChem 2017, vol. 1, pp. 148–158

	Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication] ChemSusChem 2017, vol. 10, pp. 87–90

	Enzo Alessio Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview] Eur. J. Inorg. Chem. 2017, pp. 1549–1560

	Marcel Garbe, Kathrin Junge, Matthias Beller Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview] Eur. J. Org. Chem. 2017, pp. 4344–4362

	Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review] Batteries Supercaps 2018, vol. 1, pp. 41–68

	Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe₃O₄@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826