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ChemSusChem

Electrochemical Hydrogen Evolution Reaction Efficiently Catalyzed by Ru ₂ P Nanoparticles

Published: 12 July 2018

Author(s): Yuan Wang, Zong Liu, Hui Liu, Nian‐Tzu Suen, Xu Yu, Ligang Feng

Abstract Developing alternatives to Pt catalysts is a prerequisite to cost‐effectively produce hydrogen. Herein, we demonstrate Ru2P nanoparticles (without any doping and modifications) as a highly efficient Pt‐like catalyst for the hydrogen evolution reaction (HER) in different pH electrolytes. On transferring the hexagonal close‐packed crystal structure of Ru to the orthorhombic structure of Ru2P, a greatly improved catalytic activity and...

ChemSusChem

Iron(III) N , N ‐Dialkylcarbamate‐Catalyzed Formation of Cyclic Carbonates from CO ₂ and Epoxides under Ambient Conditions by Dynamic CO ₂ Trapping as Carbamato Ligands

Published: 12 July 2018

Author(s): Giulio Bresciani, Marco Bortoluzzi, Fabio Marchetti, Guido Pampaloni

Abstract Easily available and inexpensive FeIII carbamates were employed in the solvent‐free synthesis of a series of cyclic carbonates from epoxides and CO2 at room temperature and atmospheric pressure, in the presence of a cocatalyst. Different experimental conditions (type and concentration of catalyst and cocatalyst, as well as reaction time) were investigated: Fe(O2CNEt2)3 and NBu4Br acted as the best catalyst/cocatalyst combination, allowing the...

ChemSusChem

Hierarchical Nickel–Cobalt‐Based Transition Metal Oxide Catalysts for the Electrochemical Conversion of Biomass into Valuable Chemicals

Published: 12 July 2018

Author(s): Lifang Gao, Yu Bao, Shiyu Gan, Zhonghui Sun, Zhongqian Song, Dongxue Han, Fenghua Li, Li Niu

Abstract The upgrading of biomass into sustainable and valuable fine chemicals is an alternative to the use of state‐of‐the‐art petrochemicals. The conversion of 5‐hydroxymethylfurfural (HMF) biomass derivative into 2,5‐furandicarboxylic acid (FDCA) has been recognized as an economical and green approach to replace the current polyethylene terephthalate based plastic industry. However, this reaction mostly relies on...

Chemistry - A European Journal

Corrigendum: Chiral Lithium Amido Zincates for Enantioselective 1,2‐Additions: Auto‐assembling Reagents Involving a Fully Recyclable Ligand

Published: 12 July 2018

Author(s): Mathieu Rouen, Pauline Chaumont, Gabriella Barozzino‐Consiglio, Jacques Maddaluno, Anne Harrison‐Marchand

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European Journal of Organic Chemistry

Georgios Vassilikogiannakis

Published: 12 July 2018

Abstract “Achieving greater sustainability in chemistry …” Find out more about this author's research at https://doi.org/10.1002/ejoc.201800832.

thumbnail image: European Journal of Organic Chemistry

European Journal of Inorganic Chemistry

Cover Feature: Catalytic Degradation of Orange II by Mn ^III (TPPS) in Basic Hydrogen Peroxide Medium: A Detailed Kinetic Analysis (Eur. J. Inorg. Chem. /2018)

Published: 12 July 2018

Author(s): Magdalena Procner, Łukasz Orzeł, Grażyna Stochel, Rudi van Eldik

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ChemSusChem

Iridium‐Coordinated Histidyl Bolaamphiphile Self‐Assemblies as Heterogeneous Catalysts for Water Oxidation

Published: 12 July 2018

Author(s): Changjoon Keum, Sang‐Yup Lee

Abstract Catalysts that can promote oxygen evolution from water are necessary for green energy production. In this study, colloidal heterogeneous catalysts for oxygen evolution were prepared by coordination of Ir species to self‐assemblies of histidyl bolaamphiphiles. When dissolved in water, the histidyl bolaamphiphiles self‐assembled to form particulate structures with the exposure of densely packed histidine imidazoles on their...

ChemPhysChem

Practical Guidelines for Shell‐Isolated Nanoparticle‐Enhanced Raman Spectroscopy of Heterogeneous Catalysts

Published: 11 July 2018

Author(s): Thomas Hartman, Caterina S. Wondergem, Bert M. Weckhuysen

Abstract Shell‐isolated nanoparticle‐enhanced Raman spectroscopy (SHINERS) has proven to be a useful characterization tool for heterogeneous catalysis research. The advantage of SHINERS lies in studying surface reactions on solid catalysts, including the detection of reactants, intermediates and products, in real time. However, due to the extremely strong local electric fields, minor amounts of contaminants can already have a big...

ChemPhysChem

Boron Centres Allow Design, Control and Systematic Tuning of Neutral Homoaromatics for Functionalization Purposes

Published: 11 July 2018

Author(s): James D. Mattock, Alfredo Vargas

Abstract Homoaromatic compounds are currently viewed mainly as an interesting novelty with little to no practical application. Based on calculations within density functional theory, we show that the unique charge redirection properties of tricoordinate boron, along with it being isolobal to a carbocation, allow for a larger range of two‐electron donors to be utilized, leading to the rational design of homoaromatic compounds better...

ChemMedChem

Development of Potent Pyrazolopyrimidinone‐Based WEE1 Inhibitors with Limited Single‐Agent Cytotoxicity for Cancer Therapy

Published: 11 July 2018

Author(s): Christopher J. Matheson, Kimberly A. Casalvieri, Donald S. Backos, Philip Reigan

Abstract WEE1 kinase regulates the G2/M cell‐cycle checkpoint, a critical mechanism for DNA repair in cancer cells that can confer resistance to DNA‐damaging agents. We previously reported a series of pyrazolopyrimidinones based on AZD1775, a known WEE1 inhibitor, as an initial investigation into the structural requirements for WEE1 inhibition. Our lead inhibitor demonstrated WEE1 inhibition in the same nanomolar range as AZD1775,...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

June 2018


	Saki Ichikawa, Shaolin Zhu, Stephen L. Buchwald A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination [Communication] Angew. Chem. Int. Ed. 2018, vol. 57, p. 8714

	Parker Nichols, Alexandra Born, Morkos Henen, Dean Strotz, Celestine N Chi, Peter Güntert, Beat Rolf Vögeli Extending the Applicability of Exact Nuclear Overhauser Enhancements to Large Proteins and RNA [Minireview] ChemBioChem 2018

	Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper] ChemCatChem 2011, vol. 3, p. 1159

	Klaus Roth Die Suche nach dem Blau der „Blauen Blume“ [Artikel] Chem. Unserer Zeit 2018, vol. 52, p. 192

	Balaram Mukhopadhyay, Rituparna Das Chemical O-Glycosylations: An Overview [Review] ChemistryOpen 2016, vol. 5, p. 401

	Philip C. Andrews, Lisandra L. Martin, Alexandr N. Simonov Leone Spiccia Memorial Issue [Editorial] ChemPlusChem 2018, vol. 83, p. 548

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, p. 6055

	Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen Regulatory Aspects of Nanomaterials in the EU [Research Article] Chem. Ing. Tech. 2017, vol. 89, p. 224

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, p. 75

	Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review] ChemElectroChem 2018, vol. 5, p. 6

	Santosh K. Tiwari, Raghvendra Kumar Mishra, Sung Kyu Ha, Andrzej Huczko Evolution of Graphene Oxide and Graphene: From Imagination to Industrialization [Focus Review] ChemNanoMat 2018, vol. 4, p. 598

	R. Aleyda Garza-Sanchez, Tuhin Patra, Adrian Tlahuext-Aca, Felix Strieth-Kalthoff, Frank Glorius DMSO as a Switchable Alkylating Agent in Heteroarene C−H Functionalization [Communication] Chem. Eur. J. 2018

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, p. 2696

	Yunhe Jin, Hua Fu Visible-Light Photoredox Decarboxylative Couplings [Focus Review] Asian J. Org. Chem. 2017, vol. 6, p. 368

	Christopher J Matheson, Kimberly A Casalvieri, Donald S Backos, Philip Reigan Development of potent pyrazolopyrimidinone-based WEE1 inhibitors with limited single-agent cytotoxicity for cancer therapy [Full Paper] ChemMedChem 2018

	Gloria Tabacchi Supramolecular Organization in Confined Nanospaces [Review] ChemPhysChem 2018, vol. 19, p. 1249

	Emily B. Corcoran, François Lévesque, Jonathan P. McMullen, John R. Naber Studies Toward the Scaling of Gas-Liquid Photocycloadditions [Article] ChemPhotoChem 2018

	An-Na Cho, Nam-Gyu Park Impact of Interfacial Layers in Perovskite Solar Cells [Review] ChemSusChem 2017, vol. 10, p. 3687

	Ross J. Marshall, Ross S. Forgan Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview] Eur. J. Inorg. Chem. 2016, p. 4310

	Romaric Gérardy, Noémie Emmanuel, Thomas Toupy, Victor-Emmanuel Kassin, Nelly Ntumba Tshibalonza, Michaël Schmitz, Jean-Christophe M. Monbaliu Continuous Flow Organic Chemistry: Successes and Pitfalls at the Interface with Current Societal Challenges [Microreview] Eur. J. Org. Chem. 2018, p. 2301

	46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung] Lebensmittelchemie 2018, vol. 72, p. 1

	Markus Hiebel, Katharina Reh Kreislaufwirtschaft: Von Anfang an ans Ende denken [Industrie & Technik] Nachr. Chem. 2018, vol. 66, p. 606

	Alexander Engl, Alexandra Schmelzer, Björn Risch Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel] CHEMKON 2018, vol. 25, p. 7

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal

2016


	Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

	Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke Fluorescent Probes for G-Quadruplex Structures [Review] ChemBioChem 2013, vol. 14, pp. 540–558

	Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75

	Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

	Marc Steinmetz, Stefan Grimme Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper] ChemistryOpen 2013, vol. 2, pp. 115–124

	Philipp Scharf, Jens Müller Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review] ChemPlusChem 2013, vol. 78, pp. 20–34

	Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess Production of Liquid Hydrocarbons with CO₂ as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article] Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

	Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86

	Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127

	Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper] Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

	Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp²)–H Bonds [Focus Review] Chem. Asian J. 2014, vol. 9, pp. 26–47

	Naohiko Yoshikai, Ye Wei Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review] Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

	Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper] ChemMedChem 2013, vol. 8, pp. 313–321

	Peter Politzer, Jane S. Murray Halogen Bonding: An Interim Discussion [Review] ChemPhysChem 2013, vol. 14, pp. 278–294

	Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review] ChemSusChem 2013, vol. 6, pp. 746–789

	Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou Spin Crossover at the Nanometre Scale [Microreview] Eur. J. Inorg. Chem. 2013, pp. 653–661

	Junichiro Yamaguchi, Kei Muto, Kenichiro Itami Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview] Eur. J. Org. Chem. 2013, pp. 19–30

	David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar Mit Klick zu neuen Liganden [Magazin] Nachr. Chem. 2011, vol. 59, pp. 937–941