ChemPubSoc Europe Early View Journal Articles
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Chemistry - A European Journal
Published: 21 January 2021
Author(s): Fred U. Nnamdi, Colin Diner, Pier Alexandre Champagne, Michael G. Organ
Abstract Two similar tridentate directing groups derived from glycine and 8‐aminoquinoline were shown to enable the palladium‐catalyzed anti‐Markovnikov hydrofunctionalization of 4‐pentenylamine with drastically different efficiencies. A computational investigation into the origin of the reactivity difference between these isomeric, carbonyl‐transposed auxiliaries suggests that protonation state, thus charge of the substrate‐metal complex prior to nucleopalladation is key. These investigations...
Chemistry - A European Journal
Isolation and Structural Determination of a Hexacoordinated Antimony(V) Dication
Published: 21 January 2021
Author(s): Masato Sakabe, Soichi Sato
Abstract The hexacoordinated antimony(V) dication [(ppy)3Sb]2+ ([1]2+; ppy=2‐(2‐pyridyl)phenyl), stabilized by three intramolecular donor–acceptor interactions, has been isolated as its hexachloroantimonate salt [1][SbCl6]2, prepared by the oxidative addition of chlorine to the neutral stibine [(ppy)3Sb] (1), followed by the abstraction of chloride. Air‐stable [1][SbCl6]2 exhibits remarkable thermal stability and the three ppy ligands on the antimony atom are shown to be magnetically...
Chemistry - A European Journal
Published: 21 January 2021
Author(s): Danny Lainé, Olivier Lessard, Jacob St‐Gelais, Denis Giguère
Abstract There is growing interest in the preparation of fluorine‐containing organic molecules. Multivicinal‐fluorine analogues are among the most intriguing and promising compounds, but their physical and biological investigations are held back by challenging syntheses. Herein, we report on the synthesis of a large set of novel polyfluorohexitols. The dominant solution‐state conformation of all trifluorohexitols was determined, and the solid‐state conformations of some analogues were...
Chemistry - A European Journal
How Oriented External Electric Fields Modulate Reactivity
Published: 21 January 2021
Author(s): Song Yu, Pascal Vermeeren, Trevor A. Hamlin, F. Matthias Bickelhaupt
Abstract A judiciously oriented external electric field (OEEF) can catalyze a wide range of reactions and can even induce endo/exo stereoselectivity of cycloaddition reactions. The Diels–Alder reaction between cyclopentadiene and maleic anhydride is studied by using quantitative activation strain and Kohn–Sham molecular orbital theory to pinpoint the origin of these catalytic and stereoselective effects. Our quantitative model reveals that an OEEF along the reaction axis induces an enhanced...
Chemistry - A European Journal
Published: 21 January 2021
Author(s): Jorge Juan Cabrera‐Trujillo, Israel Fernández
Abstract The activation of a single C−F bond in di‐ and trifluoromethyl groups by frustrated Lewis pairs (FLPs) has been computationally explored by means of Density Functional Theory calculations. It is found that in this activation reaction the FLP partners exhibit a peculiar cooperative action, which is markedly different from related FLP‐mediated processes, and where non‐covalent interactions established between the Lewis base and the substrate play a decisive role. In addition, the...
Chemistry - A European Journal
Nonclassical Abramov Products Formed on Orifices of Cage‐Opened C60 Derivatives
Published: 21 January 2021
Author(s): Yoshifumi Hashikawa, Shu Okamoto, Yasujiro Murata
Chemistry - A European Journal
Published: 21 January 2021
Author(s): Kensuke Suzuki, Yoshihiro Nishimoto, Makoto Yasuda
Abstract Invited for the cover of this issue are Kensuke Suzuki, Yoshihiro Nishimoto and Makoto Yasuda from Osaka University. The image depicts a circus trapeze act, with different elements of the picture representing components of the borylation reaction reported in this work. Read the full text of the article at 10.1002/chem.202004692.
ChemSusChem
Electrodeposited Trimetallic NiFeW Hydroxide Electrocatalysts for Efficient Water Oxidation
Published: 21 January 2021
Author(s): Rajmohan Rajendiran, Deviprasath Chinnadurai, Kai Chen, Aravindha Raja Selvaraj, Kandasamy Prabakar, Oi Lun Li
Abstract Tungsten‐doped Ni−Fe hydroxides fabricated on a three‐dimensional nickel foam through cathodic electrodeposition are proposed as effective oxygen evolution reaction (OER) catalysts for alkaline water oxidation. Incorporating an adequate amount of W into Ni−Fe hydroxides modulates the electronic structure by changing the local environment of Ni and Fe and create oxygen vacancies, resulting in abundant active sites for the OER. The optimized electrocatalyst, with a substantial number of...
ChemSusChem
Published: 21 January 2021
Author(s): Ayesha Khan, Michael Goepel, Adam Kubas, Dariusz Łomot, Wojciech Lisowski, Dmytro Lisovytskiy, Ariadna Nowicka, Juan Carlos Colmenares, Roger Gläser
Abstract Solar energy‐driven processes for biomass valorization are priority for the growing industrialized society. To address this challenge, efficient visible light‐active photocatalyst for the selective oxidation of biomass‐derived platform chemical is highly desirable. Herein, selective oxidation of 5‐hydroxymethylfurfural (HMF) to 2,5‐diformylfuran (DFF) was achieved by visible light‐driven photocatalysis over titania. Pristine titania is photocatalytically inactive under visible light,...
ChemSusChem
Published: 21 January 2021
Author(s): Jordi Ampurdanés, Sorin Bunea, Atsushi Urakawa
Abstract Electrolysis‐assisted nitrate (NO3−) reduction is a promising approach for its conversion to harmless N2 from waste, ground, and drinking water due to the possible process simplicity by in‐situ generation of H2/H/H+ by water electrolysis and to the flexibility given by tunable redox potential of electrodes. This work explores the use of a polymer electrolyte membrane (PEM) electrochemical cell for electrolysis‐assisted nitrate reduction using SnO2‐supported metals as the active...
Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal
November 2020
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A. L. Santhosha, Lukas Medenbach, Johannes R. Buchheim, Philipp Adelhelm The Indium−Lithium Electrode in Solid-State Lithium-Ion Batteries: Phase Formation, Redox Potentials, and Interface Stability [Article] Batteries & Supercaps 2019, vol. 2, no. 6, p. 524 |
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Merel A. T. Plassche, Marta Barniol-Xicota, Steven H. L. Verhelst Front Cover: Peptidyl Acyloxymethyl Ketones as Activity-Based Probes for the Main Protease of SARS-CoV-2 (ChemBioChem 23/2020) [Cover Picture] ChemBioChem 2020, vol. 21, no. 23, p. 3289 |
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Michael Bowker Methanol Synthesis from CO2 Hydrogenation [Minireview] ChemCatChem 2019, vol. 11, no. 17, p. 4238 |
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Yuvraj Y. Birdja, Jan Vaes Towards a Critical Evaluation of Electrocatalyst Stability for CO2 Electroreduction [Viewpoint] ChemElectroChem 2020, vol. 7, no. 23, p. 4713 |
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Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837 |
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Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication] ChemistryOpen 2020, vol. 9, no. 7, p. 743 |
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Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055 |
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Antoine Daina, Vincent Zoete A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication] ChemMedChem 2016, vol. 11, no. 11, p. 1117 |
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Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review] ChemPhotoChem 2018, vol. 2, no. 5, p. 386 |
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Thomas G. Mayerhöfer, Alicja Dabrowska, Andreas Schwaighofer, Bernhard Lendl, Jürgen Popp Beyond Beer's Law: Why the Index of Refraction Depends (Almost) Linearly on Concentration [Communication] ChemPhysChem 2020, vol. 21, no. 8, p. 707 |
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Thomas Aro, Pedram Fatehi Production and Application of Lignosulfonates and Sulfonated Lignin [Review] ChemSusChem 2017, vol. 10, no. 9, p. 1861 |
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Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief The Periodic Table of the Chemical Elements and Sustainable Development [Essay] Eur. J. Inorg. Chem. 2019, p. 4170 |
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Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056 |
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Daewoo Han, Andrew J. Steckl Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review] ChemPlusChem 2019, vol. 84, no. 10, p. 1453 |
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Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016 |
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Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper] Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636 |
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Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696 |
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Changxiang Shao, Yang Zhao, Liangti Qu Tunable Graphene Systems for Water Desalination [Minireview] ChemNanoMat 2020, vol. 6, no. 7, p. 1028 |
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Tobias P. Haider, Carolin Völker, Johanna Kramm, Katharina Landfester, Frederik R. Wurm Plastics of the Future? The Impact of Biodegradable Polymers on the Environment and on Society [Minireview] Angew. Chem. Int. Ed. 2019, vol. 58, no. 1, p. 50 |
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Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75 |
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V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article] Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904 |
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Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen Regulatory Aspects of Nanomaterials in the EU [Research Article] Chem. Ing. Tech. 2017, vol. 89, no. 3, p. 224 |
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Henrik Petersen, Klaus Roth To Tattoo or not to Tattoo [Artikel] Chem. Unserer Zeit 2016, vol. 50, no. 1, p. 44 |
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Regine Herbst-Irmer, Erhard Irmer Titelbild: Chemische Bindungen experimentell sichtbar machen (CHEMKON 6/2020) [Titelbild] CHEMKON 2020, vol. 27, no. 6, p. 263 |
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Massenspektrometrie — Eine Einführung von Herbert Budzikiewicz und Mathias Schäfer [Buchbesprechung] Lebensmittelchemie 2013, vol. 67, no. 2, p. 56 |
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Brigitte Osterath, Eliza Leusmann, Frauke Zbikowski Biochemikerin trifft Mikrobiologin [Bildung + Gesellschaft] Nachr. Chem. 2020, vol. 68, no. 11, p. 8 |
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Most cited articles from Chemistry Europe, ACES, and GDCh journals
Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.
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Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication] Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941 |
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Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review] Batteries Supercaps 2018, vol. 1, pp. 41–68 |
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Lik Hang Yuen, Raphael M. Franzini Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview] ChemBioChem 2017, vol. 18, pp. 829–836 |
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Konstantinos C. Christoforidis, Paolo Fornasiero Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review] ChemCatChem 2017, vol. 9, pp. 1523–1544 |
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Marwa Elkady, Hassan Shokry, Hesham Hamad Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article] Chem. Eng. Technol. 2018, vol. 41, pp. 553–562 |
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Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview] ChemistryOpen 2018, vol. 7, pp. 169–179 |
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Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, pp. 945–956 |
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Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826 |
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Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review] Chem. Ing. Tech. 2018, vol. 90, pp. 17–35 |
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Sayantani Sikdar, Madhusree Kundu A Review on Detection and Abatement of Heavy Metals [Review] ChemBioEng Rev. 2018, vol. 5, pp. 18–29 |
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Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication] ChemElectroChem 2017, vol. 4, pp. 1840–1845 |
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Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper] ChemNanoMat 2017, vol. 3, pp. 328–335 |
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Chengwei Liu, Michal Szostak Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview] Chem. Eur. J. 2017, vol. 23, pp. 7157–7173 |
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Jian Shu, Dianping Tang Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review] Chem. Asian J. 2017, vol. 12, pp. 2780–2789 |
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Jian Rong, Chuanfa Ni, Jinbo Hu Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review] Asian J. Org. Chem. 2017, vol. 6, pp. 139–152 |
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Juan Alberto Sirvent, Ulrich Lücking Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper] ChemMedChem 2017, vol. 12, pp. 487–501 |
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Grzegorz Greczynski, Lars Hultman C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication] ChemPhysChem 2017, vol. 18, pp. 1507–1512 |
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Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept] ChemPhotoChem 2017, vol. 1, pp. 148–158 |
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Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication] ChemSusChem 2017, vol. 10, pp. 87–90 |
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Enzo Alessio Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview] Eur. J. Inorg. Chem. 2017, pp. 1549–1560 |
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Marcel Garbe, Kathrin Junge, Matthias Beller Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview] Eur. J. Org. Chem. 2017, pp. 4344–4362 |
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