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ChemPhysChem

Temperature and Composition Dependent Optical Properties of CdSe/CdS Dot/Rod‐Based Aerogel Networks

Published: 23 November 2021

Author(s): Pascal Rusch, Denis Pluta, Franziska Lübkemann, Dirk Dorfs, Dániel Zámbó, Nadja C. Bigall

Abstract Employing nanocrystals (NCs) as building blocks of porous aerogel network structures allows the conversion of NC materials into macroscopic solid structures while conserving their unique nanoscopic properties. Understanding the interplay of the network formation and its influence on these properties like size‐dependent emission is a key to apply techniques for the fabrication of novel nanocrystal aerogels. In this work, CdSe/CdS dot/rod NCs possessing two different CdSe core sizes...

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European Journal of Inorganic Chemistry

Oxidative C−F Cleavage in Metalloenzymes and Model Compounds

Published: 23 November 2021

Author(s): Miquel Costas, Anna Company

Abstract Replacement of C−H by C−F bonds provides lipophilicity and chemical stability to organic molecules. These properties make organofluorides interesting compounds in agrochemistry, medicinal chemistry and also in materials. However, the same properties hamper their chemical degradation, resulting in an increasingly concerning environmental persistence, which is fueling the quest for biological and chemical reagents that could cleave the C−F bonds. The first part of this review makes an...

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ChemPhysChem

Reverse Intersystem Crossing of Single Deuterated Perylene Molecules in a Dibenzothiophene Matrix

Published: 23 November 2021

Author(s): Robert Smit, Zoran Ristanović, Bolesław Kozankiewicz, Michel Orrit

Abstract Intersystem crossing to the long‐lived metastable triplet state is often a strong limitation on fluorescence brightness of single molecules, particularly for perylene in various matrices. In this paper, we report on a strong excitation‐induced reverse intersystem crossing (rISC), a process where single perylene molecules in a dibenzothiophene matrix recover faster from the triplet state, turning into bright emitters at saturated excitation powers. With a detailed study of...

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European Journal of Inorganic Chemistry

Protic Ferrocenyl Acyclic Diamino Carbene Gold(I) Complexes

Published: 23 November 2021

Author(s): Sven D. Waniek, Christoph Förster, Katja Heinze

Abstract Two mononuclear protic ferrocenyl acyclic diamino carbene gold(I) complexes AuCl[C(NHFc)(NR2)] were prepared by nucleophilic attack of diethylamine (R = Et) and diisopropylamine (R = iPr) at the ferrocenyl substituted isocyanide complex chlorido(isocyanoferrocene)gold(I) AuCl(CN−Fc). In the solid state, the multifunctional protic carbene gold(I) complexes display intermolecular aurophilic interactions or intermolecular NH⋅⋅⋅Cl hydrogen bonding in addition to intramolecular...

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Chemistry - A European Journal

Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions

Published: 23 November 2021

Author(s): Manuel Kirchhof, Karina Abitaev, Abdulwahab Abouhaileh, Katrin Gugeler, Wolfgang Frey, Anna Zens, Johannes Kästner, Thomas Sottmann, Sabine Laschat

Abstract Microemulsions provide a unique opportunity to tailor the polarity and liquid confinement in asymmetric catalysis via nanoscale polar and nonpolar domains separated by a surfactant film. For chiral diene Rh complexes, the influence of counterion and surfactant film on the catalytic activity and enantioselectivity remained elusive. To explore this issue chiral norbornadiene Rh(X) complexes (X=OTf, OTs, OAc, PO2F2) were synthesized and characterized by X‐ray crystallography and...

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European Journal of Organic Chemistry

From Enantioenriched Donor‐Acceptor Cyclopropylcarbinols to Axially Chiral Arylnaphthalenes through Aryldihydronaphthalenes: Central‐to‐Axial Chirality Exchange

Published: 23 November 2021

Author(s): Taichi Saito, Yuka Shimizu, Yusuke Araki, Yoshino Ohgami, Yu Kitazawa, Yoshinori Nishii

Abstract Transformations of enantioenriched donor‐acceptor (D−A) cyclopropylcarbinols to enantioenriched 1‐arylnaphthalenes that bear an ortho‐substituent on a benzene ring provided a successful chirality‐exchange method with a high level of stereoinduction. A central chirality‐transfer step, i. e., a Lewis‐acid‐mediated ring‐opening cyclization of enantioenriched D‐A cyclopropylcarbinols (97 to 99 % ee), afforded 1‐aryl‐1,2‐dihydronaphthalenes with an ortho‐substituent (Me, Br, OMe, OBn, or...

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European Journal of Inorganic Chemistry

Ruthenium (II) Complexes Bearing Heteroleptic Terpyridine Ligands: Synthesis, Photophysics and Solar Energy Conversion

Published: 23 November 2021

Author(s): Nimisha Jain, Angelina Mary, Vishesh Manjunath, Rahul Sakla, Rupesh S. Devan, D. Amilan Jose, Abbas Raja Naziruddin

Abstract Heteroleptic ruthenium (II) complexes featuring donor functionalized phenyl‐terpyridine (ph‐tpy) and a monocarboxylic‐(ph‐tpy)/(tpy) are synthesized and characterized. Reactions of ruthenium (II) precursors at 80 °C favored heteroleptic complexes formation over the homoleptic side products. Visible light excitation of these complexes resulted in the metal‐to‐ligand charge transfer (MLCT) transitions. The inter‐planar torsional angle between the atoms of donor functionalized phenyl...

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European Journal of Organic Chemistry

N‐Thiocyanato‐2,10‐camphorsultam Derivatives: Design and Applications of Original Electrophilic Thiocyanating Reagents

Published: 23 November 2021

Author(s): Mélissa Gao, Martin Vuagnat, Philippe Jubault, Tatiana Besset

Abstract The synthesis of bench‐stable electrophilic thiocyanating reagents was depicted in two steps from readily available starting materials in good yields. These newly designed electrophilic reagents were successfully applied for the thiocyanation of different nucleophiles under mild and transition metal‐free conditions. Preliminary experiments for the asymmetric C3‐thiocyanation of an oxindole derivative were also conducted leading to the expected product with no induction of chirality,...

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ChemBioChem

Direct Enzymatic Synthesis of Fatty Amines from Renewable Triglycerides and Oils

Published: 23 November 2021

Author(s): Joan Citoler, William Finnigan, Han Bevinakatti, Nicholas J. Turner

Abstract Fatty amines represent an important class of commodity chemicals which have broad applicability in different industries. The synthesis of fatty amines starts from renewable sources such as vegetable oils or animal fats, but the process has multiple drawbacks that compromise the overall effectiveness and efficiency of the synthesis. Herein, we report a proof‐of‐concept biocatalytic alternative towards the synthesis of primary fatty amines from renewable triglycerides and oils. By...

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Chemistry - A European Journal

Metallodrug Profiling against SARS‐CoV‐2 Target Proteins Identifies Highly Potent Inhibitors of the S/ACE2 interaction and the Papain‐like Protease PLpro

Published: 23 November 2021

Author(s): Maria Gil‐Moles, Sebastian Türck, Uttara Basu, Andrea Pettenuzzo, Saurav Bhattacharya, Ananthu Rajan, Xiang Ma, Rolf Büssing, Jessica Wölker, Hilke Burmeister, Henrik Hoffmeister, Pia Schneeberg, Andre Prause, Petra Lippmann, Josephine Kusi‐Nimarko, Storm Hassell‐Hart, Andrew McGown, Daniel Guest, Yan Lin, Anna Notaro, Robin Vinck, Johannes Karges, Kevin Cariou, Kun Peng, Xue Qin, Xing Wang, Joanna Skiba, Łukasz Szczupak, Konrad Kowalski, Ulrich Schatzschneider, Catherine Hemmert, Heinz Gornitzka, Elena R. Milaeva, Alexey A. Nazarov, Gilles Gasser, John Spencer, Luca Ronconi, Ulrich Kortz, Jindrich Cinatl, Denisa Bojkova, Ingo Ott

Abstract The global spread of the severe acute respiratory syndrome coronavirus 2 (SARS‐CoV‐2) has called for an urgent need for dedicated antiviral therapeutics. Metal complexes are commonly underrepresented in compound libraries that are used for screening in drug discovery campaigns, however, there is growing evidence for their role in medicinal chemistry. Based on previous results, we have selected more than 100 structurally diverse metal complexes for profiling as inhibitors of two...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

October 2021

 


Fang Zhang, Juewen Liu
Label-Free Colorimetric Biosensors Based on Aptamers and Gold Nanoparticles: A Critical Review [Review]
Anal. Sens. 2021, vol. 1, no. 1, p. 30

Rola Houhou, Thomas Bocklitz
Trends in artificial intelligence, machine learning, and chemometrics applied to chemical data [Review]
Anal. Sci. Adv. 2021, vol. 2, no. 3-4, p. 128

Alana Zülke, Yi Li, Peter Keil, Robert Burrell, Sacha Belaisch, Mangayarkarasi Nagarathinam, Michael P. Mercer, Harry E. Hoster
High-Energy Nickel-Cobalt-Aluminium Oxide (NCA) Cells on Idle: Anode- versus Cathode-Driven Side Reactions [Article]
Batteries Supercaps 2021, vol. 4, no. 6, p. 934

Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll
Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview]
ChemBioChem 2021, vol. 22, no. 7, p. 1176

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Pooja Vadhva, Ji Hu, Michael J. Johnson, Richard Stocker, Michele Braglia, Dan J. L. Brett, Alexander J. E. Rettie
Electrochemical Impedance Spectroscopy for All-Solid-State Batteries: Theory, Methods and Future Outlook [Review]
ChemElectroChem 2021, vol. 8, no. 11, p. 1930

Keita Sakamoto, Akihiro Hakamata, Arihiro Iwasaki, Kiyotake Suenaga, Masashi Tsuda, Haruhiko Fuwa
Cover Feature: Total Synthesis, Stereochemical Revision, and Biological Assessment of Iriomoteolide-2a (Chem. Eur. J. 36/2019) [Cover Picture]
Chem. Eur. J. 2019, vol. 25, no. 36, p. 8429

Guilherme L. Tripodi, Max T. G. M. Derks, Floris P. J. T. Rutjes, Jana Roithová
Tracking Reaction Pathways by a Modular Flow Reactor Coupled to Electrospray Ionization Mass Spectrometry [Cover Profile]
Chemistry–Methods 2021, vol. 1, no. 10, p. 428

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Thomas D. Svejstrup, Anamitra Chatterjee, Denis Schekin, Thomas Wagner, Julia Zach, Magnus J. Johansson, Giulia Bergonzini, Burkhard König
Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors [Communication]
ChemPhotoChem 2021, vol. 5, no. 9, p. 808

Thomas G. Mayerhöfer, Susanne Pahlow, Jürgen Popp
The Bouguer-Beer-Lambert Law: Shining Light on the Obscure [Review]
ChemPhysChem 2020, vol. 21, no. 18, p. 2029

Francesco Bisconti, Antonella Giuri, Gianluigi Marra, Alberto Savoini, Paolo Fumo, Rosamaria Marrazzo, Stefano Zanardi, Gianni Corso, Riccardo Po, Paolo Biagini, Eleonora Quadrivi, Riikka Suhonen, Thomas M. Kraft, Mari Ylikunnari, Andrea Listorti, Carola Esposito Corcione, Silvia Colella, Aurora Rizzo
Polymer-Assisted Single-Step Slot-Die Coating of Flexible Perovskite Solar Cells at Mild Temperature from Dimethyl Sulfoxide [Full Paper]
ChemPlusChem 2021, vol. 86, no. 10, p. 1442

Layla Filiciotto, Gadi Rothenberg
Biodegradable Plastics: Standards, Policies, and Impacts [Review]
ChemSusChem 2021, vol. 14, no. 1, p. 56

Anton I. Hanopolskyi, Viktoryia A. Smaliak, Alexander I. Novichkov, Sergey N. Semenov
Autocatalysis: Kinetics, Mechanisms and Design [Review]
ChemSystemsChem 2021, vol. 3, eLoc. e2000026

Saheed E. Elugoke, Abolanle S. Adekunle, Omolola E. Fayemi, Ekemini D. Akpan, Bhekie B. Mamba, El-Sayed M. Sherif, Eno E. Ebenso
Molecularly imprinted polymers (MIPs) based electrochemical sensors for the determination of catecholamine neurotransmitters - Review [REVIEW]
Electrochem. Sci. Adv. 2021, vol. 1, eLoc. e2000026

Mauricio Cattaneo, Giovanny A. Parada, Adam L. Tenderholt, Werner Kaminsky, James M. Mayer
Structural, Electronic, and Thermochemical Preference for Multi-PCET Reactivity of Ruthenium(II)-Amine and Ruthenium(IV)-Amido Complexes [Full Paper]
Eur. J. Inorg. Chem. 2021, p. 4066

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemistryViews 2016

Michael C. Willis, Edward J. Emmett
The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry [Focus Review]
Asian J. Org. Chem. 2015, vol. 4, no. 7, p. 602

Stephanie C. C. van der Lubbe, Célia Fonseca Guerra
The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths [Minireview]
Chem. Asian J. 2019, vol. 14, no. 16, p. 2760

B. Lilli Neumeier, Mikhail Khorenko, Frauke Alves, Oliver Goldmann, Joanna Napp, Ute Schepers, Holger M. Reichardt, Claus Feldmann
Fluorescent Inorganic-Organic Hybrid Nanoparticles [Focus Review]
ChemNanoMat 2019, vol. 5, no. 1, p. 24

Xiaoye Yu, Constantin G. Daniliuc, Fatmah Ali Alasmary, Armido Studer
Direct Access to α-Aminosilanes Enabled by Visible-Light-Mediated Multicomponent Radical Cross-Coupling [Research Article]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 43, p. 23335

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Manami Ishida, Dieter Weiß
Blausäure im Haushalt [Magazin]
Chem. Unserer Zeit 2021, vol. 55, no. 5, p. 359

Digitalisierung nach der Pandemie [Editorial]
CHEMKON 2021, vol. 28, no. 6, p. 234

Cover Picture Lebensmittelchemie 5/2021 [Cover Picture]
Lebensmittelchemie 2021, vol. 75, no. 5

Sonja Herres-Pawlis, Johannes Liermann
Den Datenschatz endlich heben [Leitartikel]
Nachr. Chem. 2021, vol. 69, no. 10, p. 3

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2018 or 2019 according to Web of Science. They have contributed the most to the journal's impact factor in 2020.

 


Jing Pan, Xin Long Tian, Shahid Zaman, Zehua Dong, Hongfang Liu, Ho Seok Park, Bao Yu Xia
Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium-Air and Zinc-Air Batteries [Minireview]
Batteries Supercaps 2019, vol. 2, pp. 336–347

Veeresh Juturu, Jin Chuan Wu
Heterologous Protein Expression in Pichia pastoris: Latest Research Progress and Applications [Review]
ChemBioChem 2018, vol. 19, pp. 7–21

Tingmin Di, Quanlong Xu, WingKei Ho, Hua Tang, Quanjun Xiang, Jiaguo Yu
Review on Metal Sulphide-based Z-scheme Photocatalysts [Review]
ChemCatChem 2019, vol. 11, pp. 1394–1411

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, pp. 6–19

Min Feng, Ming-Liang Tong
Single Ion Magnets from 3d to 5f: Developments and Strategies [Minireview]
Chem. Eur. J. 2018, vol. 24, pp. 7574–7594

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Patil S. Basavarajappa, Bhojya Naik H. Seethya, Nagaraju Ganganagappa, Kumaraswamy B. Eshwaraswamy, Raghava Reddy Kakarla
Enhanced Photocatalytic Activity and Biosensing of Gadolinium Substituted BiFeO3 Nanoparticles [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 9025–9033

Deepti Goyal, Amandeep Kaur, Bhupesh Goyal
Benzofuran and Indole: Promising Scaffolds for Drug Development in Alzheimer's Disease [Review]
ChemMedChem 2018, vol. 13, pp. 1275–1299

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, pp. 386–402

Weiyin Gao, Chenxin Ran, Jun Xi, Bo Jiao, Wenwen Zhang, Mincai Wu, Xun Hou, Zhaoxin Wu
High-Quality Cs2AgBiBr6 Double Perovskite Film for Lead-Free Inverted Planar Heterojunction Solar Cells with 2.2 % Efficiency [Communication]
ChemPhysChem 2018, vol. 19, pp. 1696–1700

Achini Japahuge, Tao Zeng
Theoretical Studies of Singlet Fission: Searching for Materials and Exploring Mechanisms [Review]
ChemPlusChem 2018, vol. 83, pp. 146–182

Peixun Xiong, Xinxin Zhao, Yunhua Xu
Nitrogen-Doped Carbon Nanotubes Derived from Metal-Organic Frameworks for Potassium-Ion Battery Anodes [Full Paper]
ChemSusChem 2018, vol. 11, pp. 202–208

Nadja Stucke, Benedikt M. Flöser, Thomas Weyrich, Felix Tuczek
Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments [Microreview]
Eur. J. Inorg. Chem. 2018, pp. 1337–1355

Davin Tan, Tomislav Friščić
Mechanochemistry for Organic Chemists: An Update [Microreview]
Eur. J. Org. Chem. 2018, pp. 18–33

Esther von Grotthuss, Alexandra John, Thomas Kaese, Matthias Wagner
Doping Polycyclic Aromatics with Boron for Superior Performance in Materials Science and Catalysis [Focus Review]
Asian J. Org. Chem. 2018, vol. 7, pp. 37–53

Min-Hua Huang, Wen-Juan Hao, Bo Jiang
Recent Advances in Radical-Enabled Bicyclization and Annulation/1,n-Bifunctionalization Reactions [Focus Review]
Chem. Asian J. 2018, vol. 13, pp. 2958–2977

Amit Kumar, Qiang Xu
Two-Dimensional Layered Materials as Catalyst Supports [Focus Review]
ChemNanoMat 2018, vol. 4, pp. 28–40

Leyre Marzo, Santosh K. Pagire, Oliver Reiser, Burkhard König
Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? [Review]
Angew. Chem. Int. Ed. 2018, vol. 57, pp. 10034–10072

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH