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Tackling Capacity Fading in Vanadium Redox Flow Batteries with Amphoteric Polybenzimidazole/Nafion Bilayer Membranes

Published: 22 May 2019

Author(s): Fabio J. Oldenburg, Elisabeth Nilsson, Thomas J. Schmidt, Lorenz Gubler

Abstract Vanadium flow batteries are among the most promising technologies for stationary energy storage applications if their cost of storage can be further decreased. Capacity fading resulting from imbalanced vanadium crossover is a key operating cost component. Herein, a new approach is reported to avoid this cost by balancing electrolyte transport with amphoteric bilayer Nafion/meta‐polybenzimidazole membranes. Within this system, the anion‐ and cation‐exchange capacity can be tuned in a...

thumbnail image: ChemSusChem


Investigation of Perovskite Oxide SrCo0.8Cu0.1Nb0.1O3–δ as a Cathode Material for Room Temperature Direct Ammonia Fuel Cells

Published: 22 May 2019

Author(s): Peimiao Zou, Shigang Chen, Rong Lan, Shanwen Tao

Abstract Single‐phase perovskite oxide SrCo0.8Cu0.1Nb0.1O3–δ was synthesized using a Pechini method. X‐ray diffraction (XRD) analysis indicated a cubic structure with a=3.8806(7) Å. The oxide material was combined with active carbon, forming a composite electrode to be used as the cathode in a room temperature ammonia fuel cell based on an anion membrane electrolyte and NiCu/C anode. An open circuit voltage (OCV) of 0.19 V was observed with dilute 0.02 m (340 ppm) ammonia solution as the fuel....

thumbnail image: ChemSusChem


Low‐Cost Porous Ruthenium Layer Deposited on Nickel Foam as a Highly Active Universal‐pH Electrocatalyst for the Hydrogen Evolution Reaction

Published: 22 May 2019

Author(s): Jiawei Xia, Michael Volokh, Guiming Peng, Yongsheng Fu, Xin Wang, Menny Shalom

Abstract Low‐cost and high‐efficiency electrocatalysts for the hydrogen evolution reaction (HER) are a key constituent of a low‐carbon industrial economy based on intermittent energy production in the near future. A facile wet‐chemistry strategy has been developed for the synthesis of a porous Ru layer deposited onto Ni foam (NF) as a competitive candidate for HER over the whole pH range, especially under economical alkaline conditions. The catalyst shows outstanding HER performance, which...

thumbnail image: ChemSusChem


The Structural Determinants Accounting for the Broad Substrate Specificity of the Quorum Quenching Lactonase GcL

Published: 22 May 2019

Author(s): Celine Bergonzi, Michael Schwab, Tanushree Naik, Mikael Elias

Abstract Quorum quenching lactonases are enzymes capable of hydrolyzing lactones, including N‐acyl homoserine lactones (AHLs). AHLs are molecules known as signals in bacterial communication dubbed quorum sensing. Bacterial signal disruption by lactonases was previously reported to inhibit behavior regulated by quorum sensing, such as the expression of virulence factors and the formation of biofilms. Herein, we report the enzymatic and structural characterization of a novel lactonase...

thumbnail image: ChemBioChem


Amorphous CoFe Double Hydroxides Decorated with N‐Doped CNTs for Efficient Electrochemical Oxygen Evolution

Published: 22 May 2019

Author(s): Yang Liu, Yiping Hu, Ping Ma, Feng Li, Fei Yuan, Shuo Wang, Yutong Luo, Jiantai Ma

Abstract The development and design of a highly active and affordable nanostructured material as an efficient electrocatalyst for electrochemical oxygen evolution is a pressing necessity to realize industrial production of hydrogen by water electrolysis. Amorphous nanocomposites have recently attracted interest owing to their superior electrocatalytic activity derived from their unique structure. Herein, amorphous CoFe double hydroxides (Am‐CFDH) decorated with N‐doped carbon nanotubes (NCNTs)...

thumbnail image: ChemSusChem


Catalytic Reactivation of Industrial Oxygen Depolarized Cathodes by in situ Generation of Atomic Hydrogen

Published: 22 May 2019

Author(s): Denis Öhl, David Franzen, Melanie Paulisch, Stefan Dieckhöfer, Stefan Barwe, Corina Andronescu, Ingo Manke, Thomas Turek, Wolfgang Schuhmann

Abstract Electrocatalytically active materials on the industrial as well as on the laboratory scale may suffer from chemical instability during operation, air exposure, or storage in the electrolyte. A strategy to recover the loss of electrocatalytic activity is presented. Oxygen‐depolarized cathodes (ODC), analogous to those that are utilized in industrial brine electrolysis, are analyzed: the catalytic activity of the electrodes upon storage (4 weeks) under industrial process conditions...

thumbnail image: ChemSusChem


Synthesis and Antibacterial Evaluation of Bis‐thiazolium, Bis‐imidazolium, and Bis‐triazolium Derivatives

Published: 22 May 2019

Author(s): Benoît Thomas, Raphaël E. Duval, Stéphane Fontanay, Mihayl Varbanov, Michel Boisbrun

Abstract Given the worldwide spread of bacterial drug resistance, there is an urgent need to develop new compounds that exhibit potent antibacterial activity and that are unimpaired by this phenomenon. Quaternary ammonium compounds have been used for many years as disinfectants, but recent advances have shown that polycationic derivatives exhibit much stronger activity and are less prone to bacterial resistance than commonly used monocationic compounds. In this sense, we prepared three series...

thumbnail image: ChemMedChem

Journal of Sensory Studies Journal of Sensory Studies

From abstract to recognizable: Modeling tendencies of a basic salt solution and a tomato soup based on affective reactions

Published: 22 May 2019

Author(s): Sasha M. Barnett, Charles Diako, Carolyn F. Ross

Abstract The objective of this study was to understand the crossmodal interaction between salt taste and shape, specifically, the relationship between consumer affective reactions to a salt solution and a tomato soup. Panelists rated samples for acceptance of basic tastes and overall liking, and molded modeling clay into a shape that best reflected their sensory experience. Data were analyzed using a multinomial logit model and a two proportion z test. Shapes molded were categorized into six...

thumbnail image: Journal of Sensory Studies Journal of Sensory Studies

Advanced Synthesis & Catalysis

Recent Advances in the Synthesis and Reactivity of Isothiazoles

Published: 22 May 2019

Author(s): Ana De Oliveira Silva, James McQuade, Michal Szostak

Abstract Isothiazoles represent an important class of five‐membered sulfur heterocycles that are widely utilized in medicinal chemistry and organic synthesis due to the unique properties of two electronegative heteroatoms in a 1,2‐relationship. However, in contrast to other 1,2‐azoles, the facile assembly of isothiazoles has always been considered a substantial challenge. In the last decade, major advances have taken place in the fields of synthesis and functionalization of isothiazoles that...

thumbnail image: Advanced Synthesis & Catalysis


Javier Pérez‐Ramírez

Published: 21 May 2019

thumbnail image: ChemCatChem

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

February 2019


Pingyu Zhang, Huaiyi Huang, Samya Banerjee, Guy J. Clarkson, Chen Ge, Cinzia Imberti, Peter J. Sadler
Nucleus-Targeted Organoiridium-Albumin Conjugate for Photodynamic Cancer Therapy [Communication]
Angew. Chem. Int. Ed. 2019, vol. 58, p. 2350

Marion Rusch, Arnaud Thevenon, Dominic Hoepfner, Thomas Aust, Christian Studer, Maude Patoor, Patrick Rollin, Madeleine Livendahl, Beatrice Ranieri, Esther Schmitt, Carsten Spanka, Karl Gademann, Laure C. Bouchez
Design and Synthesis of Metabolically Stable tRNA Synthetase Inhibitors Derived from Cladosporin [Communication]
ChemBioChem 2019, vol. 20, p. 644

Wei Jin, Laura Pastor-Pérez, DeKui Shen, Antonio Sepúlveda-Escribano, Sai Gu, Tomas Ramirez Reina
Catalytic Upgrading of Biomass Model Compounds: Novel Approaches and Lessons Learnt from Traditional Hydrodeoxygenation - a Review [Review]
ChemCatChem 2019, vol. 11, p. 924

Dieter Wöhrle
Kunststoffe [Artikel]
Chem. Unserer Zeit 2019, vol. 53, p. 50

Thomas Wirth
Meet the Board of ChemistryOpen: Thomas Wirth [Meet the Board]
ChemistryOpen 2019, vol. 8, p. 251

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Mao Jiang, Kangli Wang, Shu Gao, Ruxing Wang, Jing Han, Jie Yan, Shijie Cheng, Kai Jiang
Selenium as Extra Binding Site for Sulfur Species in Sulfurized Polyacrylonitrile Cathodes for High Capacity Lithium-Sulfur Batteries [Article]
CHEMELECTROCHEM 2019, vol. 6, p. 1365

Tianchao Niu, Jialin Zhang, Wei Chen
Surface Engineering of Two-Dimensional Materials [Focus Review]
ChemNanoMat 2019, vol. 5, p. 6

Dennis Rottschäfer, Beate Neumann, Hans-Georg Stammler, Ryohei Kishi, Masayoshi Nakano, Rajendra S. Ghadwal
A Phosphorus Analogue of p-Quinodimethane with a Planar P4 Ring: A Metal-Free Diphosphorus Source [Communication]
Chem. Eur. J. 2019, vol. 25, p. 3244

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Arun K. Sinha, Danish Equbal
Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review]
Asian J. Org. Chem. 2019, vol. 8, p. 32

Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss
Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper]
ChemMedChem 2018, vol. 13, p. 988

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, p. 386

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Didier Astruc
Why is Ferrocene so Exceptional? [Microreview]
Eur. J. Inorg. Chem. 2017, p. 6

Mabuatsela V. Maphoru, Josef Heveling, Sreejarani Kesavan Pillai
Solvent and Temperature Effects on the Platinum‐Catalyzed Oxidative Coupling of 1‐Naphthols [Full Paper]
Eur. J. Org. Chem. 2016, p. 331

Cover Picture Lebensmittelchemie 1/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73

Elementerätsel 1 [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, p. 37

Schüleraufgabe: CHEMKON 2/2017 [Schüleraufgabe]
CHEMKON 2017, vol. 24, p. 91

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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