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Chemistry - A European Journal

Multi‐Color Fluorescent Carbon Dots: Graphitized sp2 Conjugated Domains and Surface State Energy Level Co‐Modulate Band Gap Rather Than Size Effects

Published: 28 May 2020

Author(s): Siqi Wei, Xinghang Yin, Haoyi Li, Xiaoyu Du, Limei Zhang, Qiang Yang, Rui Yang

Abstract Four types of carbon dots (CDs) with various color (blue, green, yellow, and red) emissions have been synthesized under solvent‐free conditions from citric acid and different nitrogen sources (DMF, urea, ethanamide, and formamide). By detailed characterization and comparison, it is confirmed that the graphitized sp2 conjugated domain and surface functional groups such as C−O and C=N play synergetic roles in adjusting the fluorescence properties. Notably, the size effect is not the...

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Chemistry - A European Journal

Co Single‐Atom Catalysts Boost Chemiluminescence

Published: 28 May 2020

Author(s): Hui Ouyang, Lvxia Zhang, Shan Jiang, Wenwen Wang, Chengzhou Zhu, Zhifeng Fu

Abstract Co single‐atom catalysts (SACs) with good aqueous solubility and abundant labelling functional groups were prepared in Co/Fe bimetallic metal‐organic frameworks by a facile solvothermal method without high‐temperature calcination. In contrast to traditional chemiluminescence (CL) catalysts, Co SACs accelerated decomposition of H2O2 to produce a large amount of singlet oxygen (1O2) rather than superoxide (O2.−) and hydroxyl radical (OH.). They were found to dramatically enhance the CL...

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Chemistry - A European Journal

Dehydropolymerisation of Methylamine Borane and an N‐Substituted Primary Amine Borane Using a PNP Fe Catalyst

Published: 28 May 2020

Author(s): Felix Anke, Susanne Boye, Anke Spannenberg, Albena Lederer, Detlef Heller, Torsten Beweries

Abstract Dehydropolymerisation of methylamine borane (H3B⋅NMeH2) using the well‐known iron amido complex [(PNP)Fe(H)(CO)] (PNP=N(CH2CH2PiPr2)2) (1) gives poly(aminoborane)s by a chain‐growth mechanism. In toluene, rapid dehydrogenation of H3B⋅NMeH2 following first‐order behaviour as a limiting case of a more general underlying Michaelis–Menten kinetics is observed, forming aminoborane H2B=NMeH, which selectively couples to give high‐molecular‐weight poly(aminoborane)s (H2BNMeH)n and only...

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Chemistry - A European Journal

Poly‐γ‐S‐perillyl‐l‐glutamate and Poly‐γ‐S‐perillyl‐d‐glutamate: Diastereomeric Alignment Media Used for the Investigation of the Alignment Process

Published: 28 May 2020

Author(s): Marcel Alcaraz Janßen, Christina M. Thiele

Abstract Residual dipolar couplings (RDCs) offer additional information for structure elucidation by NMR spectroscopy. They are measured in anisotropic media, such as lyotropic liquid crystalline phases of polypeptides. Today, some suitable polypeptides are known. Nevertheless, structural influences of these polypeptides on the alignment properties are not really understood. Thus, which influence a chiral side chain has on enantiodiscrimination and whether we can improve the...

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ChemCatChem

Surface Assembling of Highly Interconnected and Vertically Aligned Porous Nanosheets of Gd−CoB on TiO2 Nanoflowers for Durable Methanol oxidation Reaction

Published: 28 May 2020

Author(s): Tanveer ul Haq, Yusuf Bicer, Akhtar Munir, Said A. Mansour, Yousef Haik

Abstract Being a green and carbon‐neutral technology, direct methanol fuel cell (DMFC) has attracted much attention while endowing highest mass energy density at low operating temperature. However, the multistep and multielectron process of methanol oxidation reaction (MOR) taking place at the anodic side in DMFC is an energy intense process. In addition, the in situ generated CO can severely deteriorate the catalytic efficiency of electrode material, which can be, however, realized to develop...

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Advanced Functional Materials

Targeting Oligosaccharides and Glycoconjugates Using Superselective Binding Scaffolds

Published: 28 May 2020

Author(s): Stefano Tommasone, Yazmin K. Tagger, Paula M. Mendes

Abstract Recognition of oligosaccharides is associated with very limited specificity due to their strong solvation in water and the high degree of subtle structural variations between them. Here, oligosaccharide recognition sites are created on material surfaces with unmatched, binary on–off binding behavior, sharply discriminating a target oligosaccharide over closely related carbohydrate structures. The basis for the superselective binding behavior relies on the highly efficient generation...

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Angewandte Chemie

Observation of the Low‐Frequency Spectrum of the Water Trimer as a Sensitive Test of the Water‐Trimer Potential and the Dipole‐Moment Surface

Published: 28 May 2020

Author(s): Raffael Schwan, Chen Qu, Devendra Mani, Nitish Pal, Gerhard Schwaab, Joel M. Bowman, Gregory S. Tschumper, Martina Havenith

Abstract Intermolecular interactions in bulk water are dominated by pairwise and non‐pairwise cooperative interactions. While accurate descriptions of the pairwise interactions are available and can be tested by precise low‐frequency spectra of the water dimer up to 550 cm−1, the same does not hold for the three‐body interactions. Here, we report the first comprehensive spectrum of the water trimer in the frequency region from 70 to 620 cm−1 using helium‐nanodroplet isolation and free‐electron...

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Photochemistry and Photobiology

The Ca2+‐Regulated Photoprotein Obelin as a Tool for SELEX Monitoring and DNA Aptamer Affinity Evaluation

Published: 28 May 2020

Author(s): Vasilisa V. Krasitskaya, Natalia S. Goncharova, Vladislav V. Biriukov, Eugenia E. Bashmakova, Marsel R. Kabilov, Ivan K. Baykov, Aleksey E. Sokolov, Ludmila A. Frank

Abstract Bioluminescent solid‐phase analysis was proposed to monitor the selection process and to determine binding characteristics of the aptamer–target complexes during design and development of the specific aptamers. The assay involves Ca2+‐regulated photoprotein obelin as a simple, sensitive and fast reporter. Applicability and the prospects of the approach were exemplified by identification of DNA aptamers to cardiac troponin I, a highly specific early biomarker for acute myocardial...

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Angewandte Chemie

Polypyridine‐Based Helical Amide Foldamer Channels: Rapid Transport of Water and Protons with High Ion Rejection

Published: 28 May 2020

Author(s): Jie Shen, Jingrong Fan, Ruijuan Ye, Ning Li, Yuguang Mu, Huaqiang Zeng

Abstract Synthetic strategies that enable rapid construction of covalent organic nanotubes with an angstrom‐scale tubular pore remain scarcely reported. Reported here is a remarkably simple and mild one‐pot polymerization protocol, employing POCl3 as the polymerization agent. This protocol efficiently generates polypyridine amide foldamer‐based covalent organic nanotubes with a 2.8 nm length at a yield of 50 %. Trapping single‐file water chains in the 2.8 Å tubular cavity, rich in...

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Angewandte Chemie

Unveiling the Local Structure of Palladium Loaded into Imine‐Linked Layered Covalent Organic Frameworks for Cross‐Coupling Catalysis

Published: 28 May 2020

Author(s): Ignacio Romero‐Muñiz, Andreas Mavrandonakis, Pablo Albacete, Alicia Vega, Valérie Briois, Félix Zamora, Ana E. Platero‐Prats

Abstract Layered covalent organic frameworks (2D‐COFs), composed of reversible imine linkages and accessible pores, offer versatility for chemical modifications towards the development of catalytic materials. Nitrogen‐enriched COFs are good candidates for binding Pd species. Understanding the local structure of reacting Pd sites bonded to the COF pores is key to rationalize interactions between active sites and porous surfaces. By combining advanced synchrotron characterization methods with...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

January 2020

 


Hendrik Naatz, Bella B. Manshian, Carla Rios Luci, Vasiliki Tsikourkitoudi, Yiannis Deligiannakis, Johannes Birkenstock, Suman Pokhrel, Lutz Mädler, Stefaan J. Soenen
Model-Based Nanoengineered Pharmacokinetics of Iron-Doped Copper Oxide for Nanomedical Applications [Research Article]
Angew. Chem. Int. Ed. 2020, vol. 59, no. 5, p. 1828

Marc-André Kasper, Marcus Gerlach, Anselm F. L. Schneider, Christiane Groneberg, Philipp Ochtrop, Stefanie Boldt, Dominik Schumacher, Jonas Helma, Heinrich Leonhardt, Mathias Christmann, Christian P. R. Hackenberger
N-Hydroxysuccinimide-Modified Ethynylphosphonamidates Enable the Synthesis of Configurationally Defined Protein Conjugates [Full Paper]
ChemBioChem 2020, vol. 21, no. 1-2, p. 113

Michael Bowker
Methanol Synthesis from CO2 Hydrogenation [Minireview]
ChemCatChem 2019, vol. 11, no. 17, p. 4238

V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin
A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article]
Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

Dieter Wöhrle
Kunststoffe [Artikel]
Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 50

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, no. 5, p. 401

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Rüdiger-A. Eichel, Walter Leitner, Kurt Wagemann
Warum wir uns mit Power-to-X beschäftigen [Editorial]
Chem. Ing. Tech. 2020, vol. 92, no. 1-2, p. 3

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Gerhard Hilt
Basic Strategies and Types of Applications in Organic Electrochemistry [Concept]
ChemElectroChem 2020, vol. 7, no. 2, p. 395

Claire M. Cobley
Introducing our Inaugural Early Career Advisory Board [Editorial]
ChemNanoMat 2020, vol. 6, no. 1, p. 4

Felix Blei, Sebastian Dörner, Janis Fricke, Florian Baldeweg, Felix Trottmann, Anna Komor, Florian Meyer, Christian Hertweck, Dirk Hoffmeister
Simultaneous Production of Psilocybin and a Cocktail of β-Carboline Monoamine Oxidase Inhibitors in “Magic” Mushrooms [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 3, p. 729

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

Arun K. Sinha, Danish Equbal
Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review]
Asian J. Org. Chem. 2019, vol. 8, no. 1, p. 32

Thomas H. Pillow, Pragya Adhikari, Robert A. Blake, Jinhua Chen, Geoffrey Del Rosario, Gauri Deshmukh, Isabel Figueroa, Karen E. Gascoigne, Amrita V. Kamath, Susan Kaufman, Tracy Kleinheinz, Katherine R. Kozak, Brandon Latifi, Douglas D. Leipold, Chun Sing Li, Ruina Li, Melinda M. Mulvihill, Aimee O'Donohue, Rebecca K. Rowntree, Jack D. Sadowsky, John Wai, Xinxin Wang, Cong Wu, Zijin Xu, Hui Yao, Shang-Fan Yu, Donglu Zhang, Richard Zang, Hongyan Zhang, Hao Zhou, Xiaoyu Zhu, Peter S. Dragovich
Antibody Conjugation of a Chimeric BET Degrader Enables in vivo Activity [Full Paper]
ChemMedChem 2020, vol. 15, no. 1, p. 17

Vitali Tugarinov, Theodoros K. Karamanos, Alberto Ceccon, G. Marius Clore
Optimized NMR Experiments for the Isolation of I=1/2 Manifold Transitions in Methyl Groups of Proteins [Communication]
ChemPhysChem 2020, vol. 21, no. 1, p. 13

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, no. 5, p. 386

Kassem Beydoun, Jürgen Klankermayer
Efficient Plastic Waste Recycling to Value-Added Products by Integrated Biomass Processing [Communication]
ChemSusChem 2020, vol. 13, no. 3, p. 488

Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief
The Periodic Table of the Chemical Elements and Sustainable Development [Essay]
Eur. J. Inorg. Chem. 2019, p. 4170

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Cover Picture Lebensmittelchemie 6/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73, no. 6

Christian Hering-Junghans, Christian Sindlinger
Trendbericht Anorganische Chemie: Hauptgruppen [Wissenschaft + Forschung]
Nachr. Chem. 2020, vol. 68, no. 1, p. 50

Jana Novotny, Corina Wagner, Marco Oetken
Titelbild: Elektrochemisch aktive Polymere am Beispiel Polypyrrol: Modellsystem einer künstlichen Synapse Ein elektrochemischer Alleskönner - Teil 2 (CHEMKON 8/2019) [Titelbild]
CHEMKON 2019, vol. 26, no. 8, p. 331

Meng Cheng, Ramasubramonian Deivanayagam, Reza Shahbazian-Yassar
3D Printing of Electrochemical Energy Storage Devices: A Review of Printing Techniques and Electrode/Electrolyte Architectures [Review]
Batteries & Supercaps 2020, vol. 3, no. 2, p. 130

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.

 


Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

Lik Hang Yuen, Raphael M. Franzini
Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview]
ChemBioChem 2017, vol. 18, pp. 829–836

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, pp. 1523–1544

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, pp. 945–956

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen
Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication]
ChemElectroChem 2017, vol. 4, pp. 1840–1845

Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang
Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper]
ChemNanoMat 2017, vol. 3, pp. 328–335

Chengwei Liu, Michal Szostak
Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview]
Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

Jian Shu, Dianping Tang
Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review]
Chem. Asian J. 2017, vol. 12, pp. 2780–2789

Jian Rong, Chuanfa Ni, Jinbo Hu
Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

Juan Alberto Sirvent, Ulrich Lücking
Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper]
ChemMedChem 2017, vol. 12, pp. 487–501

Grzegorz Greczynski, Lars Hultman
C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication]
ChemPhysChem 2017, vol. 18, pp. 1507–1512

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, pp. 148–158

Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang
Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication]
ChemSusChem 2017, vol. 10, pp. 87–90

Enzo Alessio
Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview]
Eur. J. Inorg. Chem. 2017, pp. 1549–1560

Marcel Garbe, Kathrin Junge, Matthias Beller
Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview]
Eur. J. Org. Chem. 2017, pp. 4344–4362

Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review]
Batteries Supercaps 2018, vol. 1, pp. 41–68

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

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Magazine of Chemistry Europe (16 European Chemical Societies)published by Wiley-VCH