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Chinese Journal of Chemistry

Synthesis Methods of Graphdiyne and Graphdiyne Based Materials

Published: 24 January 2022

Author(s): Quanhu Sun, Jianjiang He, Lei Gao, Tiantian Lu, Xiaodi Ma, Changshui Huang

Comprehensive Summary Graphdiyne (GDY), as a new carbon material with two‐dimensional structure composed by sp2 and sp carbon atoms, has exhibited excellent properties in various fields due to its conjugated pore structure, high specific surface area and stable structure. Various properties can also be tuned through the adjustability of the electronic structure by chemical methods. This article systematically discusses the preparation methods and strategies of GDY and GDY based materials....

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Chinese Journal of Chemistry

Cu2O Nanocrystal Model Catalysts

Published: 24 January 2022

Author(s): Zhenhua Zhang, Rui You, Weixin Huang

Comprehensive Summary Model catalysts approach is widely adopted in fundamental studies of complex heterogeneous catalysis. Traditional model catalysts are single crystal‐based model catalysts, whose results, however, sometimes suffer from the “material gap” and “pressure gap” when applied to working catalysts. Recently, uniform catalytic nanocrystals with well‐defined structures have emerged, and we have put forward a concept of nanocrystal‐based model catalysts for fundamental studies of...

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Chinese Journal of Chemistry

On Inventing Cross‐Dehydrogenative Coupling (CDC): Forming C—C Bond from Two Different C—H Bonds

Published: 24 January 2022

Author(s): Chao‐Jun Li

Comprehensive Summary Constructing C—C bonds is central to the synthesis of all chemical products. While conventional C—C bond formation methods always require one or two functional groups, 20 years ago, our establishment of the concept of Cross‐Dehydrogenative Coupling (CDC), wherein C—C bonds are directly formed from two different C—H bonds via the “formal” removal of two H atoms, has revolutionized chemical synthesis and has become one of the most active research subjects in chemistry. This...

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Biotechnology and Bioengineering

Effects of pyruvate on primary metabolism and product quality for a high‐density perfusion process

Published: 24 January 2022

Author(s): Stefania Caso, Mathieu Aeby, Martin Jordan, Raphael Guillot, Jean‐Marc Bielser

Abstract High volumetric productivities can be achieved when perfusion processes are operated at high cell densities. Yet it is fairly challenging to keep high cell density cultures in a steady state over an extended period. Aiming for robust processes, cultures were operated at a constant biomass specific perfusion rate (BSPR) in this study. The cell density was monitored with a capacitance probe and a continuous bleed maintained the targeted viable cell volume. Despite our tightly controlled...

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Advanced Materials

Replicating the Cynandra opis Butterfly's Structural Color for Bioinspired Bigrating Color Filters

Published: 24 January 2022

Author(s): Xiaobao Cao, Ying Du, Yujia Guo, Guohang Hu, Ming Zhang, Lu Wang, Jiangtao Zhou, Quan Gao, Peter Fischer, Jing Wang, Stavros Stavrakis, Andrew deMello

Abstract Multilayer grating structures, such as those found on the wings of the butterfly Cynandra opis, are able to interact with light to generate structural coloration. When illuminated and viewed at defined angles, such structural color is characterized by exceptional purity and brightness. To provide further insight into the mechanism of structural coloration, two‐photon laser lithography is used to fabricate bioinspired bigrating nanostructures, whose optical properties may be controlled...

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Journal of the American Ceramic Society

Phase equilibria in the Nd2O3–BaO–Fe2O3 system: Crystal structure, oxygen content, and properties of intermediate oxides

Published: 24 January 2022

Author(s): Tatiana V. Aksenova, Nadezhda E. Volkova, Antoine Maignan, Vladimir A. Cherepanov

Abstract The phase equilibria in the ½Nd2O3–BaO–½Fe2O3 system were systematically studied at 1373 K in air and presented in the form of a phase diagram. By X‐ray diffraction (XRD) analysis of quenched samples, the homogeneity ranges and crystal structure were determined for the following intermediate oxides: Nd1‐xBaxFeO3‐δ with 0.0 ≤ x ≤ 0.05 (space group (SG) Pnma) and with 0.6 ≤ x ≤ 0.7 (SG Pm‐3m), Ba6+yNd2‐yFe4O15‐δ with 0.0 ≤ y ≤ 0.4 (SG P63mc), and Ba1.1Nd1.9Fe2O7‐δ (SG P42/mnm). The...

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Chinese Journal of Chemistry

Synthesis of Chiral Hydantoins and Thiazolidinediones via Iridium‐Catalyzed Asymmetric Hydrogenation

Published: 24 January 2022

Author(s): Yu Nie, Jing Li, Qianjia Yuan, Wanbin Zhang

Comprehensive Summary Herein, we report an iridium‐catalyzed asymmetric hydrogenation of hydantoin and thiazolidinedione derived exocyclic alkenes using our developed BiphPHOX as a ligand. The transformation shows good functional group tolerance, and gives the hydrogenated products with excellent yields (up to 99%) and enantioselectivities (up to 98% ee). A gram‐scale reaction was also carried out, and provided the hydrogenated product in excellent yield with no erosion in enantioselectivity....

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Advanced Materials

Additive‐Free, Low‐Temperature Crystallization of Stable α‐FAPbI3 Perovskite

Published: 24 January 2022

Author(s): Tian Du, Thomas J. Macdonald, Ruo Xi Yang, Meng Li, Zhongyao Jiang, Lokeshwari Mohan, Weidong Xu, Zhenhuang Su, Xingyu Gao, Richard Whiteley, Chieh‐Ting Lin, Ganghong Min, Saif A. Haque, James R. Durrant, Kristin A. Persson, Martyn A. McLachlan, Joe Briscoe

Abstract Formamidinium lead triiodide (FAPbI3) is attractive for photovoltaic devices due to its optimal bandgap at around 1.45 eV and improved thermal stability compared with methylammonium‐based perovskites. Crystallization of phase‐pure α‐FAPbI3 conventionally requires high‐temperature thermal annealing at 150 °C whilst the obtained α‐FAPbI3 is metastable at room temperature. Here, aerosol‐assisted crystallization (AAC) is reported, which converts yellow δ‐FAPbI3 into black α‐FAPbI3 at only...

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Advanced Materials

A PF6−‐Permselective Polymer Electrolyte with Anion Solvation Regulation Enabling Long‐Cycle Dual‐Ion Battery

Published: 24 January 2022

Author(s): Hongzhu Jiang, Xiaoqi Han, Xiaofan Du, Zheng Chen, Chenglong Lu, Xintong Li, Huanrui Zhang, Jingwen Zhao, Pengxian Han, Guanglei Cui

Abstract Graphitic carbon that allows reversible anion (de)intercalation is a promising cathode material for cost‐efficient and high‐voltage dual‐ion batteries (DIBs). However, one notorious but overlooked issue is the incomplete interfacial anion desolvation, which not only reduces the oxidative stability of electrolytes, but also results in solvent co‐intercalation into graphite layers. Here, an “anion‐permselective” polymer electrolyte with abundant cationic quaternary ammonium motif is...

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Chinese Journal of Chemistry

Self‐assembly into Polymorphic 2D Nanosheets with Crystallization‐Induced Emission Enhancement

Published: 24 January 2022

Author(s): He Zhang, Dong Jin, Dongqing Lin, Lei Huang, Jin Wang, Shasha Wang, Linghai Xie

Comprehensive Summary Organic micro/nanocrystals with polymorphic tailorability and perfect platform to modulate decode the complex relationship among molecular structures, supramolecular/noncovalent interactions, aggregates and exciton behaviors. Herein, we precisely tune the polymorphic two‐dimensional organic nanosheets (2DONs) of cyano‐spirocyclic aromatic hydrocarbon (2'‐CN‐SFX), where the crystal growth processes are dominated by precursor concentration. The low concentration (ca....

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

December 2021


Dolonchampa Maji, Donghyeon Oh, Krishna Sharmah Gautam, Mingzhou Zhou, Haini Zhang, Jeff Kao, Daryl Giblin, Matthew Smith, Junha Lim, Seunghyun Lee, Youngnam Kang, Won Jong Kim, Chulhong Kim, Samuel Achilefu
Copper-Catalyzed Covalent Dimerization of Near-Infrared Fluorescent Cyanine Dyes: Synergistic Enhancement of Photoacoustic Signals for Molecular Imaging of Tumors [Cover Profile]
Anal. Sens. 2022, vol. 2, eLoc. e202100065

Oindrila Hossain, Ehsanur Rahman, Hridoy Roy, Md. Shafiul Azam, Shoeb Ahmed
Synthesis, characterization, and comparative assessment of antimicrobial properties and cytotoxicity of graphene-, silver-, and zinc-based nanomaterials [Research Article]
Anal. Sci. Adv. https://doi.org/10.1002/ansa.202100041

Witali Beichel, Julian Skrotzki, Petra Klose, Christian Njel, Burkhard Butschke, Stephan Burger, Lili Liu, Ralf Thomann, Yi Thomann, Daniel Biro, Simon Thiele, Ingo Krossing
An Artificial SEI Layer Based on an Inorganic Coordination Polymer with Self-Healing Ability for Long-Lived Rechargeable Lithium-Metal Batteries [Research Article]
Batteries Supercaps https://doi.org/10.1002/batt.202100347

Zhenyi Hu, Craig M. Crews
Recent Developments in PROTAC-Mediated Protein Degradation: From Bench to Clinic [Review]
ChemBioChem https://doi.org/10.1002/cbic.202100270

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Pooja Vadhva, Ji Hu, Michael J. Johnson, Richard Stocker, Michele Braglia, Dan J. L. Brett, Alexander J. E. Rettie
Electrochemical Impedance Spectroscopy for All-Solid-State Batteries: Theory, Methods and Future Outlook [Review]
ChemElectroChem 2021, vol. 8, no. 11, p. 1930

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Patrick Wilson, Sabrina Sorto, Aaron K. Apawu
Optimizing an Electrochemical Protocol for Quantitative Analysis of Ascorbic Acid in Dietary Supplements [Full Paper]
Chem. Methods https://doi.org/10.1002/cmtd.202100049

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Stefanie Dehnen, Peter R. Schreiner, Sangam Chatterjee, Kerstin Volz, Nils W. Rosemann, Wolf-Christian Pilgrim, Doreen Mollenhauer, Simone Sanna
Front Cover: Amorphous Molecular Materials for Directed Supercontinuum Generation (ChemPhotoChem 12/2021) [Cover Picture]
ChemPhotoChem 2021, vol. 5, no. 12, p. 1027

Thomas G. Mayerhöfer, Susanne Pahlow, Jürgen Popp
The Bouguer-Beer-Lambert Law: Shining Light on the Obscure [Review]
ChemPhysChem 2020, vol. 21, no. 18, p. 2029

Ben S. Pilgrim, Neil R. Champness
Metal-Organic Frameworks and Metal-Organic Cages - A Perspective [Review]
ChemPlusChem 2020, vol. 85, no. 8, p. 1842

Layla Filiciotto, Gadi Rothenberg
Biodegradable Plastics: Standards, Policies, and Impacts [Review]
ChemSusChem 2021, vol. 14, no. 1, p. 56

Anton I. Hanopolskyi, Viktoryia A. Smaliak, Alexander I. Novichkov, Sergey N. Semenov
Autocatalysis: Kinetics, Mechanisms and Design [Review]
ChemSystemsChem 2021, vol. 3, eLoc. e2000026

Ankit Kumar, Hem Kanwar Rathore, Debasish Sarkar, Ashok Shukla
Nanoarchitectured transition metal oxides and their composites for supercapacitors [REVIEW]
Electrochem. Sci. Adv. https://doi.org/10.1002/elsa.202100187

Maximilian Dehmel, Marius A. Wünsche, Helmar Görls, Robert Kretschmer
Dinuclear Chlorotetrylenes of Silicon, Germanium, and Tin Based on a Backbone-Bridged Bis(amidine) [Full Paper]
Eur. J. Inorg. Chem. 2021, p. 4806

Oleksandr O. Grygorenko
Enamine Ltd.: The Science and Business of Organic Chemistry and Beyond [Editorial]
Eur. J. Org. Chem. 2021, p. 6474

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemistryViews 2016

Bin Zuo, Zeye Lu, Xiaoqiang Wu, Weiwei Fang, Wanfang Li, Mingxian Huang, Dong-Yuan Yang, Qinyue Deng, Tao Tu
Cover Feature: A N-Heterocyclic Carbene-Palladacycle with Constrained Aliphatic Linker: Synthesis, Characterization and Its Catalytic Application towards Suzuki-Miyaura Cross-Coupling (Asian J. Org. Chem. 12/2021) [Cover Picture]
Asian J. Org. Chem. 2021, vol. 10, no. 12, p. 3051

Dan Zhao, Xinliang Feng
A Special Collection on 2D Materials and Their Applications [Editorial]
Chem. Asian J. 2021, vol. 16, no. 24, p. 4009

Qi Wang, Guoxiang Yang, Yangjie Fu, Ningyi Li, Derek Hao, Shengqian Ma
Nanospace Engineering of Metal-Organic Frameworks for Heterogeneous Catalysis [Review]
ChemNanoMat 2022, vol. 8, eLoc. e202100396

Johannes G. H. Hermens, Andries Jensma, Ben L. Feringa
Highly Efficient Biobased Synthesis of Acrylic Acid [Research Article]
Angew. Chem. Int. Ed. https://doi.org/10.1002/anie.202112618

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, no. 1-2, p. 17

Joachim Simon, Patrick Théato, Thomas Früh
Perspektiven der Makromolekularen Chemie [Editorial]
Chem. Unserer Zeit 2021, vol. 55, no. 6, p. 367

Marco Oetken, Jens Friedrich
Chemiedidaktik - bunt und vielfältig [Editorial]
CHEMKON 2021, vol. 28, no. 8, p. 326

Toxikologische Risikobewertung im Lebensmittelbereich [Analytik]
Lebensmittelchemie 2021, vol. 75, no. 6, p. 198

Elementerätsel 12/2021: Das schwarze Schaf [Ausgeblättert]
Nachr. Chem. 2021, vol. 69, no. 12, p. 99

Most cited articles from Chemistry Europe, ACES, and GDCh journals

Articles on this list are the most frequently cited ones among those published in 2018 or 2019 according to Web of Science. They have contributed the most to the journal's impact factor in 2020.


Jing Pan, Xin Long Tian, Shahid Zaman, Zehua Dong, Hongfang Liu, Ho Seok Park, Bao Yu Xia
Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium-Air and Zinc-Air Batteries [Minireview]
Batteries Supercaps 2019, vol. 2, pp. 336–347

Veeresh Juturu, Jin Chuan Wu
Heterologous Protein Expression in Pichia pastoris: Latest Research Progress and Applications [Review]
ChemBioChem 2018, vol. 19, pp. 7–21

Tingmin Di, Quanlong Xu, WingKei Ho, Hua Tang, Quanjun Xiang, Jiaguo Yu
Review on Metal Sulphide-based Z-scheme Photocatalysts [Review]
ChemCatChem 2019, vol. 11, pp. 1394–1411

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, pp. 6–19

Min Feng, Ming-Liang Tong
Single Ion Magnets from 3d to 5f: Developments and Strategies [Minireview]
Chem. Eur. J. 2018, vol. 24, pp. 7574–7594

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Patil S. Basavarajappa, Bhojya Naik H. Seethya, Nagaraju Ganganagappa, Kumaraswamy B. Eshwaraswamy, Raghava Reddy Kakarla
Enhanced Photocatalytic Activity and Biosensing of Gadolinium Substituted BiFeO3 Nanoparticles [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 9025–9033

Deepti Goyal, Amandeep Kaur, Bhupesh Goyal
Benzofuran and Indole: Promising Scaffolds for Drug Development in Alzheimer's Disease [Review]
ChemMedChem 2018, vol. 13, pp. 1275–1299

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, pp. 386–402

Weiyin Gao, Chenxin Ran, Jun Xi, Bo Jiao, Wenwen Zhang, Mincai Wu, Xun Hou, Zhaoxin Wu
High-Quality Cs2AgBiBr6 Double Perovskite Film for Lead-Free Inverted Planar Heterojunction Solar Cells with 2.2 % Efficiency [Communication]
ChemPhysChem 2018, vol. 19, pp. 1696–1700

Achini Japahuge, Tao Zeng
Theoretical Studies of Singlet Fission: Searching for Materials and Exploring Mechanisms [Review]
ChemPlusChem 2018, vol. 83, pp. 146–182

Peixun Xiong, Xinxin Zhao, Yunhua Xu
Nitrogen-Doped Carbon Nanotubes Derived from Metal-Organic Frameworks for Potassium-Ion Battery Anodes [Full Paper]
ChemSusChem 2018, vol. 11, pp. 202–208

Nadja Stucke, Benedikt M. Flöser, Thomas Weyrich, Felix Tuczek
Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments [Microreview]
Eur. J. Inorg. Chem. 2018, pp. 1337–1355

Davin Tan, Tomislav Friščić
Mechanochemistry for Organic Chemists: An Update [Microreview]
Eur. J. Org. Chem. 2018, pp. 18–33

Esther von Grotthuss, Alexandra John, Thomas Kaese, Matthias Wagner
Doping Polycyclic Aromatics with Boron for Superior Performance in Materials Science and Catalysis [Focus Review]
Asian J. Org. Chem. 2018, vol. 7, pp. 37–53

Min-Hua Huang, Wen-Juan Hao, Bo Jiang
Recent Advances in Radical-Enabled Bicyclization and Annulation/1,n-Bifunctionalization Reactions [Focus Review]
Chem. Asian J. 2018, vol. 13, pp. 2958–2977

Amit Kumar, Qiang Xu
Two-Dimensional Layered Materials as Catalyst Supports [Focus Review]
ChemNanoMat 2018, vol. 4, pp. 28–40

Leyre Marzo, Santosh K. Pagire, Oliver Reiser, Burkhard König
Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? [Review]
Angew. Chem. Int. Ed. 2018, vol. 57, pp. 10034–10072

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH