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The Canadian Journal of Chemical Engineering

Experimental methods in chemical engineering: Micro‐reactors

Published: 19 August 2019

Author(s): Arturo Macchi, Patrick Plouffe, Gregory S. Patience, Dominique M. Roberge

Whereas the bulk chemical industry has historically sought economic advantage through economies of scale, a paradigm shift has researchers developing systems on smaller scales. Nano‐cages and nano‐actuators increase selectivity and robustness at the molecular scale. In parallel, micro‐contactors with sub‐millimetre lateral dimensions are decreasing boundary layers that restrict heat and mass transfer and thus meet the objectives of process intensification with great increases in productivity...

The Canadian Journal of Chemical Engineering

Effect of light irradiation on esterification of oleic acid with ethanol catalyzed by immobilized Pseudomonas cepacia lipase

Published: 19 August 2019

Author(s): Huei Ruey Ong, Ponnarasy Ganasen, Md. Abul Kalam, Baranitharan Ethiraj, Mohd Sabri Mahmud, Md. Maksudur Rahman Khan

The present study demonstrates the effect of light irradiation on the esterification of oleic acid catalyzed by immobilized Pseudomonas cepacia lipase. The reaction rates of all the experiments under light irradiation were found to be higher than dark conditions. The kinetics of reactions supported the Ping‐Pong Bi‐Bi mechanism with dead end inhibition by both the alcohol and acid substrates. Moreover, circular dichroism (CD) spectroscopy was used to analyze the effect of light on lipase...

British Journal of Pharmacology

Mibefradil, a T‐type Ca2+ channel blocker also blocks Orai channels by action at the extracellular surface

Published: 19 August 2019

Author(s): Pengyun Li, Hussein N. Rubaiy, Gui‐Lan Chen, Thomas Hallett, Nawel Zaibi, Bo Zeng, Rahul Saurabh, Shang‐Zhong Xu

Background and Purpose Mibefradil, a T‐type Ca2+ channel blocker, has been investigated for treating solid tumours. However, its underlying mechanisms are still unclear. Here, we have investigated the pharmacological actions of mibefradil on Orai store‐operated Ca2+ channels. Experimental Approach Human Orai1‐3 cDNAs in tetracycline‐regulated pcDNA4/TO vectors were transfected into HEK293 T‐REx cells with stromal interaction molecule 1 (STIM1) stable expression. The Orai currents were recorded...

thumbnail image: British Journal of Pharmacology

Journal of Food Science

Headspace fingerprinting approach to identify the major pathway influencing volatile patterns of vinasse‐cured duck processed by high pressure, as well as its impact on physicochemical and sensory attributes

Published: 19 August 2019

Author(s): Qiang Xia, Tao Feng, Xiaowei Lou, Ying Wang, Yangying Sun, Daodong Pan, Jinxuan Cao

Summary As a decisive attribute, flavour could be influenced by HP treatments through multiple physical and chemical pathways within the high pressure (HP)‐assisted meat curing process. This investigation aimed to identify the major pathway influencing volatile flavour patterns of two representative vinasse‐cured duck (VCD) products with HP treatments (150–300 MPa/15 min), including wet and dry types, by employing headspace fingerprinting as an untargeted approach. Results suggested that HP...

thumbnail image: Journal of Food Science

British Journal of Pharmacology

Tipping the scales: Are females more at risk for obesity‐ and high‐fat diet‐induced hypertension and vascular dysfunction?

Published: 19 August 2019

Author(s): Lia E. Taylor, Lindsey A. Ramirez, Jacqueline B. Musall, Jennifer C. Sullivan

Obesity is a common metabolic disorder that has become a widespread epidemic in several countries. Sex and gender disparities in the prevalence of cardiovascular disease (CVD) have been well documented with premenopausal women having a lower incidence of CVD than age‐matched men. However, women are more likely than men to suffer from obesity, which can predispose them to a greater risk of CVD. The mechanisms underlying high‐fat diet (HFD)‐ or obesity‐induced hypertension are not well defined,...

Journal of Computational Chemistry

Transformation of organic sulfur and its functional groups in nantong and laigang coal under microwave irradiation

Published: 19 August 2019

Author(s): Yue Wu, Shengfu Zhang, Shuangshuang Cai, Xiong Xiao, Cheng Yin, Jian Xu, Shuxing Qiu, Wenzhou Yu, Meilong Hu, Liangying Wen

The microwave irradiation experiment of Nantong coal (NTC) and Laigang coal (LGC) has been carried out in a microwave oven and the transformation of organic sulfur and its functional groups was investigated via compact sulfur tester and Fourier transform infrared spectra. The dielectric properties of coal sample are also measured by an Agilent N5244A network analyzer. The result shows that a certain amount of organic sulfur in both NTC and LGC is transformed into iron sulfide, sulfate, and...

thumbnail image: Journal of Computational Chemistry

Journal of Heterocyclic Chemistry

XtalFluor‐E: An Efficient Reagent for Synthesis of Oxazolines from Carboxylic Acids and O‐Silylated Amino Alcohols

Published: 19 August 2019

Author(s): Vadiga Shanthi Kumar, Veera Babu Gudise, Eeda Koti Reddy, Shaik Anwar

An efficient protocol has been developed for the synthesis of 2‐oxazolines from carboxylic acids and silylated amino alcohols. The advantage of this method was demonstrated by preparing O‐silylated amino alcohols. The reaction proceeds via in situ desilylation of O‐silylated amide followed by cyclization. Studies on silyl deprotection were carried out to explain yield for 2‐oxazolines.

thumbnail image: Journal of Heterocyclic Chemistry

Lipids

The Distribution of Fatty Acid Biomarkers of Dairy Intake across Serum Lipid Fractions: The Prospective Metabolism and Islet Cell Evaluation (PROMISE) Cohort

Published: 19 August 2019

Author(s): Ingrid D. Santaren, Richard P. Bazinet, Zhen Liu, Luke W. Johnston, John L. Sievenpiper, Adria Giacca, Ravi Retnakaran, Stewart B. Harris, Bernard Zinman, Anthony J. Hanley

Abstract Circulating fatty acids (FA) derived largely from dairy consumption have most commonly been measured in total human serum or phospholipid (PL) fractions, and have been used as validated biomarkers of dairy intake in a growing number of epidemiological studies. Nevertheless, measurement and characterization of a wider spectrum of FA biomarkers of dairy across the four major serum lipid fractions is lacking. This study aimed to (1) quantify FA biomarkers of dairy in PL, triacylglycerol...

Greenhouse Gases: Science and Technology

Impact of fluid property shift and capillarity on the recovery mechanisms of CO2 injection in tight oil reservoirs

Published: 19 August 2019

Author(s): Shouya Wu, Zhaomin Li, Hemanta K. Sarma, Chao Zhang, Guangzhong Lv

Abstract The phase equilibria with the confinement effect could shift in nano‐pores, which could have a great impact on the recovery mechanisms of CO2 injection in tight oil reservoirs; this has not been systematically studied. In this paper, the confinement effect with property shift and capillarity effect is introduced into the flash calculation of confined fluids. The Soave modification of the Redlich–Kwong equation of state is extended by the molecular‐wall collision parameter to describe...

Greenhouse Gases: Science and Technology

Investigation of GHG emission sources and reducing GHG emissions in a municipal wastewater treatment plant

Published: 19 August 2019

Author(s): Özlem Demir, Pelin Yapıcıoğlu

Abstract Global warming and the greenhouse effect are two of the most important environmental problems. Carbon dioxide, methane, and nitrous oxide emissions are the main greenhouse gas emissions in wastewater treatment plants. In this study, the greenhouse gas emission sources in a wastewater treatment plant were determined. Direct (from fossil fuel combustion, methane emissions, and process emissions of the other greenhouse gases) and indirect emissions (primarily from electricity use) in the...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

February 2019


	Pingyu Zhang, Huaiyi Huang, Samya Banerjee, Guy J. Clarkson, Chen Ge, Cinzia Imberti, Peter J. Sadler Nucleus-Targeted Organoiridium-Albumin Conjugate for Photodynamic Cancer Therapy [Communication] Angew. Chem. Int. Ed. 2019, vol. 58, p. 2350

	Marion Rusch, Arnaud Thevenon, Dominic Hoepfner, Thomas Aust, Christian Studer, Maude Patoor, Patrick Rollin, Madeleine Livendahl, Beatrice Ranieri, Esther Schmitt, Carsten Spanka, Karl Gademann, Laure C. Bouchez Design and Synthesis of Metabolically Stable tRNA Synthetase Inhibitors Derived from Cladosporin [Communication] ChemBioChem 2019, vol. 20, p. 644

	Wei Jin, Laura Pastor-Pérez, DeKui Shen, Antonio Sepúlveda-Escribano, Sai Gu, Tomas Ramirez Reina Catalytic Upgrading of Biomass Model Compounds: Novel Approaches and Lessons Learnt from Traditional Hydrodeoxygenation - a Review [Review] ChemCatChem 2019, vol. 11, p. 924

	Dieter Wöhrle Kunststoffe [Artikel] Chem. Unserer Zeit 2019, vol. 53, p. 50

	Thomas Wirth Meet the Board of ChemistryOpen: Thomas Wirth [Meet the Board] ChemistryOpen 2019, vol. 8, p. 251

	Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang Chemical Sensors Based on Metal-Organic Frameworks [Review] ChemPlusChem 2016, vol. 81, p. 675

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, p. 6055

	Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen Regulatory Aspects of Nanomaterials in the EU [Research Article] Chem. Ing. Tech. 2017, vol. 89, p. 224

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, p. 75

	Mao Jiang, Kangli Wang, Shu Gao, Ruxing Wang, Jing Han, Jie Yan, Shijie Cheng, Kai Jiang Selenium as Extra Binding Site for Sulfur Species in Sulfurized Polyacrylonitrile Cathodes for High Capacity Lithium-Sulfur Batteries [Article] CHEMELECTROCHEM 2019, vol. 6, p. 1365

	Tianchao Niu, Jialin Zhang, Wei Chen Surface Engineering of Two-Dimensional Materials [Focus Review] ChemNanoMat 2019, vol. 5, p. 6

	Dennis Rottschäfer, Beate Neumann, Hans-Georg Stammler, Ryohei Kishi, Masayoshi Nakano, Rajendra S. Ghadwal A Phosphorus Analogue of p-Quinodimethane with a Planar P₄ Ring: A Metal-Free Diphosphorus Source [Communication] Chem. Eur. J. 2019, vol. 25, p. 3244

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, p. 2696

	Arun K. Sinha, Danish Equbal Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review] Asian J. Org. Chem. 2019, vol. 8, p. 32

	Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper] ChemMedChem 2018, vol. 13, p. 988

	Gloria Tabacchi Supramolecular Organization in Confined Nanospaces [Review] ChemPhysChem 2018, vol. 19, p. 1249

	Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review] ChemPhotoChem 2018, vol. 2, p. 386

	An-Na Cho, Nam-Gyu Park Impact of Interfacial Layers in Perovskite Solar Cells [Review] ChemSusChem 2017, vol. 10, p. 3687

	Didier Astruc Why is Ferrocene so Exceptional? [Microreview] Eur. J. Inorg. Chem. 2017, p. 6

	Mabuatsela V. Maphoru, Josef Heveling, Sreejarani Kesavan Pillai Solvent and Temperature Effects on the Platinum‐Catalyzed Oxidative Coupling of 1‐Naphthols [Full Paper] Eur. J. Org. Chem. 2016, p. 331

	Cover Picture Lebensmittelchemie 1/2019 [Cover Picture] Lebensmittelchemie 2019, vol. 73

	Elementerätsel 1 [Wissenschaft + Forschung] Nachr. Chem. 2019, vol. 67, p. 37

	Schüleraufgabe: CHEMKON 2/2017 [Schüleraufgabe] CHEMKON 2017, vol. 24, p. 91

	Zheng Ma, Douglas R. MacFarlane, Mega Kar Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview] Batteries & Supercaps 2019, vol. 2, p. 115

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal

2017


	Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

	Philippe Compain, Anne Bodlenner The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview] ChemBioChem 2014, vol. 15, pp. 1239–1251

	Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75

	Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

	Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez Gated Silica Mesoporous Materials in Sensing Applications [Review] ChemistryOpen 2015, vol. 4, pp. 418–437

	Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang Direct Growth of NiCo₂S₄ Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper] ChemPlusChem 2014, vol. 79, pp. 577–583

	Francisco Trespalacios, Ignacio E. Grossmann Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review] Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

	Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86

	Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127

	Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview] Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

	Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp²)–H Bonds [Focus Review] Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

	Derong Cao, Herbert Meier Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review] Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

	Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann Bromodomains and Their Pharmacological Inhibitors [Review] ChemMedChem 2014, vol. 9, pp. 438–464

	Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera The Bright Future of Unconventional σ/π-Hole Interactions [Review] ChemPhysChem 2015, vol. 16, pp. 2496–2517

	Ksenia S. Egorova, Valentine P. Ananikov Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review] ChemSusChem 2014, vol. 7, pp. 336–360

	Shunichi Fukuzumi, Dachao Hong Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview] Eur. J. Inorg. Chem. 2014, pp. 645–659

	Fabien Toulgoat, Sébastien Alazet, Thierry Billard Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview] Eur. J. Org. Chem. 2014, pp. 2415–2428

	David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar Mit Klick zu neuen Liganden [Magazin] Nachr. Chem. 2011, vol. 59, pp. 937–941