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ChemCatChem

Theoretical Study of Rhodium‐Catalyzed C−C Activation of Cyclobutanones: Origin of Ligand‐Controlled Product Selectivity

Published: 17 January 2020

Author(s): Tian Zhang, Xiajun Wu, Juan Li

Abstract Cyclobutanone C−C activation with a Rh(I) catalyst has great potential for the synthesis of fused‐ and bridged‐ring systems. However, this synthetic application is greatly limited because of the direct CO extrusion from cyclobutanone, which leads to formation of cyclopropane as a byproduct. The calculations rationalize the experimental puzzles: why PMe2Ph and XPhos ligands can prevent cyclopropane formation for C2‐ and C3‐substituted cyclobutanone, respectively. More importantly, we...

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Chemical Engineering & Technology

Selective Hydrogenation of Biomass‐Derived Succinic Acid: Reaction Network and Kinetics

Published: 17 January 2020

Author(s): Carina Heisig, Jelka Diedenhoven, Christopher Jensen, Helmut Gehrke, Thomas Turek

Abstract The conversion of bio‐based succinic acid (SA) to the value‐added chemicals 1,4‐butanediol (BDO), γ‐butyrolactone (GBL), and tetrahydrofuran (THF) can replace the corresponding petrochemical production routes to achieve a sustainable process. The reaction network for aqueous‐phase catalytic hydrogenation of succinic acid over a supported Re‐Pd catalyst was identified and the reaction kinetics was determined. With the developed kinetic model, the composition of the product mixture...

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ChemMedChem

Metal‐Organic Sheets for Efficient Drug Delivery and Bioimaging

Published: 17 January 2020

Author(s): Yucong Song, Jingjie Yang, Lei Wang, Zhigang Xie

Abstract Metal‐organic frameworks (MOFs) formed by coordination between metal ions or clusters and organic bridging ligands possess great potential for biomedicine applications, given their high biocompatibility and biodegradability. Compared with the traditional three‐dimensional (3D) MOFs, two‐dimensional (2D) MOFs with sheet‐like morphologies exhibit unique properties. In this study, a nanoscale 2D leaf‐shaped MOF (NZIF−L) was synthesized via coordination self‐assembly between...

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ChemMedChem

Protein Therapeutics. Edited by Tristan Vaughan, Jane Osbourn, and Bahija Jallal

Published: 17 January 2020

Author(s): Seah Ling Kuan

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Journal of the Chinese Chemical Society

A ratiometric fluorescent probe with high sensitivity and selectivity for phosgene sensing in solution and gas

Published: 17 January 2020

Author(s): Wu Zhou, Qian Chen, Aibin Wu, Ying Zhang, Weichu Yu

Abstract Phosgene has attracted wide attention because of its important applications and value in modern industry, agriculture, and other fields, though it easily leaks and is difficult to detect. In this work, we designed and synthesized a naphthalimide‐based fluorescent probe, which is easy to prepare, stable, and able to discriminate between phosgene, acetyl chloride, oxalyl chloride, thionyl chloride, phosphorus oxychloride, and tosyl chloride. Our results indicate that the probe can react...

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Journal of Chemical Technology & Biotechnology

Coadsorption of gaseous xylene, ethyl acetate and water onto porous biomass carbon foam pellets derived from liquefied Vallisneria natans waste

Published: 17 January 2020

Author(s): Lei Sun, Dan Yuan, Rurong Liu, Shungang Wan, Xianju Lu

Abstract BACKGROUND Only a few studies have focused on the purification of waste gas containing a mixture of volatile organic compounds (VOCs) with engineered biochar. The adsorption behaviors of gaseous xylene and ethyl acetate (EA) individually and in binary mixture onto porous biomass carbon foam pellets (BCFPs) were studied by static headspace gas chromatography. RESULTS The removal efficiency nearly reached 100% for 17.32 mg L−1 xylene and 18.02 mg L−1 EA within 120 min at a BCFP dosage...

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Particle & Particle Systems Characterization

Noninvasive Temperature Measurement in Dental Materials Using Nd3+, Yb3+ Doped Nanoparticles Emitting in the Near Infrared Region

Published: 17 January 2020

Author(s): Anderson S. L. Gomes, Junle Qu, Guanying Chen, Hao Xu, Xin Wang, Tereza Dias, Roman Ziniuk, Tymish Y. Ohulchanskyy, Artem Yakovliev

Abstract In this work, the application of near infrared (NIR)‐emitting NaYbF4:1%Tm3+@NaLuF4:30%Nd3+ core–shell nanoparticles is reported for noninvasive probing and monitoring the temperature during photopolymerization of dental materials. When excited at 808 nm, the synthesized nanoparticles emit NIR photoluminescence (PL) with two distinctive peaks at 865 and 980 nm which correspond to radiative transitions from the doped Nd3+ and Yb3+ ions, respectively. Luminescence intensity ratio between...

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Angewandte Chemie International Edition

Synthesis of Copper‐Substituted CoS2@CuxS Double‐Shelled Nanoboxes by Sequential Ion Exchange for Efficient Sodium Storage

Published: 17 January 2020

Author(s): Yongjin Fang, Deyan Luan, Ye Chen, Shuyan Gao, Xiong Wen (David) Lou

Abstract The construction of hybrid architectures for electrode materials has been demonstrated as an efficient strategy to boost sodium‐storage properties because of the synergetic effect of each component. However, the fabrication of hybrid nanostructures with a rational structure and desired composition for effective sodium storage is still challenging. In this study, an integrated nanostructure composed of copper‐substituted CoS2@CuxS double‐shelled nanoboxes (denoted as Cu‐CoS2@CuxS...

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Angewandte Chemie

Synthesis of Copper‐Substituted CoS2@CuxS Double‐Shelled Nanoboxes by Sequential Ion Exchange for Efficient Sodium Storage

Published: 17 January 2020

Author(s): Yongjin Fang, Deyan Luan, Ye Chen, Shuyan Gao, Xiong Wen (David) Lou

Abstract The construction of hybrid architectures for electrode materials has been demonstrated as an efficient strategy to boost sodium‐storage properties because of the synergetic effect of each component. However, the fabrication of hybrid nanostructures with a rational structure and desired composition for effective sodium storage is still challenging. In this study, an integrated nanostructure composed of copper‐substituted CoS2@CuxS double‐shelled nanoboxes (denoted as Cu‐CoS2@CuxS...

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Journal of Chemical Technology & Biotechnology

Dissolution of collagen fibers from tannery solid wastes in salt aqueous solutions: Hofmeister series evaluation

Published: 17 January 2020

Author(s): Keyong Tang, Guozhen Wang, Ying Pei, Zhijing Liu, Yuelong Xiao, Zhijie Li, Luan Zhang

Abstract BACKGROUND Collagen fibers from tannery solid wastes were treated with aqueous solutions of inorganic salts. The effect of the inorganic salts on the dissolution of collagen fibers and degradation of collagen were investigated. Tests of reduced viscosity and sodium dodecylsulfate polyacrylamide gel electrophoresis (SDS‐PAGE) were applied to evaluate the degree of degradation during the dissolution process. The specific ionic effects of the Hofmeister series on the dissolution of...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

December 2019

 


Duanyang Kong, Patrick J. Moon, Odey Bsharat, Rylan J. Lundgren
Direct Catalytic Decarboxylative Amination of Aryl Acetic Acids [Research Article]
Angew. Chem. Int. Ed. 2020, vol. 59, no. 3, p. 1313

Bing Liu, Lihui He, Liping Wang, Tao Li, Changcheng Li, Huayi Liu, Yunzi Luo, Rui Bao
Protein Crystallography and Site-Direct Mutagenesis Analysis of the Poly(ethylene terephthalate) Hydrolase PETase from Ideonella sakaiensis [Communication]
ChemBioChem 2018, vol. 19, no. 14, p. 1471

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, no. 7, p. 1159

Wolfgang Pfeiffer, Van Than Nguyen, Jan Neumann, Dirk Awe, Jens Tränckner
Operation and Control of a Full-Scale Biogas Plant Treating Wastewater from the Cleaning of Car Tanks [Research Article]
Chem. Eng. Technol. 2020, vol. 43, no. 1, p. 84

Dieter Wöhrle
Kunststoffe [Artikel]
Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 50

Luling Wu, Xue Tian, Hai-Hao Han, Jie Wang, Robin R. Groleau, Paramabhorn Tosuwan, Boontana Wannalerse, Adam C. Sedgwick, Steven D. Bull, Xiao-Peng He, Tony D. James
A Simple Near-Infrared Fluorescent Probe for the Detection of Peroxynitrite [Communication]
ChemistryOpen 2019, vol. 8, no. 12, p. 1407

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, no. 1-2, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Lucia Mazzapioda, Carmelo Lo Vecchio, Annalisa Paolone, Antonino Salvatore Aricò, Vincenzo Baglio, Maria Assunta Navarra
Enhancing Oxygen Reduction Reaction Catalytic Activity Using a Sub-Stoichiometric CaTiO3−δ Additive [Cover Profile]
ChemElectrochem 2019, vol. 6, no. 24, p. 5910

S. Ghosh, B. Pradhan
Lead-Free Metal Halide Perovskite Nanocrystals: Challenges, Applications, and Future Aspects [Minireview]
ChemNanoMat 2019, vol. 5, no. 3, p. 300

Frank Tabellion, Christoph Peters, Uwe Fischbeck, Manfred Regitz, Fritz Preuss
Imidovanadium(V) Complexes as Reaction Partners for Kinetically Stabilized Phosphaalkynes: Synthesis of 1,2,4‐Azaphosphavanada(V)‐cyclobutenes, 1,3,5‐Triphosphabenzenes, and 1H‐1,2,4‐Azadiphospholes [Organophosphorus Compounds, Part 148 : Full Paper]
Chem. Eur. J. 2000, vol. 6, no. 24, p. 4558

Byunghyuck Jung, Jungkyu K. Lee, Jungnam Kim, Eunhye K. Kang, Sang Yeong Han, Hee-Yoon Lee, Insung S. Choi
Synthetic Strategies for (−)-Cannabidiol and Its Structural Analogs [Minireview]
Chem. Asian J. 2019, vol. 14, no. 21, p. 3749

Arun K. Sinha, Danish Equbal
Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review]
Asian J. Org. Chem. 2019, vol. 8, no. 1, p. 32

Avick Kumar Ghosh, Indranil Samanta, Anushree Mondal, Wenshe Ray Liu
Covalent Inhibition in Drug Discovery [Review]
ChemMedChem 2019, vol. 14, no. 9, p. 889

Andrea Álvarez, Marta Borges, Juan José Corral-Pérez, Joan Giner Olcina, Lingjun Hu, Damien Cornu, Rui Huang, Dragos Stoian, Atsushi Urakawa
CO2 Activation over Catalytic Surfaces [Concept]
ChemPhysChem 2017, vol. 18, no. 22, p. 3135

Matthias Freitag, Nadja Möller, Andreas Rühling, Cristian A. Strassert, Bart Jan Ravoo, Frank Glorius
Photocatalysis in the Dark: Near-Infrared Light Driven Photoredox Catalysis by an Upconversion Nanoparticle/Photocatalyst System [Communication]
ChemPhotoChem 2019, vol. 3, no. 1, p. 24

Mingshuai Ma, Lin Dai, Chuanling Si, Lanfeng Hui, Zhong Liu, Yonghao Ni
Front Cover: A Facile Preparation of Super Long-Term Stable Lignin Nanoparticles from Black Liquor (ChemSusChem 24/2019) [Cover Picture]
ChemSusChem 2019, vol. 12, no. 24, p. 5213

Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief
The Periodic Table of the Chemical Elements and Sustainable Development [Essay]
Eur. J. Inorg. Chem. 2019, p. 4170

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Cover Picture Lebensmittelchemie 6/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73, no. 6

Elementerätsel 1 [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, no. 12, p. 40

Schüleraufgabe: CHEMKON 2/2017 [Schüleraufgabe]
CHEMKON 2017, vol. 24, no. 2, p. 91

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, no. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2017

 


Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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A product of ChemPubSoc Europe (16 European Chemical Societies)published by Wiley-VCH