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Energy Technology

Hydrothermal Synthesis and Characterization of an Apatite‐Type Lanthanum Silicate Ceramic for Solid Oxide Fuel Cell Electrolyte Applications

Published: 22 June 2018

Author(s): Paramananda Jena, Pankaj K. Patro, Amit Sinha, Raja K. Lenka, Akhilesh K. Singh, Tarasankar Mahata, Pankaj K. Sinha

Abstract Apatite‐type lanthanum silicate (La10Si6O27; LS) nanopowders are synthesized using a hydrothermal process and used for the electrolyte applications in solid oxide fuel cells (SOFCs). The synthesized nanopowders are characterized by Rietveld refinement of the X‐ray diffraction (XRD) data, SEM–energy‐dispersive X‐ray spectroscopy (EDS), TEM, and dialotometry. The prepared nanopowders can be sintered to near theoretical density at...

ChemPhysChem

Behavior of a Metal Organic Framework Thin‐Film at Elevated Temperature and Pressure as Studied with an Autoclave‐Inserted Atomic Force Microscope

Published: 22 June 2018

Author(s): Rogier P. Brand, Laurens D. B. Mandemaker, Guusje Delen, Niek Rijnveld, Bert M. Weckhuysen

Abstract Bridging the gap in studying surface reactions, processes, and morphology and measuring at (catalytic) relevant conditions is crucial for our understanding of the working principles of porous crystalline materials. Scanning tunneling microscopy is limited because of the required conductivity of the sample, whereas atomic force microscopy (AFM) is often challenging in use owing to the physical mechanism underlying the...

Energy Technology

Interfacial Thermal Resistance in Magnetocaloric Epoxy‐Bonded La‐Fe‐Co‐Si Composites

Published: 22 June 2018

Author(s): Kai Sellschopp, Bruno Weise, Maria Krautz, Francesco Cugini, Massimo Solzi, Lars Helmich, Andreas Hütten, Anja Waske

Abstract Magnetocaloric composites made from La−Fe−Co−Si particles and an epoxy binder matrix exhibit mechanical stability and good magnetocaloric properties, but also a large characteristic time for thermal transport. Here, the origin of this large time constant is examined by comparing two measurement techniques, direct and contactless, to finite‐element simulations based on a tomographic dataset of the sample. The combination of...

FEBS Journal

Molecular chaperones: from proteostasis to pathogenesis

Published: 22 June 2018

Author(s): Madhu Sudhan Ravindran

Maintaining protein homeostasis (proteostasis) is essential for a functional proteome. A wide range of extrinsic and intrinsic factors perturb proteostasis, causing protein misfolding, misassembly, and aggregation. This compromises cellular integrity and leads to aging and disease, including neurodegeneration and cancer. At the cellular level, protein aggregation is counteracted by powerful mechanisms comprising of a cascade of enzymes...

Journal of the Science of Food and Agriculture

Biochemical composition and antioxidant activity affected by spraying potassium sulfate in black grape ( Vitis vinifera L. cv. Rasha )

Published: 22 June 2018

Author(s): Elnaz Zareei, Taimoor Javadi, Rishi Aryal

Abstract BACKGROUND The physiological and metabolic processes involved with grapevine growth and production are influenced by key macro‐ and micronutrients. Potassium is an essential plant nutrient that affects growth and fruit quality. In this study, the impact of foliar spraying of potassium sulfate (K2SO4) on qualitative characteristics of grape berries was evaluated in the cultivar ‘Rasha’, a commonly cultivated...

Journal of the Science of Food and Agriculture

Antagonistic activities of volatiles produced by two Bacillus strains against Monilinia fructicola in peach fruit

Published: 22 June 2018

Author(s): Chang Liu, Xiaohui Yin, Qingguo Wang, Yong Peng, Yurong Ma, Pei Liu, Jingying Shi

Abstract BACKGROUND Brown rot caused by Monilinia fructicola is one of most serious diseases of postharvest peach fruit. The objective of this study was to select effective antagonistic bacteria against Monilinia fructicola and evaluate the effects of these strains against brown rot. RESULTS Four bacterial strains producing inhibitory volatile gas against Monilinia...

Pest Management Science

Rtt109‐dependent histone H3 K56 acetylation and gene activity are essential for the biological control potential of Beauveria bassiana

Published: 22 June 2018

Author(s): Qing Cai, Juan‐Juan Wang, Wei Shao, Sheng‐Hua Ying, Ming‐Guang Feng

Abstract BACKGROUND Rtt109 is a histone acetyltransferase that catalyzes histone H3K56 acetylation required for genomic stability, DNA damage repair and virulence‐related gene activity in yeast‐like human pathogens but remains functionally unknown in fungal insect pathogens. This study seeks to elucidate the catalytic activity of a Rtt109 orthologue and its possible role in sustaining the biological...

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Chemistry - An Asian Journal

Solvents Effects on Film Morphologies and Memory Behavior of a Perylenediimide‐Containing Pendent Polymer

Published: 22 June 2018

Author(s): Ming Wang, Qi‐jian Zhang, Zhuang Li, Hua Li, Jian‐Mei Lu

Abstract The large polydispersity index of functional pendant polymers has hindered their application in semiconductors. Herein, a novel pendant polymer with perylenediimide (PDI) in the side chains was successfully synthesized through ring‐opening metathesis polymerization (ROMP) with a very low polydispersity index. The synthesized polymers were spin‐coated on indium tin oxide (ITO) substrate by using a mixture of...

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ChemMedChem

Structural Analysis of Small‐Molecule Binding to the BAZ2A and BAZ2B Bromodomains

Published: 22 June 2018

Author(s): Andrea Dalle Vedove, Dimitrios Spiliotopoulos, Vito G. D'Agostino, Jean‐Rémy Marchand, Andrea Unzue, Cristina Nevado, Graziano Lolli, Amedeo Caflisch

Abstract The bromodomain‐containing protein BAZ2A is a validated target in prostate cancer research, whereas the function of its paralogue BAZ2B is still undefined. The bromodomains of BAZ2A and BAZ2B have a similar binding site for their natural ligand, the acetylated lysine side chain. Here, we present an analysis of the binding modes of eight compounds belonging to three distinct chemical classes. For all compounds, the moiety...

Angewandte Chemie

Hole Mobility Modulation in Single‐Crystal Metal Phthalocyanines by Changing the Metal–π/π–π Interactions

Published: 22 June 2018

Author(s): Hui Jiang, Peng Hu, Jun Ye, Rakesh Ganguly, Yongxin Li, Yi Long, Denis Fichou, Wenping Hu, Christian Kloc

Abstract Weak intermolecular interactions in organic semiconducting molecular crystals play an important role in determining molecular packing and electronic properties. Single crystals of metal‐free and metal phthalocyanines were synthesized to investigate how the coordination of the central metal atom affects their molecular packing and resultant electronic properties. Single‐crystal field‐effect transistors were made and showed a...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

March 2018


	Zhang Luo, Bing Liu Shape-Tunable Colloids from Structured Liquid Droplet Templates [Cover Picture] Angew. Chem. Int. Ed. 10.1002/anie.201802726

	Coline Jumeaux, Olov Wahlsten, Stephan Block, Eunjung Kim, Rona Chandrawati, Philip D. Howes, Fredrik Höök, Molly M. Stevens MicroRNA Detection by DNA-Mediated Liposome Fusion [Communication] ChemBioChem 2018, vol. 19, p. 434

	Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper] ChemCatChem 2011, vol. 3, p. 1159

	Matthias Schäfer, Bernhard Hauck, Jochen Kuhn, Roland Ulber Analytik mit Licht - Das Smartphone-Photometer [Artikel] Chem. Unserer Zeit 2018, vol. 52, p. 52

	Balaram Mukhopadhyay, Rituparna Das Chemical O-Glycosylations: An Overview [Review] ChemistryOpen 2016, vol. 5, p. 401

	Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, p. 945

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, p. 6055

	Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen Regulatory Aspects of Nanomaterials in the EU [Research Article] Chem. Ing. Tech. 2017, vol. 89, p. 224

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, p. 75

	Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl [M(CO)₄(2,2'-bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO₂ at a Gold Electrode [Communication] ChemElectroChem 2015, vol. 2, p. 213

	Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review] ChemNanoMat 2017, vol. 3, p. 352

	Maximilian Koy, Frederik Sandfort, Adrian Tlahuext-Aca, Linda Quach, Constantin G. Daniliuc, Frank Glorius Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light [Communication] Chem. Eur. J. 2018, vol. 24, p. 4552

	Jian Lv, Qi Zhang, Mao Cai, Yanfang Han, Sanzhong Luo Aromatic Aminocatalysis [Focus Review] Chem. Asian J. 2018, vol. 13, p. 740

	Hidetoshi Noda, Naoya Kumagai, Masakatsu Shibasaki Abstract [Focus Review] Asian J. Org. Chem. 10.1002/ajoc.201800013

	Albert J. Kooistra, Márton Vass, Ross McGuire, Rob Leurs, Iwan J. P. de Esch, Gert Vriend, Stefan Verhoeven, Chris de Graaf 3D-e-Chem: Structural Cheminformatics Workflows for Computer-Aided Drug Discovery [Full Paper] ChemMedChem 2018, vol. 13, p. 614

	Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi A Review on Bimetallic Nickel-Based Catalysts for CO₂ Reforming of Methane [Review] ChemPhysChem 2017, vol. 18, p. 3117

	Turkan Gamze Ulusoy Ghobadi, Amir Ghobadi, Ekmel Ozbay, Ferdi Karadas Strategies for Plasmonic Hot-Electron-Driven Photoelectrochemical Water Splitting [Review] ChemPhotoChem 2018, vol. 2, p. 161

	An-Na Cho, Nam-Gyu Park Impact of Interfacial Layers in Perovskite Solar Cells [Review] ChemSusChem 2017, vol. 10, p. 3687

	Jeffrey A. Rood, Sondra E. Hinman, Bruce C. Noll, Kenneth W. Henderson The Use of Halide-Substituted Anilines for the Formation of Magnesium Imides [Full Paper] Eur. J. Inorg. Chem. 2008, p. 3935

	D. B. Ramachary [Author Profile] Eur. J. Org. Chem. 10.1002/ejoc.201800182

	46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung] Lebensmittelchemie 2018, vol. 72, p. 1

	Peter Chen Chemistry 4.0 [Leitartikel] Nachr. Chem. 2018, vol. 66, p. 203

	Ira Caspari, Gisela Weber-Peukert, Nicole Graulich Der Einsatz von Modellen zum Erkenntnisgewinn / Eine Unterrichtseinheit zur Förderung der Modellkompetenz im Kontext „Batterie“ unter explizitem Einbezug von Schülervorstellungen [Aus der Schule] CHEMKON 2018, vol. 25, p. 23

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal

2016


	Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

	Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke Fluorescent Probes for G-Quadruplex Structures [Review] ChemBioChem 2013, vol. 14, pp. 540–558

	Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75

	Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

	Marc Steinmetz, Stefan Grimme Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper] ChemistryOpen 2013, vol. 2, pp. 115–124

	Philipp Scharf, Jens Müller Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review] ChemPlusChem 2013, vol. 78, pp. 20–34

	Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess Production of Liquid Hydrocarbons with CO₂ as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article] Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

	Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86

	Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127

	Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper] Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

	Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp²)–H Bonds [Focus Review] Chem. Asian J. 2014, vol. 9, pp. 26–47

	Naohiko Yoshikai, Ye Wei Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review] Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

	Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper] ChemMedChem 2013, vol. 8, pp. 313–321

	Peter Politzer, Jane S. Murray Halogen Bonding: An Interim Discussion [Review] ChemPhysChem 2013, vol. 14, pp. 278–294

	Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review] ChemSusChem 2013, vol. 6, pp. 746–789

	Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou Spin Crossover at the Nanometre Scale [Microreview] Eur. J. Inorg. Chem. 2013, pp. 653–661

	Junichiro Yamaguchi, Kei Muto, Kenichiro Itami Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview] Eur. J. Org. Chem. 2013, pp. 19–30

	David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar Mit Klick zu neuen Liganden [Magazin] Nachr. Chem. 2011, vol. 59, pp. 937–941