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Chemistry - A European Journal

N‐Ethynylation of Anilides Decreases the Double‐Bond Character of Amide Bond while Retaining trans‐Conformation and Planarity

Published: 26 June 2019

Author(s): Ryu Yamasaki, Kento Morita, Hiromi Iizumi, Ai Ito, Kazuo Fukuda, Iwao Okamoto

Abstract Activated amide bonds have been attracting intense attention; however, most of the studied moieties have twisted amide character. To add a new strategy to activate amide bonds while maintaining its planarity, we envisioned the introduction of an alkynyl group on the amide nitrogen to disrupt amide resonance by nN→Csp conjugation. In this context, the conformations and properties of N‐ethynyl‐substituted aromatic amides were investigated by DFT calculations, crystallography, and NMR...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Selective Hydrogenation of CO2 Dictated by Isomers in Au28(SR)20 Nanoclusters: Which One is Better?

Published: 26 June 2019

Author(s): Jiayu Xu, Mingyang Chen, Yan Zhu

Abstract It is a challenge to make clear how isomerism in a heterogeneous catalyst induces distinct differences in catalytic properties, as attainment of the structural isomerism in a conventional catalyst is difficult. By successfully identifying the isomerism in the atomically precise Au nanoclusters, an exciting opportunity for unravelling catalysis of isomeric catalysts is opened up. Herein, we report that the isomerism in the Au28(SR)20 nanoclusters with different surface atom...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Transition‐Metal‐Free Aryl–Aryl Cross‐Coupling: C−H Arylation of 2‐Naphthols with Diaryliodonium Salts

Published: 26 June 2019

Author(s): Manoj K. Ghosh, Jan Rzymkowski, Marcin Kalek

Abstract Transition‐metal‐free regioselecitive C−H arylation of 2‐naphthols with diaryliodonium salts has been developed. The reaction proceeds under very simple experimental conditions and affords a range of products with various substitution patterns. The method allows for the incorporation of electron‐deficient aryls, which complements well currently existing metal‐free aryl–aryl cross‐couplings of phenols that have been so far restricted to the introduction of electron‐rich aryl moieties....

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Crystal Structures and Melting Behaviors of 2D and 3D Anionic Coordination Polymers Containing Organometallic Ionic Liquid Components

Published: 26 June 2019

Author(s): Hironori Kimata, Tomoyuki Mochida

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Mixture of Azolium Tetraphenylborate with Isopropylthioxanthone: A New Class of N‐Heterocyclic Carbene (NHC) Photogenerator for Polyurethane, Polyester, and ROMP Polymers Synthesis

Published: 26 June 2019

Author(s): Thi Kim Hoang Trinh, Jean‐Pierre Malval, Fabrice Morlet‐Savary, Julien Pinaud, Patrick Lacroix‐Desmazes, Corine Reibel, Valérie Héroguez, Abraham Chemtob

Abstract In the search of smarter routes to control the conditions of N‐heterocyclic carbene (NHCs) formation, a two‐component air‐stable NHC photogenerating system is reported. It relies on the irradiation at 365 nm of a mixture of 2‐isopropylthioxanthone (ITX) with 1,3‐bis(mesityl)imidazoli(ni)um tetraphenylborate. The photoinduced liberation of NHC is evidenced by reaction with a mesitoyl radical to form an NHC‐radical adduct detectable by electron spin resonance spectroscopy. The NHC yield...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Excited‐State Kinetics of an Air‐Stable Cyclometalated Iron(II) Complex

Published: 26 June 2019

Author(s): Jakob Steube, Lukas Burkhardt, Ayla Päpcke, Johannes Moll, Peter Zimmer, Roland Schoch, Christoph Wölper, Katja Heinze, Stefan Lochbrunner, Matthias Bauer

Abstract The complex class [Fe(N^N^C)(N^N^N)]+ with an Earth‐abundant metal ion has been repeatedly suggested as a chromophore and potential photosensitizer on the basis of quantum chemical calculations. Synthesis and photophysical properties of the parent complex [Fe(pbpy)(tpy)]+ (Hpbpy=6‐phenyl‐2,2′‐bipyridine and tpy=2,2′:6′,2′′‐terpyridine) of this new chromophore class are now reported. Ground‐state characterization by X‐ray diffraction, electrochemistry, spectroelectrochemistry, UV/Vis,...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Design of and Stability Studies on Trefoil Knots Featuring RhCp* Building Blocks

Published: 26 June 2019

Author(s): Bei‐Bei Guo, Yue‐Jian Lin, Guo‐Xin Jin

Abstract Four flexible ligands with different lengths, degrees of flexibility, and steric bulk were synthesized and used to prepare metal‐directed assemblies. Interestingly, minor differences among the ligands led to products with dramatically different topologies: a binuclear D‐shaped macrocycle, tetranuclear rectangles, and hexanuclear trefoil knots. The interconversion of the trefoil‐shaped complexes was also investigated. This contribution introduces a rare ligand‐controlled...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Exploring the Role of Coinage Metalates in Trifluoromethylation: A Combined Experimental and Theoretical Study

Published: 26 June 2019

Author(s): Sara Martínez de Salinas, Ángel L. Mudarra, Carlota Odena, Marta Martínez Belmonte, Jordi Benet‐Buchholz, Feliu Maseras, Mónica H. Pérez‐Temprano

thumbnail image: Chemistry - A European Journal

British Journal of Pharmacology

A photoswitchable GABA receptor channel blocker

Published: 26 June 2019

Author(s): Galyna Maleeva, Daniel Wutz, Karin Rustler, Alba Nin‐Hill, Carme Rovira, Elena Petukhova, Antoni Bautista‐Barrufet, Alexandre Gomila‐Juaneda, Petra Scholze, Franck Peiretti, Mercedes Alfonso‐Prieto, Burkhard König, Pau Gorostiza, Piotr Bregestovski

Background and Purpose Anion‐selective Cys‐loop receptors (GABA and glycine receptors) provide the main inhibitory drive in the CNS. Both types of receptor operate via chloride‐selective ion channels, though with different kinetics, pharmacological profiles, and localization. Disequilibrium in their function leads to a variety of disorders, which are often treated with allosteric modulators. The few available GABA and glycine receptor channel blockers effectively suppress inhibitory currents...

thumbnail image: British Journal of Pharmacology

Chemistry - A European Journal

Some Recent Advances in the Design and Use of Molecular Balances for the Experimental Quantification of Intramolecular Noncovalent Interactions of π Systems

Published: 26 June 2019

Author(s): Abil E. Aliev, William B. Motherwell

Abstract Herein, various molecular balances used for comparing the strengths of intramolecular noncovalent interactions are reviewed. Our overview indicates that considerable quantitative insight into the strength of noncovalent interactions can be gained through the careful design of molecular balances. Many exciting opportunities certainly exist for the design of further new balances to quantify and dissect the relative strengths of noncovalent interactions as a function of solvation and the...

thumbnail image: Chemistry - A European Journal

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

February 2019


Pingyu Zhang, Huaiyi Huang, Samya Banerjee, Guy J. Clarkson, Chen Ge, Cinzia Imberti, Peter J. Sadler
Nucleus-Targeted Organoiridium-Albumin Conjugate for Photodynamic Cancer Therapy [Communication]
Angew. Chem. Int. Ed. 2019, vol. 58, p. 2350

Marion Rusch, Arnaud Thevenon, Dominic Hoepfner, Thomas Aust, Christian Studer, Maude Patoor, Patrick Rollin, Madeleine Livendahl, Beatrice Ranieri, Esther Schmitt, Carsten Spanka, Karl Gademann, Laure C. Bouchez
Design and Synthesis of Metabolically Stable tRNA Synthetase Inhibitors Derived from Cladosporin [Communication]
ChemBioChem 2019, vol. 20, p. 644

Wei Jin, Laura Pastor-Pérez, DeKui Shen, Antonio Sepúlveda-Escribano, Sai Gu, Tomas Ramirez Reina
Catalytic Upgrading of Biomass Model Compounds: Novel Approaches and Lessons Learnt from Traditional Hydrodeoxygenation - a Review [Review]
ChemCatChem 2019, vol. 11, p. 924

Dieter Wöhrle
Kunststoffe [Artikel]
Chem. Unserer Zeit 2019, vol. 53, p. 50

Thomas Wirth
Meet the Board of ChemistryOpen: Thomas Wirth [Meet the Board]
ChemistryOpen 2019, vol. 8, p. 251

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Mao Jiang, Kangli Wang, Shu Gao, Ruxing Wang, Jing Han, Jie Yan, Shijie Cheng, Kai Jiang
Selenium as Extra Binding Site for Sulfur Species in Sulfurized Polyacrylonitrile Cathodes for High Capacity Lithium-Sulfur Batteries [Article]
CHEMELECTROCHEM 2019, vol. 6, p. 1365

Tianchao Niu, Jialin Zhang, Wei Chen
Surface Engineering of Two-Dimensional Materials [Focus Review]
ChemNanoMat 2019, vol. 5, p. 6

Dennis Rottschäfer, Beate Neumann, Hans-Georg Stammler, Ryohei Kishi, Masayoshi Nakano, Rajendra S. Ghadwal
A Phosphorus Analogue of p-Quinodimethane with a Planar P4 Ring: A Metal-Free Diphosphorus Source [Communication]
Chem. Eur. J. 2019, vol. 25, p. 3244

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Arun K. Sinha, Danish Equbal
Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review]
Asian J. Org. Chem. 2019, vol. 8, p. 32

Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss
Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper]
ChemMedChem 2018, vol. 13, p. 988

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, p. 386

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Didier Astruc
Why is Ferrocene so Exceptional? [Microreview]
Eur. J. Inorg. Chem. 2017, p. 6

Mabuatsela V. Maphoru, Josef Heveling, Sreejarani Kesavan Pillai
Solvent and Temperature Effects on the Platinum‐Catalyzed Oxidative Coupling of 1‐Naphthols [Full Paper]
Eur. J. Org. Chem. 2016, p. 331

Cover Picture Lebensmittelchemie 1/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73

Elementerätsel 1 [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, p. 37

Schüleraufgabe: CHEMKON 2/2017 [Schüleraufgabe]
CHEMKON 2017, vol. 24, p. 91

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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