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Photochemistry and Photobiology

Strained, Photoejecting Ru(II) Complexes that are Cytotoxic Under Hypoxic Conditions

Published: 07 December 2019

Author(s): John Roque, Dmytro Havrylyuk, Patrick C. Barrett, Tariq Sainuddin, Julia McCain, Katsuya Colón, William T. Sparks, Evan Bradner, Susan Monro, David Heidary, Colin G. Cameron, Edith C. Glazer, Sherri A. McFarland

Abstract A series of strained Ru(II) complexes were studied for potential anticancer activity in hypoxic tissues. The complexes were constructed with methylated ligands that were photolabile and an imidizo[4,5‐f][1,10]phenanthroline ligand that contained an appended aromatic group to potentially allow for contributions of ligand‐centered excited states. A systematic variation of the size and energy of the aromatic group was performed using systems containing 1–4 fused rings, and the...

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Photochemistry and Photobiology

Reactive Oxygen Species Explicit Dosimetry for Photofrin‐mediated Pleural Photodynamic Therapy

Published: 07 December 2019

Author(s): Yi Hong Ong, Andreaa Dimofte, Michele M. Kim, Jarod C. Finlay, Tianqi Sheng, Sunil Singhal, Keith A. Cengel, Arjun G. Yodh, Theresa M. Busch, Timothy C. Zhu

Abstract Explicit dosimetry of treatment light fluence and implicit dosimetry of photosensitizer photobleaching are commonly used methods to guide dose delivery during clinical PDT. Tissue oxygen, however, is not routinely monitored intraoperatively even though it is one of the three major components of treatment. Quantitative information about in vivo tissue oxygenation during PDT is desirable, because it enables reactive oxygen species explicit dosimetry (ROSED) for prediction of treatment...

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Journal of Heterocyclic Chemistry

Synthesis of fused hydroxy dihydropyrroles and unexpected dihydropyrazine and dihydroquinoxaline derivatives based on heterocyclic ketene aminals

Published: 07 December 2019

Author(s): Monireh Rezaei, Mohammad Bayat, Behrouz Notash

Abstract The one‐pot four‐component synthesis of highly functionalized fused hydroxyl dihydropyrroles and dihydropyrazines from readily available diamines, 1,1‐bis (methylsulfanyl)‐2‐nitroethene, phenylglyoxal monohydrates, and C‐H acids have been developed. This strategy provides an efficient, catalyst‐free approach for easy access to various new hydroxyl‐dihydropyrrole and dihydropyrazine rings in good to high yields. The products were confirmed by 1H and 13C NMR, IR, mass, and X‐ray crystal...

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International Journal of Applied Ceramic Technology

The fracture properties of metal‐ceramic composites manufactured via stereolithography

Published: 07 December 2019

Author(s): Bhargavi Mummareddy, Michael Maravola, Eric MacDonald, Jason Walker, Brian Hetzel, Brett Conner, Pedro Cortes

Abstract In this work, metal‐ceramic composite parts based on aluminum and alumina were manufactured in a two‐stage process. First, silica was printed using a vat photopolymerization technique, followed by a curing and sintering stage, which resulted in ceramic precursors. Subsequently, these samples were subjected to a metal infiltration process to form interpenetrating metal‐ceramic composites (IPCs). These composites have attracted considerable attention in the aerospace and defense sector...

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FEBS Journal

Cardiac regeneration and remodelling of the cardiomyocyte cytoarchitecture

Published: 07 December 2019

Author(s): Hashim Ali, Luca Braga, Mauro Giacca

Adult mammals are unable to regenerate their hearts after cardiac injury, largely due to the incapacity of cardiomyocytes (CMs) to undergo cell division. However, mammalian embryonic and fetal CMs, similar to CMs from fish and amphibians during their entire life, exhibit robust replicative activity, which stops abruptly after birth and never significantly resumes. Converging evidence indicates that formation of the highly ordered and stable cytoarchitecture of mammalian mature CMs is coupled...

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Journal of Heterocyclic Chemistry

Highlights on the synthesis of novel phenothiazine‐based azines scaffold as antioxidant agents

Published: 07 December 2019

Author(s): Wafaa S. Hamama, Moustafa A. Gouda, Hadwah A. Kamal El‐din, Hanafi H. Zoorob

Abstract Azines derivatives of phenothiazines were synthetically constructed from one‐pot multicomponent reactions of 1‐(4a,10a‐dihydro‐10H‐phenothiazin‐2‐yl)ethan‐1‐one with various reagents. The obtained novel target compounds were evaluated as antioxidant agents using ABTS+• scavenging assay. Antioxidant results revealed that the incorporation of azines to phenothiazine ring system enhanced the activity. In addition, compound 18 prevent the damage of DNA due to the formation of...

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Journal of Heterocyclic Chemistry

Amine‐carbon disulfide promoted synthesis of novel benzo[e][1,3]thiazepin‐5(1H)‐one derivatives

Published: 07 December 2019

Author(s): Mohammad Sadegh Asgari, Saeed Bahadorikhalili, Mehdi Asadi, Parviz Rashidi Ranjbar, Bagher Larijani, Rahmatollah Rahimi, Mohammad Mahdavi

Abstract In this paper, a simple method is introduced for the synthesis of novel 4‐substituted‐3‐thioxo‐3,4‐dihydrobenzo[e][1,3]thiazepin‐5(1H)‐one derivatives. The synthesis is based on a two‐step reaction of 2‐methylbenzoic acid, an amine, and carbon disulfide. In the first step, 2‐methylbenzoic acid reacts with sulfuric acid in ethanol, followed by the reaction with N‐bromosuccinimide to produce ethyl 2‐(bromomethyl)benzoate. Amine and carbon disulfide react in a separate flask in basic...

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Journal of Food Science

Applications of soy protein hydrolysates in the emerging functional foods: a review

Published: 07 December 2019

Author(s): Tolulope Joshua Ashaolu

Summary Several applications of protein hydrolysates have been documented including gelation, solubility and emulsifying properties. However, very rare reviews have solely explored the potentials of soy protein hydrolysates (SPHs). Varying and abundant pieces of information on the physicochemical properties of soy proteins, such as foaming, solubility, emulsifying, gelling, fat‐ and water‐holding capacities, suggest their hydrolysates to be equally or more important. In this regard, this...

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Journal of Food Science

Development of pectin–eugenol emulsion coatings for inhibition of Listeria on webbed‐rind melons: a comparative study with fig and citrus pectins

Published: 07 December 2019

Author(s): Elif Çavdaroğlu, Stefano Farris, Ahmet Yemenicioğlu

Summary The objective of this study was to employ pectin‐based antimicrobial coatings for inhibition of Listeria on surfaces of whole webbed‐rind melons that cause frequent outbreaks of listeriosis. For this purpose, emulsion‐based coatings were developed using citrus pectin (CPEC) or pectin extracted from processing wastes of sun‐dried figs (FPEC) and eugenol (EUG). The emulsions of FPEC and CPEC with EUG (droplet size range: 1.99–11.22 µm) were highly stable for minimum 10 days at 10 °C. The...

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Journal of Food Science

Comparison of Lupinus angustifolius protein digestibility in dependence on protein, amino acids, trypsin inhibitors and polyphenolic compounds content

Published: 07 December 2019

Author(s): Magdalena Zielińska‐Dawidziak, Aneta Tomczak, Marta Burzyńska, Ewa Rokosik, Krzysztof Dwiecki, Dorota Piasecka‐Kwiatkowska

Summary Lupine seeds are proposed as a source of valuable protein in human and animal nutrition. However, not only protein content but its bioavailability is important. Thus, the protein digestibility of twenty Lupinus angustifolius varieties seeds and the impact of some factors (protein and polyphenols content, trypsin inhibition and amino acids composition) on the protein digestion were discussed. Composition as well as the digestibility of these seeds was influenced by variety, weather...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

August 2019

 


Hartmuth C. Kolb, M. G. Finn, K. Barry Sharpless
Click Chemistry: Diverse Chemical Function from a Few Good Reactions [Review]
Angew. Chem. Int. Ed. 2001, vol. 40, no. 11, p. 2004

Bing Liu, Lihui He, Liping Wang, Tao Li, Changcheng Li, Huayi Liu, Yunzi Luo, Rui Bao
Protein Crystallography and Site-Direct Mutagenesis Analysis of the Poly(ethylene terephthalate) Hydrolase PETase from Ideonella sakaiensis [Communication]
ChemBioChem 2018, vol. 19, no. 14, p. 1471

Petra E. de Jongh, Deryn E. Fogg, Li-Zhu Wu, Sandra González-Gallardo
Meet the Women of Catalysis [Editorial]
ChemCatChem 2019, vol. 11, no. 16, p. 3557

V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin
A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article]
Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

Rainer Stosch, Olaf Rienitz, Axel Pramann, Bernd Güttler
Wie viele Moleküle enthält ein Mol? [Artikel]
Chem. Unserer Zeit 2019, vol. 53, no. 4, p. 256

Benjamin A. E. Lehner, Vera A. E. C. Janssen, Ewa M. Spiesz, Dominik Benz, Stan J. J. Brouns, Anne S. Meyer, Herre S. J. van der Zant
Creation of Conductive Graphene Materials by Bacterial Reduction Using Shewanella Oneidensis [Full Paper]
ChemistryOpen 2019, vol. 8, no. 7, p. 888

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, no. 7, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Michael C. Zimmermann, Thomas N. Otto, Simon Wodarz, Thomas A. Zevaco, Stephan Pitter
Mesoporous H-ZSM-5 for the Conversion of Dimethyl Ether to Hydrocarbons [Research Article]
Chem. Ing. Tech. 2019, vol. 91, no. 9, p. 1302

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Andrey Shatskiy, Helena Lundberg, Markus D. Kärkäs
Organic Electrosynthesis: Applications in Complex Molecule Synthesis [Review]
ChemElectroChem 2019, vol. 6, no. 16, p. 4067

S. Ghosh, B. Pradhan
Lead-Free Metal Halide Perovskite Nanocrystals: Challenges, Applications, and Future Aspects [Minireview]
ChemNanoMat 2019, vol. 5, no. 3, p. 300

João M. J. M. Ravasco, Hélio Faustino, Alexandre Trindade, Pedro M. P. Gois
Bioconjugation with Maleimides: A Useful Tool for Chemical Biology [Review]
Chem. Eur. J. 2019, vol. 25, no. 1, p. 43

Stephanie C. C. van der Lubbe, Célia Fonseca Guerra
The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths [Minireview]
Chem. Asian J. 2019, vol. 14, no. 16, p. 2760

Adrian G. Amador, Evan M. Sherbrook, Tehshik P. Yoon
A Redox Auxiliary Strategy for Pyrrolidine Synthesis via Photocatalytic [3+2] Cycloaddition [Full Paper]
Asian J. Org. Chem. 2019, vol. 8, no. 7, p. 978

Avick Kumar Ghosh, Indranil Samanta, Anushree Mondal, Wenshe Ray Liu
Covalent Inhibition in Drug Discovery [Review]
ChemMedChem 2019, vol. 14, no. 9, p. 889

Andrea Álvarez, Marta Borges, Juan José Corral-Pérez, Joan Giner Olcina, Lingjun Hu, Damien Cornu, Rui Huang, Dragos Stoian, Atsushi Urakawa
CO2 Activation over Catalytic Surfaces [Concept]
ChemPhysChem 2017, vol. 18, no. 22, p. 3135

Matthias Freitag, Nadja Möller, Andreas Rühling, Cristian A. Strassert, Bart Jan Ravoo, Frank Glorius
Photocatalysis in the Dark: Near-Infrared Light Driven Photoredox Catalysis by an Upconversion Nanoparticle/Photocatalyst System [Communication]
ChemPhotoChem 2019, vol. 3, no. 1, p. 24

Biwei Xiao, Teófilo Rojo, Xiaolin Li
Hard Carbon as Sodium-Ion Battery Anodes: Progress and Challenges [Minireview]
ChemSusChem 2019, vol. 12, no. 1, p. 133

Didier Astruc
Why is Ferrocene so Exceptional? [Microreview]
Eur. J. Inorg. Chem. 2017, p. 6

Kennedy J. Ngwira, Jonas Kühlborn, Quintino A. Mgani, Charles B. de Koning, Till Opatz
Front Cover: Valorisation of Cashew Nut Shell Liquid Phenolics in the Synthesis of UV Absorbers (Eur. J. Org. Chem. 30/2019) [Cover Picture]
Eur. J. Org. Chem. 2019, p. 4763

Cover Picture Lebensmittelchemie 4/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73, no. 4

Olaf Deutschmann, Roland Dittmeyer, Jan-Dierk Grunwaldt, Gunther Kolb, Stefan Löbbecke, Gregor D. Wehinger
Technische Chemie [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, no. 6, p. 50

Titelbild: (CHEMKON 5/2019) [Titelbild]
CHEMKON 2019, vol. 26, no. 5, p. 173

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, no. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2017

 


Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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