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Advanced Materials

Hydration‐Effect‐Promoting Ni–Fe Oxyhydroxide Catalysts for Neutral Water Oxidation

Published: 17 January 2020

Author(s): Ning Wang, Zhen Cao, Xueli Zheng, Bo Zhang, Sergey M. Kozlov, Peining Chen, Chengqin Zou, Xiangbin Kong, Yunzhou Wen, Min Liu, Yansong Zhou, Cao Thang Dinh, Lirong Zheng, Huisheng Peng, Ying Zhao, Luigi Cavallo, Xiaodan Zhang, Edward H. Sargent

Abstract Oxygen evolution reaction (OER) catalysts that function efficiently in pH‐neutral electrolyte are of interest for biohybrid fuel and chemical production. The low concentration of reactant in neutral electrolyte mandates that OER catalysts provide both the water adsorption and dissociation steps. Here it is shown, using density functional theory simulations, that the addition of hydrated metal cations into a Ni–Fe framework contributes water adsorption functionality proximate to the...

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Energy Technology

Solid versus Liquid—A Bottom‐Up Calculation Model to Analyze the Manufacturing Cost of Future High‐Energy Batteries

Published: 17 January 2020

Author(s): Gunther Reinhart, Anna Julia Imbsweiler, Heiko Knörzer, Joscha Schnell

All‐solid‐state batteries (ASSB) are promising candidates for future energy storage. However, only a little is known about the manufacturing costs for industrial production. Herein, a detailed bottom‐up calculation is performed to estimate the required investment and to facilitate comparison with conventional lithium‐ion batteries (LIB). Results indicate that sulfide‐based ASSBs can indeed be competitive if the material compatibility issues can be solved and production is successfully scaled....

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British Journal of Clinical Pharmacology

A phase 1/1b study of PUR1900, an inhaled formulation of itraconazole, in healthy volunteers and asthmatics to study safety, tolerability and pharmacokinetics

Published: 17 January 2020

Author(s): David L. Hava, Lisa Tan, Patrick Johnson, Aidan K. Curran, Jason Perry, Steve Kramer, Katie Kane, Pauline Bedwell, Gary Layton, Clarie Swann, Dennis Henderson, Naimat Khan, Lucy Connor, Litza McKenzie, Dave Singh, James Roach

Aims Oral itraconazole has variable pharmacokinetics and risks of adverse events associated with high plasma exposure. An inhalation formulation of itraconazole (PUR1900) is being developed to treat allergic bronchopulmonary aspergillosis, an allergic inflammatory disease occurring in asthmatics and patients with cystic fibrosis. Methods A 3‐part, open‐label Phase 1 study was conducted to evaluate safety, tolerability and pharmacokinetics of PUR1900. Healthy volunteers (n = 5–6/cohort)...

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British Journal of Clinical Pharmacology

Direct oral anticoagulants uptake and an oral anticoagulation paradox

Published: 17 January 2020

Author(s): Cormac Kennedy, Caitriona Ni Choitir, Sarah Clarke, Kathleen Bennett, Michael Barry

Oral anticoagulation (OAC) for stroke prevention in patients with atrial fibrillation is underutilised. One of the impediments to warfarin therapy is the frequent monitoring required, usually at a specialised warfarin clinic. The advent of direct oral anticoagulants (DOACs) facilitates OAC therapy without an onerous monitoring regimen. This benefit may result in the more significant adoption of DOACs in areas without a warfarin clinic. This study analysed national administrative data for...

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British Journal of Clinical Pharmacology

Serious adverse effects occurring after chemotherapy: A general cancer registry‐based incidence survey

Published: 17 January 2020

Author(s): Marie‐Christine Pérault‐Pochat, Pierre Ingrand, Aurélie Ferru, François Chavant, Claire Lafay‐Chebassier, Gautier Defossez, Isabelle Ingrand

Aims Pharmaco‐epidemiological surveys enable the frequency of serious adverse effects—and also the determining factors of their occurrence and seriousness—to be quantified. Few studies systematically gathering post‐chemotherapy adverse effects data have been conducted. The objective was to assess the incidence of post‐chemotherapy serious adverse effects on the basis of cancer registry data. Methods The population was composed of new invasive cancer cases, with the exception of haematopoietic...

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Magnetic Resonance in Chemistry

Increasing field strength versus advanced isotope labeling for NMR‐based fluxomics

Published: 17 January 2020

Author(s): Mickael Dinclaux, Edern Cahoreau, Pierre Millard, Fabien Létisse, Guy Lippens

Abstract Nuclear magnetic resonance (NMR)‐based fluxomics seeks to measure the incorporation of isotope labels in selected metabolites to follow kinetically the synthesis of the latter. It can however equally be used to understand the biosynthetic origin of the same metabolites. We investigate here different NMR approaches to optimize such experiments in terms of resolution and time requirement. Using the isoleucine biosynthesis as an example, we explore the use of different field strengths...

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Archives of Insect Biochemistry and Physiology


Published: 17 January 2020

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Journal of Food Biochemistry

Investigation of the effect of sodium nitrite on protein oxidation markers in food protein suspensions

Published: 17 January 2020

Author(s): Vasfiye Hazal Ozyurt, Semih Otles

Abstract The aim of this study is to investigate the effect of sodium nitrite (NaNO2) on protein oxidation and the use of 3‐nitrotyrosine (3NT) as a protein oxidation marker in suspensions of the food protein. Food proteins, namely bovine serum albumin, casein, and myofibrillar protein, were suspended in 100 mM sodium phosphate buffer and nitrated with 25 µM iron (III) chloride, 2.5 mM hydrogen peroxide, and 150 mg/kg NaNO2 at 37°C for a period of 24 hr. The food protein suspensions were...

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Journal of Food Biochemistry

Solanum vegetable‐based diets improve impairments in memory, redox imbalance, and altered critical enzyme activities in Drosophila melanogaster model of neurodegeneration

Published: 17 January 2020

Author(s): Opeyemi B. Ogunsuyi, Ganiyu Oboh, Gulmira Özek, Fatih Göger

Abstract The effects of two Solanum vegetables, S. macrocarpon L. (African eggplant), and S. nigrum L. (black nightshade) on aluminum model of neurodegeneration in Drosophila melanogaster was investigated. Flies were treated with AlCl3 alone or in combination with the leaves from both samples in their diets for 7 days. Thereafter, locomotor performance and aversive phototaxic suppression test for learning and memory were carried out. This was followed by assay for reactive oxygen species,...

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Journal of Heterocyclic Chemistry

A comparison between Suzuki cross‐coupling reaction and direct arylation in the synthesis of new antibacterial imidazo‐pyrazines/pyridazines

Published: 17 January 2020

Author(s): Siavash Salek Soltani, S. Morteza F. Farnia, Alireza Foroumadi

Abstract Two efficient synthetic routes to preparation of 2,3‐diarylimidazo[1,2‐a]pyrazines and 2,3‐diarylimidazo[1,2‐b]pyridazines are described. The procedures involve a Suzuki cross‐coupling reaction and a palladium‐catalyzed direct arylation at position 3 and finally a comparative study is achieved. The antibacterial activities of the synthesized compounds in vitro were measured and the results showed that most products presented moderate to good antibacterial activities. Compounds 3a, 3c,...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

December 2019


Duanyang Kong, Patrick J. Moon, Odey Bsharat, Rylan J. Lundgren
Direct Catalytic Decarboxylative Amination of Aryl Acetic Acids [Research Article]
Angew. Chem. Int. Ed. 2020, vol. 59, no. 3, p. 1313

Bing Liu, Lihui He, Liping Wang, Tao Li, Changcheng Li, Huayi Liu, Yunzi Luo, Rui Bao
Protein Crystallography and Site-Direct Mutagenesis Analysis of the Poly(ethylene terephthalate) Hydrolase PETase from Ideonella sakaiensis [Communication]
ChemBioChem 2018, vol. 19, no. 14, p. 1471

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, no. 7, p. 1159

Wolfgang Pfeiffer, Van Than Nguyen, Jan Neumann, Dirk Awe, Jens Tränckner
Operation and Control of a Full-Scale Biogas Plant Treating Wastewater from the Cleaning of Car Tanks [Research Article]
Chem. Eng. Technol. 2020, vol. 43, no. 1, p. 84

Dieter Wöhrle
Kunststoffe [Artikel]
Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 50

Luling Wu, Xue Tian, Hai-Hao Han, Jie Wang, Robin R. Groleau, Paramabhorn Tosuwan, Boontana Wannalerse, Adam C. Sedgwick, Steven D. Bull, Xiao-Peng He, Tony D. James
A Simple Near-Infrared Fluorescent Probe for the Detection of Peroxynitrite [Communication]
ChemistryOpen 2019, vol. 8, no. 12, p. 1407

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, no. 1-2, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Lucia Mazzapioda, Carmelo Lo Vecchio, Annalisa Paolone, Antonino Salvatore Aricò, Vincenzo Baglio, Maria Assunta Navarra
Enhancing Oxygen Reduction Reaction Catalytic Activity Using a Sub-Stoichiometric CaTiO3−δ Additive [Cover Profile]
ChemElectrochem 2019, vol. 6, no. 24, p. 5910

S. Ghosh, B. Pradhan
Lead-Free Metal Halide Perovskite Nanocrystals: Challenges, Applications, and Future Aspects [Minireview]
ChemNanoMat 2019, vol. 5, no. 3, p. 300

Frank Tabellion, Christoph Peters, Uwe Fischbeck, Manfred Regitz, Fritz Preuss
Imidovanadium(V) Complexes as Reaction Partners for Kinetically Stabilized Phosphaalkynes: Synthesis of 1,2,4‐Azaphosphavanada(V)‐cyclobutenes, 1,3,5‐Triphosphabenzenes, and 1H‐1,2,4‐Azadiphospholes [Organophosphorus Compounds, Part 148 : Full Paper]
Chem. Eur. J. 2000, vol. 6, no. 24, p. 4558

Byunghyuck Jung, Jungkyu K. Lee, Jungnam Kim, Eunhye K. Kang, Sang Yeong Han, Hee-Yoon Lee, Insung S. Choi
Synthetic Strategies for (−)-Cannabidiol and Its Structural Analogs [Minireview]
Chem. Asian J. 2019, vol. 14, no. 21, p. 3749

Arun K. Sinha, Danish Equbal
Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review]
Asian J. Org. Chem. 2019, vol. 8, no. 1, p. 32

Avick Kumar Ghosh, Indranil Samanta, Anushree Mondal, Wenshe Ray Liu
Covalent Inhibition in Drug Discovery [Review]
ChemMedChem 2019, vol. 14, no. 9, p. 889

Andrea Álvarez, Marta Borges, Juan José Corral-Pérez, Joan Giner Olcina, Lingjun Hu, Damien Cornu, Rui Huang, Dragos Stoian, Atsushi Urakawa
CO2 Activation over Catalytic Surfaces [Concept]
ChemPhysChem 2017, vol. 18, no. 22, p. 3135

Matthias Freitag, Nadja Möller, Andreas Rühling, Cristian A. Strassert, Bart Jan Ravoo, Frank Glorius
Photocatalysis in the Dark: Near-Infrared Light Driven Photoredox Catalysis by an Upconversion Nanoparticle/Photocatalyst System [Communication]
ChemPhotoChem 2019, vol. 3, no. 1, p. 24

Mingshuai Ma, Lin Dai, Chuanling Si, Lanfeng Hui, Zhong Liu, Yonghao Ni
Front Cover: A Facile Preparation of Super Long-Term Stable Lignin Nanoparticles from Black Liquor (ChemSusChem 24/2019) [Cover Picture]
ChemSusChem 2019, vol. 12, no. 24, p. 5213

Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief
The Periodic Table of the Chemical Elements and Sustainable Development [Essay]
Eur. J. Inorg. Chem. 2019, p. 4170

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Cover Picture Lebensmittelchemie 6/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73, no. 6

Elementerätsel 1 [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, no. 12, p. 40

Schüleraufgabe: CHEMKON 2/2017 [Schüleraufgabe]
CHEMKON 2017, vol. 24, no. 2, p. 91

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, no. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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