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Advanced Materials

Multishelled CaO Microspheres Stabilized by Atomic Layer Deposition of Al 2 O 3 for Enhanced CO 2 Capture Performance

Published: 22 August 2017

Author(s): Andac Armutlulu, Muhammad Awais Naeem, Hsueh‐Ju Liu, Sung Min Kim, Agnieszka Kierzkowska, Alexey Fedorov, Christoph R. Müller

CO2 capture and storage is a promising concept to reduce anthropogenic CO2 emissions. The most established technology for capturing CO2 relies on amine scrubbing that is, however, associated with high costs. Technoeconomic studies show that using CaO as a high‐temperature CO2 sorbent can significantly reduce the costs of CO2 capture. A serious disadvantage of CaO derived from earth‐abundant precursors, e.g., limestone, is the rapid, sintering‐induced ...

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Advanced Functional Materials

Free‐Standing and Eco‐Friendly Polyaniline Thin Films for Multifunctional Sensing of Physical and Chemical Stimuli

Published: 22 August 2017

Author(s): Weiwei Wu, Bin Wang, Meital Segev‐Bar, Wei Dou, Fang Niu, Yehu David Horev, Yunfeng Deng, Marian Plotkin, Tan‐Phat Huynh, Raneen Jeries, Han Zhu, A'laa Garaa, Shifaa' Badarneh, Linfeng Chen, Mingliang Du, Wenwen Hu, Hossam Haick

Multifunctional flexible sensors that are sensitive to different physical and chemical stimuli but remain unaffected by any mechanical deformation and/or changes still present a challenge in the implementation of flexible devices in real‐world conditions. This challenge is greatly intensified by the need for an eco‐friendly fabrication technique suitable for mass production. A new eco‐friendly and scalable fabrication approach is reported...

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Advanced Materials

Valuing Metal–Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbents

Published: 22 August 2017

Author(s): Karim Adil, Prashant M. Bhatt, Youssef Belmabkhout, Sk Md Towsif Abtab, Hao Jiang, Ayalew H. Assen, Arijit Mallick, Amandine Cadiau, Jamal Aqil, Mohamed Eddaoudi

The development of practical solutions for the energy‐efficient capture of carbon dioxide is of prime importance and continues to attract intensive research interest. Conceivably, the implementation of adsorption‐based processes using different cycling modes, e.g., pressure‐swing adsorption or temperature‐swing adsorption, offers great prospects to address this challenge. Practically, the successful deployment of practical...

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Advanced Functional Materials

Smart Photonic Crystal Hydrogel Material for Uranyl Ion Monitoring and Removal in Water

Published: 22 August 2017

Author(s): Fubing Xiao, Yongfang Sun, Wenfang Du, Wenhui Shi, Yan Wu, Shuzhen Liao, Zhaoyang Wu, Ruqin Yu

Uranyl ion (UO22+) pollution is a serious environmental problem, and developing novel adsorption materials is essential for UO22+ monitoring and removal. Although some progress is achieved, it is still a challenging task to develop an adsorption material with indicating signal for real‐time evaluation of the adsorption degree and the UO22+ concentration. Herein, this paper describes a smart photonic crystal hydrogel (PCH) material, which not only can be used ...

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Israel Journal of Chemistry

Recent Advances in Iron Catalyzed Oxidation Reactions of Organic Compounds

Published: 22 August 2017

Author(s): Eike B. Bauer

Abstract Iron‐catalyzed oxidation reactions have been increasingly investigated in the past two decades and have seen a major increase in research activity. This review article demonstrates the vigorous research activities in the field based on examples from the most recent literature. Catalyst systems are discussed that are active in the oxygenation of alkanes and alkenes to obtain alcohols, ketones or epoxides. Iron‐catalyzed...

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Chemistry - A European Journal

Structural Features of Europium(II)‐Containing Cryptates That Influence Relaxivity

Published: 22 August 2017

Author(s): Chamika U. Lenora, Fabio Carniato, Yimin Shen, Zahid Latif, E. Mark Haacke, Philip D. Martin, Mauro Botta, Matthew J. Allen

Abstract EuII‐containing complexes were studied with respect to properties relevant to their use as contrast agents for magnetic resonance imaging. The influences of molecular parameters and field strength on relaxivity were studied for a series of EuII‐containing cryptates and their adducts with β‐cyclodextrins, poly‐β‐cyclodextrins, and human serum albumin. Solid‐ and solution‐phase characterization of EuII‐containing complexes is presented...

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ChemPhysChem

A Review on Bimetallic Nickel‐Based Catalysts for CO 2 Reforming of Methane

Published: 22 August 2017

Author(s): Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi

Abstract In recent years, CO2 reforming of methane (dry reforming of methane, DRM) has become an attractive research area because it converts two major greenhouse gasses into syngas (CO and H2), which can be directly used as fuel or feedstock for the chemical industry. Ni‐based catalysts have been extensively used for DRM because of its low cost and good activity. A major concern with Ni‐based catalysts in DRM is severe carbon deposition ...

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Israel Journal of Chemistry

Polyhydrides of Sc, Zr and Hf and Their Proposed Formation.

Published: 22 August 2017

Author(s): Takashi Kurogi, Masahiro Kamitani, Patrick J. Carroll, Daniel J. Mindiola

Abstract Hydrogenation at 500 psi of (PNP)Sc(CH3)2 results in formation of a trinuclear polyhydride complex [(PNP)Sc]3(μ2‐H)4(μ3‐H)2 (1) in 55 % yield. The solid‐state structure shows a non‐symmetric trinuclear species resulting from one pincer phosphine arm being demetallated, and where two hydrides bridge all three Sc centers, whereas the other four bridge two. Hydrogenation of (PNP)Zr(CH3)3 at 200 psi results instead in formation of a...

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Chemistry - A European Journal

A Novel Bulky Heteroaromatic‐Substituted Methanide Mimicking NacNac: Bis(4,6‐ tert‐ butylbenzoxazol‐2‐yl)methanide in s‐Block Metal Coordination

Published: 22 August 2017

Author(s): Ingo Koehne, Sebastian Bachmann, Thomas Niklas, Regine Herbst‐Irmer, Dietmar Stalke

Abstract A novel bulky bis(4,6‐tBu‐benzoxazol‐2‐yl)methane ligand was synthesized in a straightforward three‐step synthesis. The corresponding complexes [Li{(4,6‐tBu‐NCOC6H2)2CH}THF], [K{η5‐(4,6‐tBu‐NCOC6H2)2CH}]∞, and [MgCl{(4,6‐tBu‐NCOC6H2)2CH}(THF)2] were obtained upon metalation with alkaline or alkaline‐earth‐metal reagents. Reduction of [MgCl{(4,6‐tBu‐NCOC6H2)2CH}(THF)2] with potassium metal or KC8 led to the formation of the homoleptic compound...

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ChemPhysChem

Nanocrystal–Dye Interactions: Studying the Feasibility of Co‐Sensitization of Dyes with Semiconductor Nanocrystals

Published: 22 August 2017

Author(s): Mona Mittal, Sameer Sapra

Abstract One of the recent developments in enhancing the performance of quantum dot sensitized solar cells (QDSSCs) is to combine QDs with dyes in order to overcome the drawbacks of QDSSCs. However, implementation of this requires a detailed investigation of the interaction between QDs and dye. Here, we have studied the effect of size and surface ligands in the interaction of CdSe nanocrystals (NCs) with Ru N‐719 dye. The...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

July 2017

 


Xinxing Zhang, Gaoxiang Liu, Sandra Ciborowski, Kit Bowen
Stabilizing Otherwise Unstable Anions with Halogen Bonding [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 9897

Jonathan Okerblom, Ajit Varki
Biochemical, Cellular, Physiological, and Pathological Consequences of Human Loss of N-Glycolylneuraminic Acid [Review]
ChemBioChem 2017, vol. 18, p. 1155

Hélène Olivier-Bourbigou, Céline Chizallet, Franck Dumeignil, Pascal Fongarland, Christophe Geantet, Pascal Granger, Franck Launay, Axel Löfberg, Pascale Massiani, Françoise Maugé, Armelle Ouali, Anne-Cécile Roger, Yves Schuurman, Nathalie Tanchoux, Denis Uzio, François Jérôme, Daniel Duprez, Catherine Pinel
The Pivotal Role of Catalysis in France: Selected Examples of Recent Advances and Future Prospects. [Review]
ChemCatChem 2017, vol. 9, p. 2029

Klaus Roth, Elisabeth Vaupel
Von Insekten, Chrysanthemen und Menschen [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 162

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Sigma Hashimoto, Takahiro Iwamoto, Daisuke Kurachi, Eiichi Kayahara, Shigeru Yamago
Shortest Double-Walled Carbon Nanotubes Composed of Cycloparaphenylenes [Communication]
ChemPlusChem 2017, vol. 82, p. 1015

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Marc T. M. Koper, Hasan Yılmaz, Ruud Kortlever, Recep Kas, Guido Mul
Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO2 Electroreduction by Process Conditions [Communication]
ChemElectroChem 2015, vol. 2, p. 354

Liming Dai, Xinliang Feng, Zhongfan Liu, Hua Zhang
Two-Dimensional Materials: A Powerful Platform for Energy Applications [Editorial]
ChemNanoMat 2017, vol. 3, p. 338

Ralf Haiges, Piyush Deokar, Monica Vasiliu, Trent H. Stein, David A. Dixon, Karl O. Christe
Cover Picture: Preparation and Characterization of Group 13 Cyanides (Chem. Eur. J. 38/2017) [Cover Picture]
Chem. Eur. J. 2017, vol. 23, p. 8989

Yilong Yang, Songcan Wang, Yongli Li, Jinshu Wang, Lianzhou Wang
Strategies for Efficient Solar Water Splitting Using Carbon Nitride [Focus Review]
Chem. Asian J. 2017, vol. 12, p. 1421

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Edmond Differding
The Drug Discovery and Development Industry in India-Two Decades of Proprietary Small-Molecule R&D [Review]
ChemMedChem 2017, vol. 12, p. 786

Sergey Akbulatov, Roman Boulatov
Experimental Polymer Mechanochemistry and its Interpretational Frameworks [Review]
ChemPhysChem 2017, vol. 18, p. 1422

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, p. 148

Hirotaka Koga, Naoko Namba, Tsukasa Takahashi, Masaya Nogi, Yuta Nishina
Renewable Wood Pulp Paper Reactor with Hierarchical Micro/Nanopores for Continuous-Flow Nanocatalysis [Communication]
ChemSusChem 2017, vol. 10, p. 2560

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Gregory J. P. Perry, Igor Larrosa
Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 3517

MATLAB für Dummies von Jim Sizemore und John Paul Mueller [Buchbesprechung]
Lebensmittelchemie 2017, vol. 71, p. 32

Reinhard Zellner
Die Fakten und ihre Wahrnehmung [Bildung & Gesellschaft]
Nachr. Chem. 2017, vol. 65, p. 662

Jana Thomas, Sabine Struckmeier, Bernhard F. Sieve
„Molekulares Sieben 2.0“ - vom Kontinuum zum Diskontinuum mit molekularer Küche [Das Experiment]
CHEMKON 2017, vol. 24, p. 142

Sarah Millar
Tips and Tricks for the Lab: Column Choices
ChemViews Magazine 2012.

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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